Ultrawideband high‐gain dual‐polarized antenna with anti‐interference capability

In this article, a high‐gain dual‐polarized antenna with band‐rejection capability for ultrawideband (UWB) applications is proposed. Tapered dipoles are chosen as a primary radiator to achieve UWB operation and it is reflected by a metallic cavity reflector for high gain radiation. A notch at WLAN band is realized by etching a set of four bent slots in the radiating elements. The measured results demonstrate that the proposed design with overall dimensions of 0.69λ _L × 0.69λ _L × 0.16λ _L (λ _L is free‐space wavelength at the lowest operating frequency) has operating bandwidth of 95.1% (3.2‐9.0 GHz) and the rejected frequency band from 5.0 to 5.9 GHz. Additionally, good unidirectional radiation patterns with a broadside gain from 8.1 to 11.5 dBi and radiation efficiency of better than 90% are also achieved.     

A dual‐patch polarization rotation reflective surface and its application to wideband wide‐beam low‐profile circularly polarized patch antennas

This study investigates the use of a polarization rotation reflective surface (PRRS) to construct a wideband, wide‐beam, low‐profile circularly polarized (CP) patch antenna. The device is composed of a feeding monopole antenna and a novel PRRS‐based dual‐patch artificial magnetic conductor (AMC) cell structure. The PRRS has two polarization rotation (PR) frequency points, generated by properly adjusting the width between square and L‐shaped metallic patches. A large PR band of 35.5% (5.1‐7.3 GHz) was achieved by combining two adjacent PR frequency points. The PRRS‐based patch antenna impedance bandwidth was measured to be 28.6% (5.1‐6.35 GHz), with a 3 dB axial ratio (AR) bandwidth of 21.8% (4.8‐6.4 GHz) and a profile of 0.045λ₀. Additionally, the proposed antenna exhibited the largest AR beamwidth (to our knowledge) of 175° and 128° in the xoz and yoz planes, respectively. It also produced a high broadside gain of 6.7 dBic within the operational bandwidth.     

Compact bandpass filter using CMRC‐based dual‐behavior resonator

This article presents a novel bandpass filter (BPF) using two proximity‐coupled dual‐behavior resonators (DBRs). The employed DBR is implemented by a single shunt stub with the compact microstrip resonator cell at its open end instead of the traditional dual stubs in cross‐shape. Due to the adoptions of the proposed DBR and proximity‐coupling scheme, both the transverse and longitudinal dimensions of the proposed BPF are reduced significantly. To verify the proposed idea, a demonstration microstrip BPF is designed and fabricated, and good agreement between the simulated and measured results can be observed, showing low loss and high selectivity due to four transmission zeroes in the stopband.     

Dual pH‐Induced Reversible Self‐Assembly of Gold Nanoparticles by Surface Functionalization with Zwitterionic Ligands

The dual pH‐induced reversible self‐assembly (PIRSA) of Au‐nanoparticles (Au NPs) is reported, based on their decoration with the self‐complementary guanidiniocarbonyl pyrrole carboxylate zwitterion (GCPZ). The assembly of such functionalized Au NPs is found at neutral pH, based on supramolecular pairing of the GCPZ groups. The resulting self‐assembled system can be switched back to the disassembled state by addition of base or acid. Two predominant effects that contribute to the dual‐PIRSA of Au NPs are identified, namely the ionic hydrogen bonding between the GCPZ groups, but also a strong hydrophobic effect. The contribution of each interaction is depending on the concentration of GCPZ on NPs, which allows to control the self‐assembly state over a wide range of different water/solvent ratios.     

Strong Electronic Interaction in Dual‐Cation‐Incorporated NiSe2 Nanosheets with Lattice Distortion for Highly Efficient Overall Water Splitting

Exploring highly efficient and low‐cost electrocatalysts for electrochemical water splitting is of importance for the conversion of intermediate energy. Herein, the synthesis of dual‐cation (Fe, Co)‐incorporated NiSe₂ nanosheets (Fe, Co‐NiSe₂) and systematical investigation of their electrocatalytic performance for water splitting as a function of the composition are reported. The dual‐cation incorporation can distort the lattice and induce stronger electronic interaction, leading to increased active site exposure and optimized adsorption energy of reaction intermediates compared to single‐cation‐doped or pure NiSe₂. As a result, the obtained Fe_0.09Co_0.13‐NiSe₂ porous nanosheet electrode shows an optimized catalytic activity with a low overpotential of 251 mV for oxygen evolution reaction and 92 mV for hydrogen evolution reaction (both at 10 mA cm^?2 in 1 m KOH). When used as bifunctional electrodes for overall water splitting, the current density of 10 mA cm^?2 is achieved at a low cell voltage of 1.52 V. This work highlights the importance of dual‐cation doping in enhancing the electrocatalyst performance of transition metal dichalcogenides.     

Two-Dimensional Superstructures of Silica Cages

Despite extensive studies on mesoporous silica since the early 1990s, the synthesis of two-dimensional (2D) silica nanostructures remains challenging. Here, mesoporous silica is synthesized at an interface between two immiscible solvents under conditions leading to the formation of 2D superstructures of silica cages, the thinnest mesoporous silica films synthesized to date. Orientational correlations between cage units increase with increasing layer number controlled via pH, while swelling with oil and mixed surfactants increase micelle size dispersity, leading to complex clathrate type structures in multilayer superstructures. The results suggest that a three-dimensional (3D) crystallographic registry within cage-like superstructures emerges as a result of the concerted 3D co-assembly of the organic and inorganic components. Mesoporous 2D superstructures can be fabricated over macroscopic film dimensions and stacked on top of each other. The realization of previously inaccessible mesoporous silica heterostructures with separation or catalytic properties unachievable via conventional bulk syntheses is envisioned.     

A Full‐Spectrum Metal‐Free Porphyrin Supramolecular Photocatalyst for Dual Functions of Highly Efficient Hydrogen and Oxygen Evolution

A full‐spectrum (300–700 nm) responsive porphyrin supramolecular photocatalyst with a theoretical solar spectrum efficiency of 44.4% is successfully constructed. For the first time, hydrogen and oxygen evolution (40.8 and 36.1 µmol g^?1 h^?1) is demonstrated by a porphyrin photocatalyst without the addition of any cocatalysts. The strong oxidizing performance also presents an efficient photodegradation activity that is more than ten times higher than that of g‐C₃N₄ for the photodegradation of phenol. The high photocatalytic reduction and oxidation activity arises from a strong built‐in electric field due to molecular dipoles of electron‐trapping groups and the nanocrystalline structure of the supramolecular photocatalyst. The appropriate band structure of the supramolecular photocatalyst adjusted via the highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels of the porphyrin gives rise to thermodynamic driving potential for H₂ and O₂ evolution under visible light irradiation. Controlling the energy band structure of photocatalysts via the ordered assembly of structure‐designed organic molecules could provide a novel approach for the design of organic photocatalysts in energy and environmental applications.