冷中间包衬对铸坯皮下气泡的影响

对铸坯产生皮下气泡的原因进行了调查和分析。认为中间包绝热板村中的有机挥发物和残余水分是铸坯产生皮下气泡的主要原因。从中间包绝热板的配方、制造技术和装砌等方面采取改进措施，可有效减少铸坯皮下气泡。     

Stochastic defect diffusion model for relaxation effects in crystalline polyethylene

It is suggested that some relaxation processes observed in crystalline polyethylene are consequences of the diffusive motion of a particular defect called a point dislocation or twist dispiration loop along the polyethylene stems in lamellar crystals. The motion of the defect, characterized by a diffusion coefficient and a mobility, is described by solutions of the Smoluchowski diffusion equation with boundary conditions that constrain the defect to move along routes that produce experimentally observable results. The fact that passage of the defect causes both a 180° rotation of the chain and moves an extra CH₂ group in the direction of the chain axis is important to the interpretation of the data according to this model. The diffusion coefficient for a defect is estimated to be around 2 × 10^?9 cm² s^?1 at 70°C. This value is shown to be reasonable both from the viewpoint of detailed computer modelling of defect motion and contemporary ideas about scaling.     

一种路点受限的移动传感器网络移动模型

提出了一种基于随机路点移动模型的路点受限移动模型。在模型设计中,对节点的路点选择和暂停时间进行了设置,从而保持节点移动的规律性,满足特定场景的需要。利用仿真工具模拟模型的节点移动轨迹与其它移动模型进行比较,并从路由协议方面进行评估。仿真结果证明:该模型对集体搜索等特定场景具有较好的适用性。     

分离式双管板列管换热器的设计与制造

论述了双管板换热器材料选择、管板胀管槽等结构的设计、双管板检漏设计、最佳胀管压力计算等 ,以及双管板制造中内侧管子管板液压强度胀接、外侧管子管板强度焊接、双管板间空腔内和管子管板焊接接头气密性试验的要求     

校园机会网络移动模型研究

节点的移动模型对机会网络的研究有着重要的影响。本文在分析校园环境下学生移动节点的活动特性,提出一种目的驱动和状态转换移动模型。构建节点移动的目的空间和目的位置空间,利用正态分布模拟节点在目的位置的停留时间。仿真结果表明,本模型更接近真实数据。     

Ionic liquids as electrolytes

Salts having a low melting point are liquid at room temperature, or even below, and form a new class of liquids usually called room temperature ionic liquids (RTIL). Information about RTILs can be found in the literature with such key words as: room temperature molten salt, low-temperature molten salt, ambient-temperature molten salt, liquid organic salt or simply ionic liquid. Their physicochemical properties are the same as high temperature ionic liquids, but the practical aspects of their maintenance or handling are different enough to merit a distinction. The class of ionic liquids, based on tetraalkylammonium cation and chloroaluminate anion, has been extensively studied since late 1970s of the XX century, following the works of Osteryoung. Systematic research on the application of chloroaluminate ionic liquids as solvents was performed in 1980s. However, ionic liquids based on aluminium halides are moisture sensitive. During the last decade an increasing number of new ionic liquids have been prepared and used as solvents. The general aim of this paper was to review the physical and chemical properties of RTILs from the point of view of their possible application as electrolytes in electrochemical processes and devices. The following points are discussed: melting and freezing, conductivity, viscosity, temperature dependence of conductivity, transport and transference numbers, electrochemical stability, possible application in aluminium electroplating, lithium batteries and in electrochemical capacitors.     

具有纳米结构的TiO_2纤维光催化氧化活性

研究了具有纳米结构,高比表面的锐钛矿TiO2纤维在光催化降解苯酚体系中的氧化性能,发现其活性与P25相当;通过加羟基自由基猝灭剂证实了羟基自由基(HO.)对苯酚降解的贡献;而通过加空穴猝灭剂则观察到明显的空穴(h )效应。并通过K I氧化反应进一步研究了催化剂表面上的空穴效应,结果表明,TiO2纤维上的光生空穴比P25稳定,其空穴量子产率是后者的3.3倍。     

Propagation of the Chain Explosive‐Decomposition Reaction in Silver Azide Crystals

The velocity of the chain explosivedecomposition reaction in silver azide whiskes has been measured (1500 m/sec). The measured velocity is identified as the propagation velocity of the diffusion front of holes generated in the course of explosive decomposition.     

The role of clay network on macromolecular chain mobility and relaxation in isotactic polypropylene/organoclay nanocomposites

It is well known that a so-called “three-dimensional filler network structure” will be constructed in the polymer/layered silicate nanocomposites when the content of layered clay reaches a threshold value, at which the silicate sheets are incapable of freely rotating, due to physical jamming and connecting of the nanodispersed layered silicate. In this article, the effect of such clay network on the mobility and relaxation of macromolecular chains in isotactic polypropylene(iPP)/organoclay nanocomposites was investigated in detail with a combination of DMTA, DSC, TGA, TEM, rheometry and melt flow index measurements. The main aim is to establish a relationship between the mesoscopic filler network structure and the macroscopic properties of the polymer nanocomposites, particularly to explore the role of the clay network on the mobility and relaxation of macromolecular chains. It was found that the nanodispersed clay tactoids and layers play less important or dominant roles on the mobility of iPP chains depending on the formation of percolating filler network. The turning point of macroscopic properties appeared at 1 wt% organoclay content. Before this point, the effect of organoclay can be negligible, and the increase of chain mobility was ascribed to the decrease of molecular weight of polymer chains, as commonly occurs during dynamic melt processing; after this point, however, a reduced mobility of chains and a retarded chain relaxation were observed and attributed to the formation of a mesoscopic filler network. The essential features of such a mesoscopic organoclay network were estimated and discussed on the basis of stress relaxation and structural reversion measurements. A schematic model was proposed to describe the different relaxation and motion behaviors of macromolecular chains in the unfilled polymer and the filled hybrids with partial and percolated organoclay networks, respectively.     

Investigating Modern‐Day Talaria: Mobile Phones and the Mobility‐Impaired in Singapore

Revisiting the medical and social models of disability, this study adopted the integrated biopsychosocial approach to examine experiences of 25 mobility‐impaired respondents in Singapore with using mobile phones. We found that mobile phones provided respondents a greater degree of mobility, a sense of control, and opportunities to escape the stigma of disability, thus challenging the boundaries between the able‐bodied and the disabled. Mobile phone appropriation allowed the management of personal identities and social networks, leading to a sense of empowerment. However, mobile phone usage might act as a double‐edged sword for disabled people, creating mobile dependencies and a spatial narrowing of social connections. Theoretical and practical implications are discussed.