一种基于SBL和APIT的混合定位算法

由于子区域分割粒度的限制,基于阶次序列的定位算法(Sequence-based localization,SBL)存在边缘区域节点定位误差较大和不能保证平均定位误差性能的问题。针对这些问题,提出了一种基于SBL和APIT的混合定位算法,利用APIT信标三角形切割SBL算法子区域,减小子区域面积,实现了分割粒度的细化。通过预先进行系统训练,优化了混合算法的加权系数,进一步提升了算法的定位精度。仿真结果表明,相比于原算法,所提出的混合算法有效地提升了边界区域节点的定位精度,其平均定位误差降低了17.9%,使基于阶次序列的定位算法的定位精度得到了有效改善。     

分子内敏化鎓盐的合成及光敏性研究

二芳基碘鎓盐和三芳基硫鎓盐是阳离子聚合的光引发剂和光敏产酸物,但他们在300nm以上的光吸收很低,限制了对紫外光的利用效率。为解决此问题,本文合成了一些新的碘鎓盐和硫鎓盐,并用凝胶时间方法考察了它们的光引发效率。实验结果表明,2-苯硫基甲基,2′,4′-二甲基二苯碘鎓盐和9-蒽丙基,二苯基硫鎓盐具有特别高的光引发效率,这归之于光照时这些鎓盐发生了分子内电荷转移反应,即发生了分子内敏化。9-蒽丙基二苯硫鎓盐分子中的蒽基(An)是电子给体也是敏化基团,光照时可发生如下反应:     

On the nature of the active state of silver during catalytic oxidation of methanol

Under the applied high reaction temperatures (900 K) the Ag surface is restructured and a tightly held oxygen species is formed on the surface (O) apart from O atoms dissolved in the bulk (O). Methanol oxidation to formaldehyde proceeds through this O species as demonstrated by application of a variety of spectroscopic techniques.     

Morphologies and microstructures of tree-like carbon produced at different reaction conditions in a CVD process

Centimeter-size multi-branched tree-like carbon structures have been generated by the catalytic chemical vapor deposition of toluene using ferrocene as the catalyst precursor and investigated by means of SEM, TEM, and EDX. It is found that a temperature of 1000-1200 °C and a carrier gas flow rate of 1000-2500 ml/min are necessary for the generation of the carbon trees. Their morphologies and microstructures change greatly with the changing reaction conditions. The fractal dimensions of the trees are calculated to quantitatively investigate the influence of different reaction temperatures on the morphologies.     

Synthesis of carbon nanocapsules containing Fe, Ni or Co by arc discharge in aqueous solution

A simple, inexpensive and one-step synthesis method of metal-containing carbon nanocapsules using an arc discharge in aqueous solution is reported. It was found that Ni, Co and Fe nanoparticles could be in situ encapsulated in carbon shells when the arc was performed respectively in aqueous solutions of NiSO₄, CoSO₄ and FeSO₄. Transmission electron microscopy, energy dispersive X-ray spectroscopy and electron diffraction patterns of selected areas were used to determine the crystalline phase of the metal cores. To explain the formation mechanism of metal-containing carbon nanocapsules, a model of discharge in solution is proposed. This result presents a simply controllable way to synthesize metal-containing carbon nanocapsules.     

Scrolls and nested tubes in multiwall carbon nanotubes

Recent high-resolution transmission electron microscopy (HREM) studies of multiwalled carbon nanotubes (MWCNTs) reveal a class of defects analogous to edge dislocations in a crystal. These defects are believed to mark the transition from scrolls on one side to nested tubes on the other. On the tube side, layer spacing becomes irregular. Analysis of the helicity of the tubes shows a strong correlation between diameter and helicity. This suggests that the organizing principle for the tubes is not Van der Waals forces, as in the case of graphite or turbostratic carbon, but preservation of helicity. Based on these observations and total energy calculations, the authors speculate that graphene monolayers initially form scrolls and subsequently transform into multiwall nanotubes through the progression of defects. Scrolls and nested tubes thus coexist within a single MWNT.     

Influence of untreated and novel electron‐beam‐modified surface‐coated silica filler on the thermorheological properties of ethylene–octene copolymer

We developed surface‐modified silica fillers by coating these with an acrylate monomer, trimethylolpropane triacrylate, or a silane coupling agent, triethoxyvinyl silane, followed by electron‐beam irradiation at room temperature. These were incorporated in an ethylene–octene copolymer rubber. Thermorheological studies of the unvulcanized ethylene–octene copolymer and its untreated and modified silica‐filled composites were done with a shear dynamic oscillating rheometer. Modification of the silica filler, especially via the silanization process followed by electron beam treatment, significantly reduced filler–filler networking as revealed from the log–log plots of storage modulus and complex shear viscosity, and its real component. The rheological complexity of the compositions was analyzed from a double logarithmic plot of the storage modulus and loss modulus. The results obtained from the master curves constructed on the basis of the time–temperature superposition principle and the activation energy calculated from the Arrhenius equation for the flow of above these compounds further supported these findings. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2453–2459, 2003     

基于自适应定位的传感器频率的对比研究

为了研究传感器的运动频率对目标定位的影响,运用传感器与目标之间的距离信息,提出一种能在连续时间内进行目标定位的线性自适应算法。借助定位算法的稳定性条件,理论分析了传感器的频率对目标定位的作用。进一步通过Matlab仿真,对比研究了不同频率的传感器对固定目标以及持续漂移目标的定位效果。实验表明,传感器的频率会影响目标定位的时间以及定位结果的准确性;高频率的传感器可以减少目标定位所需的时间;在三维空间中,当传感器在每个坐标方向上的振幅相同时,为取得准确的定位结果,传感器的频率分量不能完全相同。对持续漂移的目标进行准确定位,传感器的运动频率要比目标漂移频率高。     

改进的DV-Hop算法在节点定位中的应用研究

基于传统DV-Hop算法的定位技术,通过分析该算法误差产生的主要原因,提出了节点间跳数的修正方法。通过在广播通信中采用双通信频率,将节点间的跳数缩减为0.5 R,减少了平均跳距的误差。通过Matlab软件的实验验证,本算法可以提高节点定位精度和网络通信频率,可进一步提高定位精度,定位结果达到了预期的目的。