溶液缩聚物分子量分布及其控制的研究

本文根据溶液缩聚基本原理及反应过程的基本事实，用随机过程方法，得到缩聚产物分子量分布函数，并对分子量及其分布的控制作了讨论。     

Coverage and invariability in fuzzy systems

This paper presents a new complex system systemic. Here, we are working in a fuzzy environment, so we have to adapt all the previous concepts and results that were obtained in a non-fuzzy environment, for this fuzzy case. The direct and indirect influences between variables will provide the basis for obtaining fuzzy and/or non-fuzzy relationships, so that the concepts of coverage and invariability between sets of variables will appear naturally. These two concepts and their interconnections will be analyzed from the viewpoint of algebraic properties of inclusion, union and intersection (fuzzy and non-fuzzy), and also for the loop concept, which, as we shall see, will be of special importance.     

充油S-SBR加工行为的研究

在中试装置上合成相对分子质量分布较宽的充油S-SBR，考察不同环烷油和芳烃油填充量的充油S-SBR的流变性能和混炼行为。结果表明，增大油的填充量能提高充油S-SBR的流动性能，充芳烃油S-SBR相对于充环烷油的S-SBR对温度更敏感，宽相对分子质量分布的充环烷油S-SBR的混炼性能优于S-SBR1204及E-SBRl778，竟相对分子质量分布的充芳烃油S-SBR的混炼性能优于S-SBR1204，Solprene380和E-SBR1712。     

淮河流域水资源短缺风险评估与时空分析

根据2003-2013年淮河流域五省的降水量、径流系数、人均水资源量、人均GDP、人口密度等相关数据,构建水资源短缺风险评价体系,用熵权法对指标赋值,运用可变模糊模型对淮河流域及各省的水资源短缺风险进行评估和时空差异分析。结果表明:2003-2013年间淮河流域水资源短缺风险值总体较高,且呈缓慢的增长趋势,2004年降水较少,风险值达到最高;十年间河南省风险增加最为明显,而山东省较为稳定,风险增加也最低;在淮河流域五个区域中,河南省的风险程度最高,达到3.52;江苏省、山东省次之;安徽省和湖北省相对较低,达到2.86和2.51。水资源短缺风险二级指标分析发现,危险性最强的是河南省,安徽省最小;水资源短缺易损性最强的是山东省,湖北省最小;水资源短缺暴露性最强的是江苏省,山东省最小;水资源短缺可恢复性最好的是湖北省,河南省最差。同时,所有评价指标中人口密度、人均GDP、降水量对水资源短缺风险的影响较大。     

应用质谱扫描测定胸腺肽相对分子质量

目的 精确测定胸腺肽相对分子质量分布。方法 采用质谱扫描法。结果 3批胸腺肽相对分子质量均在2000～4000,无10 000以上的大分子蛋白。结论 本方法灵敏度高,可直观地测定胸腺肽相对分子质量分布状况,为控制胸腺肽质量提供了新的检测方法。     

Oxidative stability of high-fatty acid rice bran oil at different stages of refining

The contents of natural antioxidants and the oxidative stability of rice bran oils at different refining steps were determined. Tocopherols and oryzanols were constant in crude and degummed oils but decreased in alkali-refined, bleached and deodorized oils. The process of degumming, alkali-refining, bleaching and deodorization removed 34% of the tocopherols and 51% of the oryzanols. During storage of deodorized oil for 7 wk, 34% of the tocopherols and 19% of the oryzanols were lost. The maximum weight gain, peroxide value and anisidine value were obtained from alkali-refined oil during storage. The order of oxidation stability was crude ≥ degummed > bleached = deodorized > alkali-refined oil.     

面向水环境的传感网虚拟距离覆盖算法

针对水面传感器随机部署时网络覆盖率较低的问题,采用了一种面向水环境的无线传感网虚拟距离覆盖算法,在保证连通性的前提下提高网络的覆盖率。在虚拟距离算法中,每个传感器节点的运动受到3个虚拟距离的影响:节点之间的虚拟距离、未被覆盖区域格点与节点的虚拟距离以及边界与节点间的虚拟距离。仿真结果表明:该算法可以有效地提高网络覆盖率。可以得出以下结论:虚拟距离算法通过对节点位置的控制更新有效提高了网络覆盖率,使节点得到优化部署。     

High molecular weight polypropylene nanospheres: Synthesis and characterization

The high molecular weight (MW) polypropylene with average particle size of 60 nm was synthesized by controlled growth mechanism using Ziegler–Natta catalyst. The atomic force microscopy (AFM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) studies showed that PP nanoparticles were spherical in shape. Structure and crystallinity were concomitantly studied through Fourier transform infrared spectroscopy and X‐ray diffraction, respectively. It shows nanospherical PP particles with more crystallinity (～ 75%) compared with macrosized PP (～ 59%). In addition, differential scanning calorimetry studies revealed the finite particle size effect on T_g and the scale dependence T_g followed a first order exponential trend. As particle size goes down to nano‐ scale from macrosize, continuous elevation of T_g's were observed from ?25 to ?11°C. This phenomenon was directed to configuration entropy of single spherical nanoparticles of PP. The mechanical properties and surface roughness were also evaluated through AFM. At last, the properties of nanosized PP were compared with micron and macrosized particles. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

超高分子质量聚乙烯纤维黏结强度增强方法研究

为提高超高分子质量聚乙烯(UHMWPE)纤维复合材料中纤维与树脂基体之间的界面黏结强度,提出通过不同质量分数的硅烷偶联剂KH-570处理纳米SiO_2对UHMWPE纤维进行表面改性。对改性处理后的纤维与乙烯基酯树脂进行黏结强度试验,发现硅烷偶联剂处理纳米SiO_2能有效提高纤维的界面黏结强度,同时使纤维保持一定的断裂强度。     

阻垢缓蚀剂对不锈钢管缓蚀效果的评定方法

用点蚀电位法和失重法评价了七种阻垢缓蚀剂在不同冷却水样中对不锈钢的缓蚀效果。用腐蚀失重法评价阻垢缓蚀剂对不锈钢的缓蚀效果，既不合理也很难测准。点蚀电位法是评价阻垢缓蚀剂对不锈钢缓蚀效果的有效方法，但要选择合适的空白水样。