对堆芯熔化条件下锆合金包壳腐蚀动力学有关问题的讨论

针对在堆芯熔化条件下建立铝合金包壳腐蚀动力学模型时所涉及的有关问题和已有的模型进行了讨论和评述。     

Formation and thermal stability of amorphous Ni-Mo-P alloys

The experimental researches on the chemical deposition of Ni-Mo-P amorphous alloys were carried out by adding Na2 MoO4 into acidic solutions. The optimum technology conditions were obtained by orthogonal design experiments. The structures and the relationship between compositions and their thermal stability were studied by energy spectrum (EC), scanning electron micrograph and X-ray diffraction spectrum. Compared with Ni-P amorphous alloys, the Ni-Mo-P amorphous alloys have high crystallization temperature and thermal stability, and the hardness reaches its peak when the annealing temperature is 500 ℃. With the increase of the heat treatment temperature, the surface morphology of the alloys changes.     

INVESTIGATION ON CRYSTALLIZATION KINETICS OF Pd-Cu-Si GLASS

The crystallization kinetics of Pd-Cu-Si glass was studied by means of diferential scanningcalorimetry-Ⅱ.According to Kissinger peak shift meth(?)d and Arrhenius equation,theapparent activation energy was calculated.The crystallization kinetics follows Johnson-Mehl-Avrami equation with n=3.0 within 0.15相似文献   

High-temperature oxidation of SiC in a glow-discharge oxygen plasma

The oxidation kinetics and structure of the oxide scales formed on high-density SiC were studied in molecular oxygen at 740 Torr and in a glow-discharge oxygen plasma at 0.1 Torr at temperatures of 1000, 1100, and 1200°C. The monatomic oxygen formed by the glow discharge markedly increased the reaction rate and the vaporization of some of the oxidation products. The marked differences in kinetics suggest that the rate-controlling step during oxidation in molecular oxygen is the dissociation of adsorbed diatomic oxygen to the monatomic species. Films formed in molecular oxygen were mostly amorphous SiO₂ with small inclusions of SiC and graphite, whereas films formed in dissociated oxygen were primarily amorphous SiO₂ containing SiO, S₂O₃, and the coesite form of SiO₂.     

热处理非晶态Ni-P合金镀层的晶化过程

运用电沉积的方法在45钢基体上制备Ni-P合金镀层,使用差示扫描量热法(DSC)和热重法(TG)分析非晶态NiP合金镀层在20℃/min加热速率下的热效应和质量变化。在300℃和400℃分别对镀层进行0,15,30,45,60,75min的热处理,采用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、显微硬度计对镀层进行表征。结果表明:Ni-P合金镀层在加热过程中的放热峰出现在284.8℃处,镀层的质量和元素组成稳定;晶化过程经历了非晶态、亚稳态NiP和Ni5P2、稳定态Ni3P的转变;经过热处理后,镀层的显微硬度显著提高,最大值达1036.56HV,约为镀态的2倍;热处理态镀层的耐NaCl溶液腐蚀性能比镀态有所下降,但两者都比45钢基体好。     

A Two‐Stage Annealing Strategy for Crystallization Control of CH3NH3PbI3 Films toward Highly Reproducible Perovskite Solar Cells

The solvent‐engineering method is widely used to fabricate top‐performing perovskite solar cells, which, however, usually exhibit inferior reproducibility. Herein, a two‐stage annealing (TSA) strategy is demonstrated for processing of perovskite films, namely, annealing the intermediate phase at 60 °C for the first stage then at 100 °C for the second stage. Compared to conventional direct annealing temperature (DHA) at 100 °C, using this strategy, MAPbI₃ films become more controllable, leading to superior film uniformity and device reproducibility with the champion device efficiency reaching 19.8%. More specifically, the coefficient of variation of efficiency for 49 cells is reduced to 5.9%, compared to 9.8% for that using DHA. The TSA process is carefully studied using Fourier transform infrared spectroscopy, X‐ray diffraction, and UV–vis absorption spectroscopy. It is found that in comparison with DHA the formation of hydrogen bonding and crystallization of perovskite are much slower and can be better controlled when using TSA. The improvements in film uniformity and device reproducibility are attributed to: 1) controllable MAPbI₃ crystal growth stemming from the progressive formation of hydrogen bonding between methylammonium and halide; 2) suppression of intermediate phase film dewetting, which is believed to be due to its decreased mobility at the initial low‐temperature annealing stage.     

蒸发结晶操作中传热温差的选择

蒸发结晶是化工生产中常见的单元操作，在其加热过程中，较高的传热温差对于强化传热效率、提高设备能力极为有利。但是，传热温差过高会引起蒸发结晶操作的不稳定，甚至造成生产装置停车，使所追求的高效率适得其反。因此，必须合理选择传热温差，以保证生产装置在高效、稳定的状况下运行。     

Fat bloom formation and characterization in milk chocolate observed by atomic force microscopy

The surface microstructure and polymorphic behavior of milk chocolate subjected to multiple thermal cycles between 20 and 32, 33, or 34°C were examined using atomic force microscopy (AFM) and powder X-ray diffraction (XRD). The surface of unbloomed milk chocolate was smooth (surface roughness of 278 nm) and consisted of small, evenly distributed crystals. XRD results indicated the presence of mostly form V crystals and little or no form VI crystals. Cycling between 20 and 32°C resulted in little bloom formation and change in polymorphic behavior. Gradual bloom formation occurred as a result of cycling between 20 and 33°C, and was accompanied by the nascence of form VI crystals. Surface roughness increased gradually from 417 nm after one cycle to 476 and 521 nm after two and three cycles, respectively. Extensive bloom arose from cycling between 20 and 34°C. Surface roughness increased from 373 nm after one cycle to 603 and 736 nm after two and three cycles, respectively. This heavily bloomed chocolate consisted of jutting crystals and large raised, yet smooth areas that were haphazardly located within the chocolate matrix. In summary, a new perspective on the development of surface bloom due to thermal cycling is provided.     

Cooling rate effects on the microstructure and phase formation in Zr51Cu20.7Ni12Al16.3 bulk metallic glass

A detailed transmission electron microscope (TEM) study has been conducted to investigate the microstructures of the Zr₅₁Cu_20.7Ni₁₂Al_16.3 metallic glass formed at different cooling rates. It has been found that the most competitive crystalline phase to the amorphous structure is an oxygen-stabilized FCC NiZr₂-type phase, which in turn acts as the leading phase to trigger the formation of other crystalline phases in the slow-cooled alloy.