类金刚石薄膜的激光损伤特性测试与分析

使用脉宽12ns，波长1064nm调Q Nd：YAG激光器对真空阴极电弧沉积（VCAD）法制备的类金刚石薄膜进行抗激光损伤测试，结果表明，VCAD法镀制的薄膜抗激光损伤阈值为0．6J／cm^2。通过对热冲击效应的数值计算，得到了光斑中心的温度场和薄膜表面的应力场分布。研究表明，热应力在类金刚石薄膜的破坏过程中起主导作用，脉冲电弧沉积的DIE薄膜的激光损伤主要源于应力破坏。     

Effect of impinging ion energy on the substrates during deposition of SiOx films by radiofrequency plasma enhanced chemical vapor deposition process

Radiofrequency (13.56 MHz) plasma enhanced chemical vapor deposition process is used for deposition of SiO_x films on bell metal substrates using Ar/hexamethyldisiloxane/O₂ glow discharge. The DC self-bias voltage developed on the substrates is observed to be varied from − 35 V to − 115 V depending on the RF power applied to the plasma. Plasma potential measurements during film deposition process are carried out by self-compensated emissive probe. The deposited films are characterized by Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), nanoindentation, nano-scratch test and thermogravimetric analysis. The characterization results show strong dependency of the SiO_x films properties on the energy of the ions impinging on the substrates during deposition. Analysis of Raman spectra indicates an increase in vitreous silica content and reduction in defective Si-O-Si chemical structure in the deposited SiO_x films with increasing ion energy impinging on the substrates. The increase in inorganic (Si and O) content in the SiO_x films is further confirmed from XPS analysis. The growth of SiO_x films with more inorganic content and defect free chemical structure apparently contribute to the increase in their hardness and scratch resistance behavior. The films show higher thermal stability as the energy of the ions arriving at substrates increases with DC self-bias voltage. The possibility of using SiO_x films for surface protection of bell metal is also explored.     

玻璃微珠的应用研究进展

介绍了玻璃微珠的类型及其特性,综述了近年来玻璃微珠的应用研究进展,包括在建材、塑料、橡胶、涂料、医药等领域的应用情况。改性后的玻璃微珠可应用于电磁屏蔽和吸波材料的制备,拓宽了其应用范围,并分析了其应用前景。     

“Quasi‐freestanding” Graphene‐on‐Single Walled Carbon Nanotube Electrode for Applications in Organic Light‐emitting Diode

An air‐stable transparent conductive film with “quasi‐freestanding” graphene supported on horizontal single walled carbon nanotubes (SWCNTs) arrays is fabricated. The sheet resistance of graphene films stacked via layer‐by‐layer transfer (LBL) on quartz, and modified by 1‐Pyrenebutyric acid N‐hydroxysuccinimide ester (PBASE), is reduced from 273 Ω/sq to about 76 Ω/sq. The electrical properties are stable to heat treatment (up to 200 ºC) and ambient exposure. Organic light‐emitting diodes (OLEDs) constructed of this carbon anode (T ≈ 89.13% at 550 nm) exhibit ≈88% power efficiency of OLEDs fabricated on an ITO anode (low turn on voltage ≈3.1 eV, high luminance up to ≈29 490 cd/m², current efficiency ≈14.7 cd/A). Most importantly, the entire graphene‐on‐SWCNT hybrid electrodes can be transferred onto plastic (PET) forming a highly‐flexible OLED device, which continues to function without degradation in performance at bending angles >60°.     

Co-Se化合物薄膜的电沉积制备与表征

采用电沉积方法在SnO2玻璃基底上制备了Co-Se化合物薄膜.研究了薄膜形成的电化学机理和电沉积工艺对薄膜组成与形貌的影响,并表征了薄膜的结构与光学性质.结果表明:Co2+受预沉积Se的表面诱导还原或直接与H2SeO3的六电子还原反应产物H2Se发生反应形成Co-Se化合物;沉积电位、沉积温度和pH值均显著影响电沉积Co-Se化合物薄膜的形貌与成分;在沉积电位为?0.5V(vs SCE)、沉积温度为50℃和pH值为2.0时可制备出表面致密平整且呈六方晶型结构的富硒CoSe薄膜,其光吸收系数达到1×105 cm?1,直接带隙宽度为(1.53±0.01)eV,接近单结太阳电池光吸收层材料的理论最佳值.     

高强度Cu基块状非晶合金的最新研究进展

Cu基块状非晶合金是一种新型高性能材料,从合金体系、力学性能、合金过冷液体区域的性能及非晶形成能力几方面对Cu基块状非晶合金的最新研究进展进行了综述,并展望了新型Cu基块状非晶合金的工程应用前景.     

Preparation and characterization of polypropylene/sodium propionate (PP/SP) composite films for bread packaging application

To prolong the shelf life of bread, polypropylene/sodium propionate (PP/SP) composite films were prepared via a melt‐extrusion process. To investigate the feasibility of using PP/SP composite films as a bread packaging material, their chemical structure, morphology, mechanical properties, barrier properties against water, surface properties, and antimicrobial properties were investigated. A storage test for bread was also conducted. The mechanical and thermal stability of the PP/SP composite films enhanced with increasing SP content. Compared with pure PP, the PP/SP composites had increased hydrophilicity that increased with increasing SP content. These composite films showed enhanced antimicrobial activity against both Gram‐negative and Gram‐positive microorganisms. This was due to the interaction of SP and water originating from the bread, which modifies the pH of the bread and causes destruction of the cellular structures of fungi and also reduces the growth rate of bacteria. The enhanced thermal, mechanical, antifungal, and antimicrobial properties achieved by the addition of SP can be beneficial for maintaining the freshness of bread and prolonging its shelf life.     

Investigation of temperature-dependent polarization, dielectric, and magnetization behavior of multiferroic layered nanostructure

The PbZr_0.53Ti_0.47O₃(PZT)/CoFe₂O₄(CFO) layered nanostructures show lowering of dielectric constant and polarization, and an enhanced magnetization with a decrease in temperature from 400 K to 100 K. The temperature dependence of the real part of the dielectric constant illustrates a step-like behavior, whereas the imaginary part gives a relaxation peak near the step maxima temperature. A slow decrease in the polarization was observed from 300 K to 200 K, with an eventual collapse of polarization at ~ 100 K, and a complete polarization recovery with heating, these phenomena is reproducible over cycles of experiment. Remanent magnetization of the layered nanostructure was found to be three times higher at 100 K than that at room temperature. There is a slow enhancement in remanent (internal) magnetization with lowering of temperature, resulting in slow polarization switch and finally the collapse. The temperature-dependent dielectric, polarization and magnetization were different from the parent layer, indicating a kind of dynamic magneto-electric coupling in the layered nanostructures.     

Fatigue analysis of unidirectional GFRP composites under combined bending and torsional loads

Fatigue behavior of unidirectional glass fiber reinforced polyester (GFRP) composites at room temperature under in-phase combined torsion/bending loading was investigated. All fatigue tests were carried out on constant-deflection fatigue machine with frequency of 25 Hz. A 30% reduction from the initial applied moments was taken as a failure criterion in the combined torsion/bending fatigue tests of the composite materials. A series of pure torsional fatigue tests were conducted to construct the failure contour of GFRP composites using different failure theories. The obtained S–N curves from combined torsion/bending tests were compared with both, pure torsion fatigue test results and published results of pure bending fatigue tests of GFRP rods. Pictures by scanning electron microscope were used to closely examine the failure mode of the tested specimens under combined torsion/bending loading.

The results showed that, the unidirectional glass fiber reinforced polyester composites have poor torsional fatigue strength compared with the published results of pure bending fatigue strength. Endurance limit value (calculated from S–N equation at N = 10⁷ cycles) of GFRP specimens tested under combined torsion/bending loading equals 8.5 times the endurance limit of pure torsion fatigue. On the other hand the endurance limit of combined torsion/bending fatigue strength approximately half the fatigue limit of pure bending fatigue strength. The predicted values of combined torsion/bending fatigue strength at different number of cycles, using the published failure theory are in good agreement with the experimental data. For the investigated range of fiber volume fractions (V_f) it was found that higher stress levels are needed to produce fatigue failure after the same number of cycles as V_f increases.     

玻璃固载TiO2/纳米纤维素复合薄膜的制备及其光催化性能

将微晶纤维素溶解于NaOH-尿素的低温溶液中形成纤维素溶液, 在水浴中再生形成纳米纤维素溶液。然后将纳米纤维素溶液与TiO₂(P25)混合, 并添加少量的钛酸正丁酯作为交联剂形成复合溶液。将制备得到的复合溶液通过流延法固载到玻璃片表面形成玻璃固载的TiO₂/纳米纤维素复合膜。通过SEM、XRD表征了复合膜的形貌与结构。将玻璃固载的TiO₂/纳米纤维素复合膜在紫外光下进行光催化降解甲基橙(MO)以评估复合膜的光催化性能, 研究了纳米TiO₂含量对复合膜光催化性能的影响, 复合膜的重复使用性能以及光降解的动力学过程。结果表明: 复合膜对MO的光催化降解能力可达90%以上, 与纯TiO₂粉末相当, 并重复使用3次光催化性能基本保持不变。复合膜对甲基橙的降解动力学符合一级动力学特征。当纳米TiO₂相对于纤维素的质量分数为33.3%时, 光催化活性最高, 动力学速率常数为0.035 min^-1。