碱土金属在萃取剂与树脂间反应平衡常数的测定

研究了碱土金属离子在Ｄ００１树脂与８－羟基喹啉三氯甲烷溶液间的平衡常数Ｏ－ｔＫ的测定。其值依Ｍｇ、Ｃａ、Ｓｒ、Ｂａ次序减小。并得出萃取剂浓度［ＨＡ］。与金属离子在两相分配的关系。     

Stochastic defect diffusion model for relaxation effects in crystalline polyethylene

It is suggested that some relaxation processes observed in crystalline polyethylene are consequences of the diffusive motion of a particular defect called a point dislocation or twist dispiration loop along the polyethylene stems in lamellar crystals. The motion of the defect, characterized by a diffusion coefficient and a mobility, is described by solutions of the Smoluchowski diffusion equation with boundary conditions that constrain the defect to move along routes that produce experimentally observable results. The fact that passage of the defect causes both a 180° rotation of the chain and moves an extra CH₂ group in the direction of the chain axis is important to the interpretation of the data according to this model. The diffusion coefficient for a defect is estimated to be around 2 × 10^?9 cm² s^?1 at 70°C. This value is shown to be reasonable both from the viewpoint of detailed computer modelling of defect motion and contemporary ideas about scaling.     

基于DSP的恒温控制系统设计与实现

介绍了应用于DNA提取自动化工作站的一种基于DSP(数字信号处理器)的恒温控制系统。针对自动化工作站中敞开式恒温模块的高精度温控要求和纯滞后、易受环境干扰的温控特点,分别对温控系统软硬件进行设计,应用改进的位置式PID控制算法并结合高质量的PID参数整定,实现了对恒温模块的高精度温度控制。实际测试结果表明,在开放式温控环境下,恒温模块的温控精度达到了±0.15℃,具有调温速度快、温控精度高和抗干扰能力强的特点,完全满足DNA提取自动化工作站的设计要求。     

不同频率激励信号下土壤水分传感器性能试验

激励信号频率是影响高频电容式土壤水分传感器性能的重要因素。利用去离子水和2—异丙氧基乙醇(2—isoproxyethanol)或二氧六环(dioxane)2种溶液混合,配制了一系列等效土壤体积含水率为0.9%~51.8%的待测介电溶液来替代土样。从与土壤含水率的函数关系、温度变异性2个方面,分别对激励信号频率为40,50,60,70,80,90,100 MHz的7种土壤水分传感器进行了性能测试与分析。结果表明:7种频率的传感器的输出电压均与土壤体积含水率呈线性负相关,其相关系数R2均大于0.94;激励信号频率不影响传感器输出电压的温度变异性,温差是影响温度变异性的主要因素,其最大变异率均小于4%。试验结果可为设计高频电容式土壤水分传感器时选择激励信号频率提供依据。     

凸轮磨恒线速加工过程曲线优化

为了提高凸轮轴的加工效率和加工精度,开发可用于凸轮轴磨削修整系统的动态优化模块。根据凸轮轴恒线速磨削原理,在Matlab中完成了数学模型的建模,采用三次样条曲线拟合插值法对加工过程曲线进行了优化,从而得到了波动更小的速度曲线并减少了恒线速度磨削所引起的联动轴响应问题。实验表明,该方法很好地实现了在二次磨削中对凸轮轴表面轮廓的修整,提高了凸轮轴的表面质量。     

Change of the amorphous state by heat treatment below the glass transition temperature

This study was undertaken to elucidate the state of a polymer in the amorphous state through a change of motion of the molecular chain caused by heat treatment below the glass transition temperature. From dielectric measurements of amorphous poly(ethylene terephthalate) heat-treated below T_g, it was found that the average relaxation time, the distribution of relaxation time and the dielectric strength increase with increase of heat treatment. From these results, it was concluded that the amorphous state becomes more random by heat treatment.     

复合泡沫塑料的性能改进研究

为改善复合泡沫塑料的介电性能,采用金属氧化物粒子填充改性双马来酰亚胺空芯玻璃微球复合泡沫塑料得到了高介电常数、低介质损耗因数、低密度、力学性能良好的电介质材料。     

Evaluation of Polyester Resin as a New Compatibilizer for SBR/PVC Blends

A polyester (PE) based on the glycolyzed products of PET was prepared and added in different concentrations to a series of SBR/PVC blends. The addition of the polyester showed that all properties of SBR/PVC blends were improved by incorporation of PE. Highest mechanical strength values were obtained at a polyester concentration of 7.5 phr. Thermal analysis as well as dynamic mechanical properties of SBR/PVC blends after the addition of 7.5 and 10 phr polyester indicated one single glass transition temperature. The dielectric losses (?") were analyzed in the frequency domains in the two terms of Fröhlich related to the Maxwell Wagner effect and the orientation of the aggregates caused by the movement of the main chain. The permittivity (?') values were found to increase by increasing the polyester content. This increase was followed by a decrease in the ?" up to a 7.5 phr polyester content after which no pronounced change was noticed.     

抗氧剂3114合成反应热力学和动力学的研究

研究了常温溶剂法合成抗氧剂3114反应热力学和动力学过程。控制温度在117±2℃,研究结果表明,反应是零级反应,反应速率常数k=1.91×10-3/min,反应的平衡常数K=138.4(mol/L)-6,反应活化能Ea=1366.2J/mol。     

基于变速积分PID的恒温控制系统的应用研究

在多个领域都会用到恒温控制系统,设计一种基于变速积分PID的恒温控制系统,系统以STM32为核心处理器。该文讲述了系统的构成,分析了变速积分PID算法,并在恒温控制系统中得到运用。经过长时间的调试,得到合适的PID系数,使得系统的控制精度达到＆#177;0.01℃/30min。系统具有性能稳定,可靠性高的优点。