A universal dependence for thermal conductivity of metals and dilute alloys

A universal curve relating the maximum of thermal conductivity and its respective temperature with the residual electrical resistivity has been proposed for metals and dilute alloys. Based on the equation of that curve, a comparative analysis of selected literature data of thermal conductivity of metals, which have residual electrical resistivity in the range 10^–11<₀<10^–5. cm, have been performed. Using the data for 33 metals, confirmation of the Wiedemann-Franz law for the impurity component/T of thermal conductivity was obtained, which means that _th/_el1, where _th and _el are the parameters of the electron-lattice defect interaction obtained from measurements of thermal and electrical conductivity, respectively. Examples of the failure of the Wiedemann-Franz law are also presented, exhibiting the values of _th/_el in the range 0.16 to 25. Measurements of thermal conductivity in the range 2 to 20 K and determination of the residual electrical resistivity for the samples of Cd doped with Zn and quenched were performed, resulting in values _th/_el1.     

深海带电插拔连接器力学特性分析

以水下7 000 m工况的深海带电插拔连接器为研究对象,旨在获得湿插拔连接器在深海双重高压下的受力特性和插拔过程中的动密封性能。介绍连接器的插头结构与压力补偿技术;推导压力补偿器工作容积的计算公式;运用Ansys Workbench建立插头内壳体组件与插孔组件的动密封有限元模型,对内壳体、压力平衡膜及内胆进行强度计算;分析由连接器插拔引起的平衡膜内外瞬时压差对膜的应力分布及变形情况;讨论密封件径向压缩量、密封接触面摩擦因数、插拔速度对插拔过程中动密封性能的影响。结果表明:插头插合时,平衡膜外表面应力基本不变,其变形减小;拔出时,平衡膜外表面的应力及变形都逐渐增大。密封件之间的接触压力受密封接触面过盈配合量的影响明显,增大过盈配合量可显著提高动密封区域的接触压力及密封性能,同时也会加剧密封件失效的可能性,密封接触面的摩擦因数、插拔速度对接触压力的影响则较小。     

热压烧结Ti3AlC2材料的制备、结构与性能研究

采用热压工艺研究了不同工艺制度和原料中不同的Si含量对Ti3AlC2合成的影响.研究表明在1 300℃～1 500℃,30MPa压力和Ar气氛中热压摩尔比为n(TiC)n(Ti)n(Al)n(Si)=2110.2的混合粉末,可以得到纯度达98%(质量分数)以上的致密块体Ti3AlC2材料;添加的Si均匀分布在基体中,形成固溶体,当添加Si的摩尔比为0.2时,固溶体的化学式为Ti2 76Al0 78Si0.22C2.烧结试样的晶体为层片状结构,1 300℃和1 400℃时,烧结试样的晶粒尺寸分别为10μm～15μm和20μm～30μm.材料的维氏硬度为3.3 GPa～5.0 GPa,弹性模量为289 GPa,抗压强度为785 MPa,抗弯强度为375 MPa,断裂韧性为7.0 MPa·m1/2;25℃时,电导率为3.1×106 S·m-1,热容为125.4 J/mol·K,热导率为27.5 W/m·K;热膨胀系数为8.8×10-6 K-1.     

综合管廊电气工程的相关问题研究

城市综合管廊是现代城市建设的重要综合系统,其电气工程设计工作需要关注供电电源、接地系统、照明设计、电气设备防潮、电缆敷设等关键环节。     

不同添加剂对AgSnO2In2O3触头材料电性能的影响

采用内氧化法工艺制备了不含添加剂及分别含添加剂CuO或TeO2的3种AgSnO2In2O3触头材料。应用模拟继电器试验设备检测了这3种材料在AC230 V、25 A阻性负载条件下的电寿命、熔焊力、电弧能量、燃弧时间、质量侵蚀率等相关电性能参数,并对检测结果及试验后铆钉触头样品进行了分析。研究发现:与不含添加剂的AgSnO2In2O3材料相比,添加剂CuO对材料的电寿命影响不大,而添加剂TeO2明显提高了材料的电寿命;含添加剂的两种材料的熔焊力和电弧能量均有了不同程度的降低,但它们的质量侵蚀率却明显增加。     

连续通电条件下触点接触电阻劣化的初步分析

电器长期通电后可使触点表面劣化,具体体现为接触电阻稳定增大、无规律增大、周期性变化、瞬时变化等电接触失效形式。本文以银镍触点材料为例,试验研究了接触压力、通电时间和通电电流对接触电阻的影响,并分析了接触电阻劣化失效的物理机制。     

Synergistic Effect of PVDF-Coated PCL-TCP Scaffolds and Pulsed Electromagnetic Field on Osteogenesis

Bone exhibits piezoelectric properties. Thus, electrical stimulations such as pulsed electromagnetic fields (PEMFs) and stimuli-responsive piezoelectric properties of scaffolds have been investigated separately to evaluate their efficacy in supporting osteogenesis. However, current understanding of cells responding under the combined influence of PEMF and piezoelectric properties in scaffolds is still lacking. Therefore, in this study, we fabricated piezoelectric scaffolds by functionalization of polycaprolactone-tricalcium phosphate (PCL-TCP) films with a polyvinylidene fluoride (PVDF) coating that is self-polarized by a modified breath-figure technique. The osteoinductive properties of these PVDF-coated PCL-TCP films on MC3T3-E1 cells were studied under the stimulation of PEMF. Piezoelectric and ferroelectric characterization demonstrated that scaffolds with piezoelectric coefficient d₃₃ = −1.2 pC/N were obtained at a powder dissolution temperature of 100 °C and coating relative humidity (RH) of 56%. DNA quantification showed that cell proliferation was significantly enhanced by PEMF as low as 0.6 mT and 50 Hz. Hydroxyapatite staining showed that cell mineralization was significantly enhanced by incorporation of PVDF coating. Gene expression study showed that the combination of PEMF and PVDF coating promoted late osteogenic gene expression marker most significantly. Collectively, our results suggest that the synergistic effects of PEMF and piezoelectric scaffolds on osteogenesis provide a promising alternative strategy for electrically augmented osteoinduction. The piezoelectric response of PVDF by PEMF, which could provide mechanical strain, is particularly interesting as it could deliver local mechanical stimulation to osteogenic cells using PEMF.     

交流滤波器避雷器电气特性分析中不同仿真模型的影响

交流滤波器是直流输电系统的重要设备。主要分析仿真模型对交流滤波器用避雷器电气特性（过电压、电流和吸收能量）的影响,基于PSCAD电磁仿真程序,开展滤波器投入和交流滤波器母线接地故障下的建模及仿真计算。仿真结果表明：在交流滤波器投入工况下,采用单个滤波器大组模型（模型1）进行仿真时,在运滤波器的避雷器不动作,与实际情况不符;在滤波器投入及滤波器母线接地故障下,完整参数模型（模型3）中各组滤波器用避雷器过电压比原系统模型（模型2）和模型1降低可达21%,电流降低可达53%,但吸收能量升高可达56%。因此,若在绝缘设计中不采用完整参数模型,避雷器电压电流设计值会偏大,能量设计值会偏小,同时会在滤波器投入工况下忽略同大组其他交流滤波器的避雷器动作情况。     

AlCl3-BMIC离子液体的电导率

研究AlCl3-BMIC(氯化-1-甲基-3-丁基咪唑)离子液体电导率与温度、组分之间的关系。结果表明:当离子液体中AlCl3的摩尔分数x(AlCl3)<0.667时,离子液体的电导率随着x(AlCl3)的增加而增大;但在0.6670.5的路易斯酸性区域,x(AlCl3)对温度系数α、β的影响均不明显。     

中小电机新能效等级对无取向电工钢需求的影响

电机新能效等级标准的实施,对硅钢产品提出了更高的要求。本文结合中小电机、无取向电工钢的发展,分析了电机的损耗与硅钢性能的关系,并提出了新能效等级标准实施后对无取向电工钢的需求预测。