Interfacial tension of demixed polymer solutions near the critical temperature: polystyrene + methylcyclohexane

Interfacial tension between demixed solutions of polystyrene + methylcyclohexane has been measured near the critical temperature as a function of temperature using polystyrenes with molecular weights 9000 ～ 1.26 × 10⁶. The critical exponent for the interfacial tension was determined to be about 1.30 for the lower molecular weight systems. However, for higher molecular weights the exponent could not be obtained because the system departed from critical behaviour. Magnitudes of the interfacial tension were proportional to about N^?0.44, where N is the polymerization index. Experimental results were compared with the recently-proposed theories and found to be in qualitative agreement. The tricritical theory of polymer solutions was also compared with the experimental results.     

Estimation of the critical properties of compounds using volume-based thermodynamics

The importance, yet scarcity of the critical constants of thermally unstable fluids warrants the development of reliable methods for the estimation of these essential thermodynamic properties. A thorough investigation undertaken in this study on 1,589 compounds belonging to 83 chemical classes, indicated that the ratio of critical temperature to critical pressure of both low and high molecular weight compounds could be well expressed in terms of their volumetric properties. In addition, two new methodologies are presented for estimating V_c, as well as an indirect approach for prediction of T_c from surface tension data, altogether allowing the calculation of Z_c. Moreover, comparative studies are made with five group contribution methods. It is also demonstrated that by employing the Peng-Robinson EOS, and without prior knowledge of the critical properties, it is possible to calculate various thermophysical properties including P^sat., T_b, , ∆H^vap. , C_p, and even the T_c and P_c themselves.     

Relationship of structure to properties of surfactants. 16. Linear decyldiphenylether sulfonates

The properties of some well-characterized sodium linear decyldiphenylether (C₁₀DPE)sulfonates have been studied. Among the properties investigated are dynamic and equilibrium surface tension, critical micelle concentration (CMC), area per molecule at the aqueous solution/air interface, wetting time by the Draves technique, foaming by the Ross-Miles method, solubilization, and hydrotropy. The decyldiphenylether moiety appears to be equivalent to a terminally substituted straight alkyl chain of 16 carbon atoms. The trialkyl- and dialkyl-mono-sulfonates have solubilities of < 0.01 g/dm³ in water, but are readily soluble in hexane. The didecyldiphenyl ether disulfonate (DADS) has a very low CMC value (1.0 × 10⁻⁵ mol dm⁻³) in aqueous 0.1 N Na⁺ solution (NaCl), characteristic of surfactants with two hydrophilic and two hydrophobic groups. It also has a much larger area per molecule at the aqueous solution/air interface than the monodecyldiphenyl-ether monosulfonate (MAMS) and a much higher surface tension at the CMC. MAMS has a much lower surface tension at a surface age of 1 second (γ_1s) than either DADS or the monodecyldiphenylether disulfonate (MADS). In agreement with γ_1s and γ_eq values, wetting times increase in the order: MAMS < DADS < MADS and initial foam heights decrease in the order: MAMS > DADS > MADS. Solubilization for three water-insoluble surfactants decreases in the order: DADS > MAMS > MADS, while hydrotropy is most pronounced with the disulfonates.     

Investigations of fluid dynamics in mechanically stirred aerated slurry reactors

The fluid dynamics of stirred aerated slurry reactors with A-310® propeller, 4-blade 45° pitch turbine and 6-blade Rushton disc turbine were studied over a wide range of gas flow rates. With respect to power consumption, gas hold-up, and fluid dynamically limiting cases, viz., suspension and flooding, the Rushton disc turbine was found to be the best in stirred aerated slurry reactors. The influence of particle density, shape and mass fraction and of liquid properties on gassed critical stirrer speed, N_jsg, and of gassed power input per unit volume, P_jsg, on particle suspension and gas dispersion, were investigated. Empircal correlations in combination with that of Zwietering were established for scale-up design in three-phase slurry reactors.     

飞机水平盘旋下弹性支承转子的特性研究

为研究转子系统在一定的外激励下的特性,使得研究与实际状况更加吻合,采用Jeffcott转子弹性支承模型,建立飞机处于水平盘旋状态下弹性支承转子系统的运动微分方程.运用Runge-Kutta数值法研究了飞机水平盘旋下处于一定角速度的刚性和弹性不同支承情况下的瞬态响应,并对仿真结果进行对比分析.结果表明,由于弹性支承使其转轴刚度降低,其临界转速随之降低;处于同一角速度下的弹性支承比刚性支承进入稳定振动的时间长,比刚性支承振动幅度大;弹性支承和刚性支承在同样的情况下转动都会产生稳定的周期解;因此可以通过对转子系统支承刚度的适当调节,可以达到优化系统性能的目的.     

Reproducibility of transition temperature and critical current density of thin films of YBa2Cu3O7 on (100) LaAlO3

Submicrometer epitaxial films of YBa₂Cu₃O₇(YBCO) on (100) LaAlO₃ were made by coevaporation and furnace annealing. Samples from more than a dozen runs are used in this study. The zero resistance transition temperature (T _c) is high (89 or 90 K) if the film composition is phase pure (Ba/Y=2, Cu/Y=3) or if it is enriched in Ba and Cu. For these compositions the critical current density (J _c) at 77 K has an average value of 2×10⁵ A cm^–2, with a tendency for decreasingJ _c with increasing film thickness (0.2 to 0.8m). Variations inJ _c are not correlated with deviations from ideal stoichiometry. Steeper slopes of the resistance-temperature curves above 100 K and lower values of the room-temperature resistivity are associated with high values ofJ _c. If the film composition is enriched in Y relative to Ba and Cu,T _c decreases by several degrees.     

考虑用户偏好和平台收益的共享泊位分配模型

与机动车数量激增类似,泊位短缺也是导致城市交通拥堵主要问题之一,在不增加车位的情况下提高泊车位利用率也是解决交通拥堵的一种方法。针对城市“泊车难”和部分泊车场利用率较低的问题,考虑了用户的偏好特征,研究了一种具有用户偏好的泊车位共享策略。考虑存在三种不同的泊车方式,在中央商务区（CBD）等待泊车、共享私人泊位、共享公共泊位,运用累积前景理论分析用户的泊车成本,发现用户在不同情形下的选择存在差异。平台通过对关键路径法修改,采用了偏好分组法进行分配。算例对偏好分组的结果与采用关键路径法的分配结果进行了比较,结果表明,基于偏好分组法的分配满足了更多的用户需求,平台收益更高,为管理者提供决策参考。     

应对长江口咸潮入侵的临界流量经验模型研究

1994年以来,长江口咸潮入侵严重威胁当地供水安全,随着长江上游水库群陆续建成,有关部门提出了通过上游水库群压咸调度保障长江口地区供水安全的方案。为明确压咸调度的目标流量(即临界流量),基于统计分析的方法,采用多元回归分析和主成分分析方法,选取实测站点数据建立了盐度-潮差-入海流量的相关关系统计模型,研究了咸潮发生的机理;通过模型分析多次咸潮入侵数据,确定临界流量为一个变化值,潮差290～335 cm下的临界流量在9 390～21 633 m³/s之间。研究表明,当长江口咸潮入侵时,单独依靠长江上游水库调度压咸所需的流量大,响应时间长,压咸效果不明显。因此,实际压咸调度应通过流域整体调度与本地蓄淡避咸水库共同作用应对咸潮入侵。     

一类超临界椭圆方程组正解的存在性

讨论了n≥3维球域上具零边值的一类椭圆方程组,Henon型椭圆方程组,它是Lane-Emden方程组的变形,即其主要非线性项各有一个在球心取零值的对称权重.通过建立对称Sobolev函数空间到加权Lp空间的嵌入定理,证明存在一条关于所论方程组非线性项指数(p,q)的双曲线,称为Henon双曲线,它位于临界Hardy-Littlewood-Sobolev曲线上方,使得对于Henon双曲线下方的点(p,q),方程组具有一组非平凡解.     

分布式云数据库复合Trigger新机制

为灵活高效地解决在不同的场景下,更新云数据库系统中缓存的全局共享数据表的问题,本文提出了一种在云服务端分布式数据库使用的复合触发器新型的软件架构,并基于数据库触发器技术,引入了直接、间接和复合Trigger的3种机制,这3种Trigger机制的引用,使来自业务支撑模块的数据变化,或是实时业务模块的数据变化,其前端的应用程序都可以及时高效的更新缓存。该研究提高了系统的灵活性,稳定性和鲁棒性。特别复合Trigger机制,可以避免大量的跨网络数据交互发生,提高了应用的服务质量。