氢氧化铝对PE-HD／木粉复合材料阻燃性能和力学性能的影响

对Al(OH)3阻燃的高密度聚乙烯／木粉复合材料研究结果表明：随木粉和Al(OH)3添加量的增加，Al(OH)3对复合材料的阻燃效率增加，高木粉添加量的复合材料氧指数达27．1％，Al(OH)3的阻燃效率达0．203。增加木粉含量，复合材料的拉伸强度和弯曲强度明显提高；但Al(OH)3对拉伸强度的影响不大，而明显提高弯曲强度。增加木粉和Al(OH)3的含量，均能明显降低复合材料的冲击强度，破坏复合材料的韧性。     

内构件对高密度提升管内流体力学及径向气体混合的影响

Effect of bluff internals on the hydrodynamics and lateral gas mixing was studied in a 0.186m ID high-density riser. With the bluff internals, the extremely non-uniform radial profiles of solid fraction and particle velocity become flat and the dense downflow layer near the wall disappears, indicating the significant enhancement of solid turbulence introduced by the internals. The fluctuation velocity and solid fraction transient signal analysis indicates a significant increase in fluctuation intensity near the wall region. The length influenced by the internals on the flow structure is about 1 meter. The lateral gas dispersion coefficient increases significantly as the bluff internals exist in the riser.     

The massive formation of hybrid shish‐kebab structures in HDPE/PA6 microfibril blend subjected to melt second flow

During the melt second flow process, the synergetic effect of intense shear and polyamide 6 (PA6) microfibrils finally results in the massive formation of highly oriented crystalline structures in the entire thickness of high‐density polyethylene (HDPE)/PA6 microfibril blend. Interestingly, not only does the small microfibril induce HDPE crystallization to form typical hybrid shish–kebab structure, but the large microfibril (about 2 μm in diameter) also induces the formation of local hybrid shish–kebab structure. For the small PA6 microfibril, the oriented HDPE chains caused by the intense shear are absorbed on the whole surface of the microfibril and then a complete polymer underlayer is formed. Subsequently, the crystal nuclei appear on the underlayer, and then the other oriented HDPE chains overgrow from the nuclei in the form of folded chains and grow perpendicular to the microfibril. Finally, the typical hybrid shish–kebab structure is formed. While for the large PA6 microfibril, a few HDPE chains can be still absorbed on the microfibril surface due to the high surface energy of PA6. However, the driving force is insufficient to absorb largely oriented HDPE chains to form complete hybrid shish but only local adsorption layer, so the local hybrid structure is formed. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45274.     

PCPZ/Mg（OH）2对高密度聚乙烯热性能的影响

通过苯氧基环三磷腈(PCPZ)、氢氧化镁[Mg(OH)2]添加量以及二者协同对高密度聚乙烯(PE–HD)热性能影响的实验研究,探讨了PCPZ和Mg(OH)2对PE–HD热性能的影响规律,并对其影响原因进行了分析。结果表明,在PE–HD/PCPZ混合体系中,随着PCPZ含量的增加,材料的热稳定性和残炭率也随之增大,当PCPZ质量分数为44%时,800℃时的残炭率为33.3%。PCPZ/Mg(OH)2同时作用于PE–HD时对材料的热稳定性有协同效应,当PCPZ,Mg(OH)2质量分数分别为15%,35%时,协同效果最佳,800℃时的残炭率约为35.2%。     

ApoA1 Deficiency Reshapes the Phenotypic and Molecular Characteristics of Bone Marrow Adipocytes in Mice

In the present study, we studied the effect of apolipoprotein A-1 (APOA1) on the spatial and molecular characteristics of bone marrow adipocytes, using well-characterized ApoA1 knockout mice. APOA1 is a central regulator of high-density lipoprotein cholesterol (HDL-C) metabolism, and thus HDL; our recent work showed that deficiency of APOA1 increases bone marrow adiposity in mice. We found that ApoA1 deficient mice have greatly elevated adipocytes within their bone marrow compared to wild type counterparts. Morphologically, the increased adipocytes were similar to white adipocytes, and displayed proximal tibial-end localization. Marrow adipocytes from wild type mice were significantly fewer and did not display a bone-end distribution pattern. The mRNA levels of the brown/beige adipocyte-specific markers Ucp1, Dio2, Pat2, and Pgc1a; and the expression of leptin were greatly reduced in the ApoA1 knock-out in comparison to the wild-type mice. In the knock-out mice, adiponectin was remarkably elevated. In keeping with the close ties of hematopoietic stem cells and marrow adipocytes, using flow cytometry we found that the elevated adiposity in the ApoA1 knockout mice is associated with a significant reduction in the compartments of hematopoietic stem cells and common myeloid, but not of the common lymphoid, progenitors. Moreover, the ‘beiging’-related marker osteopontin and the angiogenic factor VEGF were also reduced in the ApoA1 knock-out mice, further supporting the notion that APOA1—and most probably HDL-C—regulate bone marrow microenvironment, favoring beige/brown adipocyte characteristics.     

高密度下行床相结构分析

在自行设计的一套高密度下行循环流化床中（80 mm ID, 高5.6 m）,对下行床内相结构进行了实验研究.实验结果显示：稀密两相时间分率的径向分布中心区域比较均匀,变化范围在10%～20%之间;轴向密相尺寸在十几毫米之间,密相内颗粒平均浓度为床层浓度的1.7倍,稀相颗粒浓度约为平均浓度的40%.在下行床中,稀密两相的转变是一渐变过程,而提升管内两相的转变是突变.通过比较高密度下行床与高密度提升管内密相特性,发现下行床内的密相因停留时间短、尺寸小和密度低而难以观察到.     

高密度烃燃料合成进展

总结了液体高密度烃燃料合成的最新进展,从原料、合成路线、使用性能等方面评价了多环高密度烃、高张力笼状烃、纳米添加剂等的优缺点及发展前景,分析了高密度烃燃料合成中存在的问题,介绍了作者所在课题组在此领域的工作进展。     

辐照交联对PE-HD薄膜结构和性能的影响

制备了辐照改性的高密度聚乙烯(PE-HD)薄膜,并对薄膜的结构和性能进行了分析。结果表明,随着辐照剂量的增加,薄膜的拉伸强度、耐撕裂强度得到提高,而薄膜的韧性降低太大。当辐照的剂量由1Mrad提高到6Mrad时,薄膜的纵向拉伸强度由20.5MPa提高到了23.2MPa,横向拉伸强度由18.1MPa提高到了19.5MPa,而纵向撕裂强度由11.8mN提高到了17.2mN,横向撕裂强度由8.3mN提高到了9.3mN,可见适度的辐照剂量可提高薄膜的力学性能,同时当辐照的剂量由1Mrad提高到6Mrad时,薄膜的断裂伸长率变化不大,当辐照剂量达到8Mrad时,薄膜的力学性能提高明显,而随着辐照剂量的进一步提高,薄膜的力学性能下降明显,同时凝胶含量增加,分子间的交联程度提高,从薄膜的熔体流动速率测试结果可以看到这种趋势。     

HDPE/PA6/MRP共混物阻燃性能研究

用微胶囊化红磷(MRP)作为阻燃剂,利用双螺杆挤出机制备了阻燃HDPE/MRP共混物,并首次使用点燃氧指数和燃烧氧指数来表征它们的阻燃性能。结果表明:添加少量的PA6可提高HDPE/MRP复合材料的阻燃效果,固定PA6与MRP的添加总量为15%,且在HDPE∶PA6∶MRP=85∶4∶11时,其极限氧指数最大,为22.1%;在固定MRP含量的情况下,随PA6含量的增加,HDPE/PA6/MRP复合材料的阻燃性增强。     

基于二维高密度电阻率数据的二、三维反演对比(英文)

目前高密度电阻率法所采用的数据处理方法主要是将地质结构体视为二度体进行二维处理,因而二维数据资料处理结果只是一种近似解释,其计算精度与反演效果达不到精确反演的要求。设计两种典型的电阻率异常地质体模型,利用有限单元法进行正演计算。为更真实地模拟实测数据并分析二维、三维反演算法对噪声的敏感度,在正演剖面中加入1%的高斯随机误差,然后再分别利用最小二乘法进行高密度电阻率法二维、三维反演。对比二维和三维高密度电阻率法的反演水平切片及垂直切片图可知,三维反演受高斯随机误差的影响更小,反演结果在模型异常位置、形态和电阻率特性反映上都比二维反演的效果更好,与实际地质模型更接近。