Ar^39／Ar^40 dating of three typical gold deposits in southern Qinling and its implication

1　ＩＮＴＲＯＤＵＣＴＩＯＮＱｉｎｌｉｎｇｏｒｏｇｅｎｉｃｂｅｌｔａｂｕｔｓＮｏｒｔｈＣｈｉｎａ ｐｌａｔ ｆｏｒｍｗｉｔｈＳｈａｎｇｚｈｏｕ ＤａｎｆｅｎｇｇｅｏｓｕｔｕｒｅｉｎｔｈｅｎｏｒｔｈａｎｄｎｅｉｇｈｂｏｒｓＹａｎｇｔｚｅ ｐｌａｔｆｏｒｍｗｉｔｈ     

Effects of gold plating on the resistance to high temperature discoloration of the cavity for ceramic packages

The effects of thickness and types of gold plating on the resistance to high temperature discoloration of gold plating on cavity surface of ceramic package were investigated. It was found that the thicker gold plating, the less discoloration degree for ceramic packages. Non-cyanide gold plating performed better resistance to high-temperature aging than cyanide gold plating. The relationship between the gold plating thickness and the amount of diffused Ni to the gold plating of ceramic packages with Au/Ni and Au/Ni-Co platings after heating at 420℃for 15 min was also studied. When the gold plating thickness reach 2.0 μm and 1.6 μm for Au/Ni and Au/Ni-Co plating systems, respectively, no discoloration was observed on the gold plating surface of cavity, and the corresponding diffused Ni amounts (mass fraction) are 1.0% and 0.4%, while the diffused Co to the gold plating is 0.04%.     

晋东北金矿床石英流体包裹体与找矿

晋东北各种类型金矿中都广泛发育热液型石英脉，与矿化有关的石英流体包裹体的特征反映了不同的矿床类型。对该区石英脉型、蚀变岩型及磁铁石英岩型金矿床的研究表明，石英中流体包裹体的成分、温度和红外吸收光谱等特征可以作为划分矿床类型和作为金矿找矿评价的标志     

XPS characteristics of sulfur of bio-oxidized arsenic-bearing gold concentrate and changes of surface nature of bio-oxidation residue

During bio-oxidation of sulfides, the chemical state change of sulfur is a complex and key factor. It is not only an indicator of the extent and intensity of the bio-oxidation, but also controls the property of bio-leaching medium and the period of oxidation. The chemical state of sulfur in sulfides oxidized by leaching bacteria was studied with XPS. Sulfide minerals in the arsenic-bearing gold concentrate consist of pyrite, arsenopyrite, chalcopyrite, galena, sphalerite and so on. In order to probe the pattern of the chemical state change of sulfur in the bio-oxidation residue of arsenic-bearing gold concentrate, the structure of the grains, and the surface nature of the residue, XPS test was carried out through different sputtering duration. The study of XPS clearly shows that: sulfides is progressively oxidized from the surface of minerals to the core by leaching bacteria; the chemical valence of sulfur changes from S^2- or [S2]^2- to [SO4]^2- ; sulfur in the core is in a reduction state, S^2- or [S2]^2- , but exists in an oxidation state S^6 on the surface; due to the chemical state change of sulfur, mineral phase of the bio-oxidation residue is also changed(sulfides inside, while sulfates outside); the layered structure is found in the grains of the bio-oxidation residue.     

Gold leaching with elemental sulfur in alkaline solutions under oxygen pressure

1　ＩＮＴＲＯＤＵＣＴＩＯＮＣｙａｎｉｄａｔｉｏｎｐｒｏｃｅｓｓ ,ｃｈａｒａｃｔｅｒｉｚｅｄｂｙｅｆｆｅｃｔｉｖｅｎｅｓｓａｎｄｌｏｗｏｐｅｒａｔｉｎｇｃｏｓｔ,ａｓａｃｏｎｖｅｎｔｉｏｎａｌｔｅｃｈｎｏｌｏｇｙｆｏｒｇｏｌｄｅｘｔｒａｃｔｉｏｎｆｒｏｍｏｒｅｓ ,ｈａｓｂｅｅｎｕｓｅｄｉｎｉｎｄｕｓｔｒｙｆｏｒｏｖｅｒ 10 0ｙｅａｒｓ .Ｈｏｗｅｖｅｒｔｈｅｃｙａｎｉｄｅｉｓａｈｉｇｈｌｙｔｏｘｉｃｃｈｅｍｉｃａｌ,ａｎｄｃｏｍｍｅｒｃｉａｌｃｙａｎｉｄａｔｉｏｎｐｒｏｃｅｓｓｉｓｌｉｍｉｔｅｄｉｎｔ…     

Bioleaching of refractory gold ore （ Ⅲ ）——Fluid leaching Jinya refractory gold concentrate by Thiobacillus ferrooxidans

A novel fluidized-bed reactor was designed and installed for bloleaching in a semi-continuous way, by which a process for biuleaching-cyanidation of Jinya refractory gold arsenical concentrate was studied. The arsenic extraction rate reaches 82.5 % after 4-day batch biooxidation of the concentrate under the optimized condition of pH 2.0, ferric ion concentration 6.Sg/L and pulp concentration 10%. And leached rate of gold in the following cyanida.tion is over 90%. The parameters of three series fluidized-bed reactors exhibit stability during the semi-continuous bioleaching of the concentrate.Armmic in the concentrate can be got rid of 91% after 6-day leaching. Even after 4 days, 82% of arsenic extraction rate was still obtained. The recovery rates of gold are 92 % and 87.5 % respectively in cyaniding the above bioleached residues.The results will provide a base for further commercial production of gold development.     

铜基仿金合金

为了寻找金的代用品,长期以来研究者竞相研制铜基仿金合金以满足制造较大的金色艺术品。文中阐述了研制铜基仿金合金的原理及其金色度和抗变色性的测试方法,分别叙述了铝、锌、锡、铟、硅、镍、稀土等元素对合金金色度和抗变色性的影响。鉴于各研究者得出的合金化学成分相差极大,最后提供了较为合理的铜基仿金合金的化学成分。     

无氰电刷镀金技术在航天工业中的应用

应用FJY-18无氰电刷镀金技术制得的金镀层具有孔隙率低、色泽金黄、光亮、结合力好,镀厚能力大于20μm,显微硬度HV=130～150,施工温度范围宽、无毒等特点,该技术已用于航天工业中某一关键部件的表面减磨密封镀金.     

Manufacturing processes of Atlantic Bronze Age annular gold ornaments—A case study of the Guînes gold hard (Pas-de-Calais,France)

ABSTRACT

The gold work from the Western European Middle and Late Bronze Age (about 1500–700 BC) is characterized by solid ornaments and vessels. This article deals with manufacturing techniques of heavy gold jewelry by presenting a gold hoard found at Guînes, Pas-de-Calais, in Northern France, as a case study. In particular, three ornament types will be taken into consideration: (1) solid penannular neck and arm-rings, plain or with linear or geometric decoration; (2) flange-twisted ornaments that appear in different dimensions, as small as ear rings, as neck rings, up to the large size of a belt; (3) complex, composite ornaments. The technological aspects dealt with in this precious metal working context are manifold, including ingot and lost wax casting, hammering and bending of solid rods, the production of flange-twisted rods, chasing as decoration method, and finally joining techniques such as soldering, riveting and folding, and creasing.     

Graphene-Au nanoparticle based electrochemical immunosensor for fish pathogen Aphanomyces invadans detection

Epizootic ulcerative syndrome (EUS) that is primarily caused by an invasive oomycete fungus Aphanomyces invadans is a devastating fish disease. Rapid diagnosis of EUS is significantly important for the control and treatment of this highly invasive disease. In our study, a label-free immunosensor constructed with G-AuNPs/SAM-Ab-BSA/GCE was proposed for the determination of Aphanomyces invadans. The electrode was prepared by the immobilization of anti-mycelium antibodies on graphene-AuNPs nanocomposite-cysteamine monolayers modified GCE. The optimized parameters were as follows: 90 min as the immersion time of SAM modified electrode in the anti-mycelium solution, 0.20 µg/mL as the concentration of anti-mycelium solution and 10 min as the interaction time of immunoreaction. The immunosensors exhibited low limit detection of 309 ng/mL and good reproducibility.