Preparation of rechargeable lithium batteries with poly(methyl methacrylate) based gel polymer electrolyte by <Emphasis Type="Italic">in situ</Emphasis>γ-ray irradiation-induced polymerization

An admixture of commercial liquid electrolyte (LB302, 1 M solution of LiPF₆ in 1:1 EC/DEC) and methyl methacrylate (MMA) was enclosed in CR2032 cells. The assembled cells were then -ray-irradiated using configurations of half cells and full cells. Through this in situ irradiation polymerization process, we obtained rechargeable lithium ion cells with poly(methyl methacrylate) (PMMA) based gel polymer electrolytes (GPE). Galvanostatic cycling, AC impedance spectroscopy, and cyclic voltammetry were employed to investigate the electrochemical properties of the cells and the gel polymer electrolyte. This PMMA-based gel polymer electrolyte was found to exhibit a high ionic conductivity (at least 10^–3 S cm^–1) at room temperature. Due to a significant increase in the charge transfer resistance between the GPE and the cathode, the cell impedance of a PMMA-based lithium ion cell is greater than that of a liquid-electrolyte-based cell. The discharge capacity of a LiNi_0.8Co_0.2O₂/GPE/graphite is approximately 145 mAh g^–1 for the first cycle and decreases to123 mAh g^–1 after 20 cycles. In addition, a large initial cell impedance (LICI) was observed in the irradiated positive half cell. In this paper, we propose a possible mechanism related to the detachment of the PMMA layer from the lithium electrode. This detachment of the PMMA layer from the lithium electrode has not been explicitly discussed previously.     

Hydrogen induced cracking of X80 pipeline steel

The hydrogen-induced cracking (HIC) behavior of X80 pipeline steel was studied by means of electrochemical charging, hydrogen permeation tests, tension test, and scanning electron microscopy (SEM). The experimental results indicate that the increase of charging time and charging current density or the decrease of the solution pH value leads to an increase of the hydrogen content in X80 steel, which plays a key role in the initiation and propagation of HIC. It is found that the majority of macro-inclusions w...     

偏振激光诱导的薄膜表面周期性自组织结构

本文研究了激光诱导的周期性表面结构(LIPSS)在聚甲基丙烯酸甲酯(PMMA)薄膜表面的形成过程。在导电玻璃衬底上制备得到PMMA薄膜,经p偏振的XeCl准分子激光照射后形成周期性的褶皱结构。用原子力显微镜(AFM)观察发现,形成的褶皱结构周期具有纳米量级,且当引入外加电场时,褶皱形成所需的激光脉冲数减少到2。当外加电压增加到30V时,褶皱的周期间隔明显减小,LIPSS变得不可控,出现了柱状的自组织结构。与直接用准分子激光照射的薄膜样品相比,外加辅助电压的引入改变了PMMA样品表面褶皱结构形成的时间和周期大小,褶皱形成的内部驱动力也发生了变化。     

均匀流场中三维陷落腔流激振荡实验研究

针对均匀流场中,三维等高型陷落腔因分离流而产生的流激振荡问题,开展了系列的实验研究.实验过程中,主要考虑来流攻角为0时,流速变化(Re=2.06×105~1.16×106)对三维陷落腔流激振荡特性的影响.同时,分别测量了三维腔体侧壁周向及垂向流体压力,分析了腔体内稳态压力和脉动压力的周口、垂向分布规律及腔口剪切层自持振荡特性.实验结果表明:均匀流场中三维陷落腔内部压力分布复杂,且当雷诺数大于某值时腔体内稳态压力全都呈现出负压,同时腔口随边处存在着较大的脉动压力,且脉动压力随相对高度增加而减小,但腔口导边及侧面处的脉动压力随相对高度增加而增大.剪切层自持振荡频率的无量纲数St数随Re变化为一常数值,但其值略大于气流场中二维陷落腔的St数.     

应力型大模面积光子晶体光纤的纤芯设计

通过施加完美匹配层,利用有限元法,研究热应力诱导的单偏振大模面积光子晶体光纤的偏振特性,计算纤芯参数对场能量分布系数和偏振损耗比的影响.结果表明,随着纤芯折射率提高,两正交偏振模的损耗比下降,当纤芯直径减小时,场能量分布系数降低.     

金属网架天线罩中金属梁杆的感应电流矩量法分析

用矩量法对金属网架天线罩中金属梁杆的感应电流率进行了理论分析,并利用此方法对导电圆柱体的感应电流率进行了仿真分析,数值仿真结果与经典方法吻合较好。针对常规矩量法在处理规则矩形柱体感应电流率中存在的问题提出了改进模型,结果可较理想地满足工程设计的需要。     

适应长春-吉林高速铁路建设的公路诱增客流量预测方法

分析了长春-吉林高速铁路的修建对吉林省区域公路旅客运输方式的影响,通过分析相关数据,确定了长春-吉林高速铁路公路诱增客流量的变化规律,并采用适当的计算模型预测高速铁路建设项目影响区域范围内的公路诱增客流量。研究结果不仅能为长春-吉林高速铁路建设项目的可行性研究提供理论依据,而且能为受该铁路影响,公路旅客运输系统做相应的调整提供技术支持。     

合金元素对TRIP钢连续冷却固态相变和硬度的影响

为了研究Al和P合金元素在TRIP钢固态相变过程中的重要作用,利用热膨胀实验、金相观察、显微硬度测量等方法绘制了4种不同Al和P含量的C-Mn-Al-P TRIP钢的CCT图.结果表明,Al元素强烈缩小奥氏体相区,提高Ac3与Ms,促使CCT图左移和上移.P元素能够阻碍碳化物的生成,当钢中w(P)达到0.14%时,能显著将CCT曲线图中的珠光体区与贝氏体区右移.P元素对先共析铁素体相变和马氏体相变没有显著影响.随着冷却速率的增加,材料的显微硬度增加.对于每一种成分超过其临界冷却速率时将得到完全的马氏体组织.添加固溶强化元素可以强化铁素体基体,增加铁素体基体的硬度,P元素固溶强化能力最强,Mn元素稍弱,Al元素很弱.     

圆柱形建筑双幕墙结构的内部风效应

对圆柱形建筑双幕墙进行了多参数对比风洞试验,研究了圆弧双幕墙结构风致平均内压的空间分布特性,阐述了廊道内平均风压的分布机理,给出了风致平均内压的理论估算方法,并与试验结果进行对比,吻合较好.研究表明:圆弧型双幕墙在背风向时,廊道内的平均风压非常均匀,其风致平均内压的分布受外幕墙开孔率、廊道间距和来流风速的影响很小;而在迎风向和侧风向时,廊道内的平均风压分布不均匀,其风致平均内压的分布随开孔率和来流风速的增大、廊道间距的减小变得越来越不均匀.     

Optimization of material structure of ploy-Si thin film based on Al induced crystallization

Based on Al induced crystallization (AIC) method, influences of different material structures on formation and characteristics of ploy-silicon thin films were studied and optimized. Al-Si films on glass with different structures (Si/Al/Glass, Al/Si/Glass, Si/Al/…/Si/Al/Glass) were deposited on glass substrates by sputtering method. All samples were annealed for MIC with varied time processes under 500℃ N2 environment. X-ray diffraction test and scanning electron microscope were adopted to characterize cryst...