Kinetics of synthesis of Li4Ti5O12 through solid-solid reaction

1. Introduction The solid-solid reaction used in synthesizing various kinds of electrochemical materials has many advantages, such as simple process, without using solvent, saving energy, friendly to the environment and easy to obtain good quality materials like nano-size materials. Recently, the manufacturing of electrochemistry materials has been paid more atten- tion due to its increasing needs. Therefore it is a natural interest to study the synthesis of electro- chemical materials by usin…     

Grain-size effects in the quasi-static fracture resistance of a thermally embrittled RPV steel (quenched and tempered microstructures)

The elastic-plastic fracture toughness and crack extension behavior under the quasi-static loading regimen of several thermally embrittled conditions of a nuclear reactor pressure vessel (RPV) steel were assessed on the basis of microstructural parameters. It was discovered that the bainite packet size is the fracture properties controlling parameter of single-phase quenched and tempered microstructures. Results were found in close agreement to those obtained in a parallel study with dual-phase annealed microstructures derived from the same low alloy steel. Similarly, it was concluded that a Hall-Petch type relationship correlates J-fracture mechanics criteria to the grain size.     

离心铸造梯度功能材料凝固过程中第二相的迁移行为

金属液在离心铸造下将发生第二相质点的径向移动。本文分析了第二相质点的移动规律。     

摆动滚子从动件盘形凸轮的CAD动画设计与加工

在AutoCAD基础上利用速度瞬心进行摆动滚子从动件凸轮机构轮廓曲线的CAD动画设计,同时可以生成刀具中心的加工轨迹、计算出压力角,能够实现CAD/CAM一体化,是一种简捷实用的新方法,可以直接应用于生产实际和教学.     

高碳钢钢丝在铅浴和CMC水溶液中的冷却行为

利用钢丝探头分别测量了含碳0.70%的钢丝在铅浴和CMC水溶液中的冷却过程。用冷却曲线分析法阐释了钢丝的冷却过程和相变规律。钢丝的“体积效应”和在其冷却介质中的热扩散能力共同决定了铅浴淬火过程及钢丝的相变过程。高碳钢钢丝在0.25%CMC水溶液中可完全转变为珠光体组织,但其转变温度由于其连续冷却转变特性而高于在铅浴中的转变温度。根据铅浴淬火的冷却本质和CMC水溶液的冷却特性,用于替代铅浴的淬火介质应设法加快初始阶段冷却速率。     

离心泵性能参数的自动测定和自动控制

通过将计算机技术应用于离心泵性能参数的研究，实现了离心泵性能参数的自动测定和自动控制。     

应力交变下微型土压力计的标定及应用

为了研究土压力计在不同应力状态下的敏感系数,利用镶嵌有微型土压力计的模型桩,按照两种方式设计应力交变加载模式进行标定:(a)从初始零应力状态分级加载—卸载至零;(b)从初始零应力状态加载到应力最大值,分级卸载—加载,逐渐到零应力状态。研究结果表明:初始应力为零的加载曲线线性较好,敏感系数可用线性函数进行拟合;初始应力不为零的加载曲线线性也较好,敏感系数也可用线性函数进行拟合;而卸载曲线包含显著的非线性和滞后效应,此时敏感系数就不是一个固定值,可采用指数曲线来进行拟合。将获取的标定系数应用于水平受荷模型桩的桩身应力分析中,在加载过程中3.5D~5.5D深处桩身应力一直变大,且变化幅度最大。研究成果可为水利工程中板桩、抗滑桩等水平受荷桩桩身截面尺寸及配筋设计提供参考。     

塔式旋转混凝土布料机的工况计算及配重调控分析

塔式旋转混凝土布料机是一种可高效输送混凝土的工程机械,被广泛用于混凝土浇筑。施工过程中,为减小其布料端悬臂力矩、保证其塔架的稳定性,需要随时根据其伸缩桁架的伸缩量来调节其配重块的位置。运用有限元ANSYS软件,分析了布料机在极限工况条件下的结构强度和最大合力矩,计算了19种不同工况下力矩、桁架伸缩量及配重调节距离之间的数值关系。在此基础上,利用MATLAB的拟合优化功能得出三者之间的函数关系并绘制三维曲线。研究结果为塔式旋转混凝土布料机的安全运行提供数据支持,同时为其后续的优化设计提供参考。     

Miscibility of oligomeric poly(dimethyl siloxanes) with long-chain unbranched alkanes: 2. Unsymmetrical cloud point curves

Previously obtained cloud point curves for mixtures of oligomeric poly(dimethyl siloxanes) (weight fraction W₁) with oligomeric polyethylenes have been supplemented by the use of samples of higher molecular weight. Initial flat regions at low-medium W₁ as well as a slight shoulder at extremely high W₁ are now considered to be due to crystallization, since the temperatures at which they occur are the melting points of the oligoethylenes. The actual cloud point curves were of an unsymmetrical dome shape, the form of which could not be simulated by using a concentration-independent interaction parameter g in the Flory-Huggins equation. However, spinodals calculated by assuming a quadratic dependence of g on composition were of the same shape as the experimental cloud point curves. The critical compositions calculated on this basis were also close to the experimental ones.