如何提高预焙铝电解槽阳极质量

预焙阳极的质量已严重制约铝电解技术的发展，必须予以足够的重视．国外在提高阳极质量方面的有效措施，可以供国内阳极工厂技术改造及科研攻关借鉴．     

NCO含量对聚氨酯-丙烯酸酯复合乳液性能的影响

以甲苯二异氰酸酯(TDI-80)、聚醚二元醇(N210)、二羟甲基丙酸(DMPA)和甲基丙烯酸甲酯(MMA)为主要原料，采用原位乳液聚合法，合成聚氨酯-丙烯酸酯(PUA)复合乳液。在保证DMPA含量、中和度等不变的情况下，研究了NCO／OH物质的量之比对乳液的性能及外观的影响。     

Binder effect on cycling performance of silicon/carbon composite anodes for lithium ion batteries

The cycling performance of a silicon/carbon composite anode has been significantly enhanced by using acrylic adhesive and modified acrylic adhesive as binder to fabricate the electrodes for lithium ion batteries. The capacity retentions of Si/C composite electrodes bound by acrylic adhesive and modified acrylic adhesive are 79% and 90% after 50 cycles, respectively. These two binders are electrochemically stable in the organic electrolyte in the working window. They also show larger adhesion strength between the coating and the Cu current collector as well as smaller solvent absorption in the electrolyte solvent than polyvinylidene fluoride (PVDF). Furthermore, sodium carboxyl methyl cellulose (CMC) plays an important role on improving the properties of acrylic adhesive, which increases the adhesive strength of acrylic adhesive and improves the activation of the electrodes.     

Quadratic control of stochastic hybrid systems with renewal transitions

We study the quadratic control of a class of stochastic hybrid systems with linear continuous dynamics for which the lengths of time that the system stays in each mode are independent random variables with given probability distribution functions. We derive a condition for finding the optimal feedback policy that minimizes a discounted infinite horizon cost. We show that the optimal cost is the solution to a set of differential equations with unknown boundary conditions. Furthermore, we provide a recursive algorithm for computing the optimal cost and the optimal feedback policy. The applicability of our result is illustrated through a numerical example, motivated by stochastic gene regulation in biology.     

锂离子电池层状LiMnO2正极材料的研究进展

论述了锂离子电池层状LiMnO2正极材料的结构、性能、制备、存在的问题和掺杂改性等方面的研究状况,讨论了今后层状LiMnO2的研究趋势.     

Delay time compensation based on coefficient of restitution for collision hybrid motion simulator

A hybrid motion simulator embeds a hardware experiment in a numerical simulation loop. However, it is often subjected to the inherent problem of an energy increase in the collision of two pieces of hardware in a loop because of the delay time. This paper proposes a delay time compensation method based on contact dynamics model for a collision hybrid motion simulator under delay time and establishes a compensation method for coupled translational and rotational motion. The model developed in this paper describes linear uniform motion of a floating object during the period of the delay time until the force and torque are observed and non-linear motion according to environmental stiffness after the initial delay time period in contact. By using the above model, compensation parameters are designed based on desired coefficient of restitution with iterative calculation. The proposed method achieves accurate delay time compensation and simultaneously realizes a variable desired coefficient of restitution over a wide range of frequencies. Furthermore, the compensation method for multi-dimensional motion is established under the assumption that the friction effect is very small. The efficiency of the proposed method is verified through collision experiments for the coupled motion in two dimensions.     

Characterization of poly(vinyl pyrrolidone‐co‐isobutylstyryl polyhedral oligomeric silsesquioxane) nanocomposites

Poly(vinyl pyrrolidone‐co‐isobutyl styryl polyhedral oligomeric silsesquioxane)s (PVP–POSS) were synthesized by one‐step polymerization and characterized using FTIR, high‐resolution ¹H‐NMR, solid‐state ¹³C‐NMR, ²⁹Si‐NMR, GPC, and DSC. The POSS content can be controlled by varying the POSS feed ratio. The T_g of the PVP–POSS hybrid is influenced by three main factors: (1) a diluent role of the POSS in reducing the self‐association of the PVP; (2) a strong interaction between the POSS siloxane and the PVP carbonyl, and (3) physical aggregation of nanosized POSS. At a relatively low POSS content, the role as diluent dominates, resulting in a decrease in T_g. At a relatively high POSS content, the last two factors dominate and result in T_g increase of the PVP–POSS hybrid. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2208–2215, 2004     

Mechanical,flow, and morphological properties of talc‐ and kaolin‐filled polypropylene hybrid composites

Polypropylene (PP) hybrid composites have been produced by compounding two types of mineral fillers, viz., talc and kaolin with PP copolymer using a twin screw extruder. The PP hybrid composite was injection‐molded into dumbbell specimen for tensile, flexural, and impact properties characterizations. MFI and SEM studies were used to characterize the flow and morphological properties of the PP hybrid composites. The result shows that most of the hybrid composites showed a significant decrease in flow, tensile, flexural, and impact properties compared with the single filler‐filled PP composites. However, a hybridization effect was seen for the PPT20K10 hybrid composites, through the synergistic coalescence of positive characteristics from 20 wt % of talc and 10 wt % of kaolin. This hybrid formulation have given an economically advantageous material with the mechanical properties (tensile, flexural, and impact) comparable to those of the talc‐filled PP composites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 434–441, 2007     

A polyamide-silica composite prepared by the sol-gel process

Summary A new kind of organic-inorganic hybrid composite was prepared by means of the sol-gel process. The polymer employed was a mixed-isomer aromatic polyamide having good solubility and thermal stability. The silica constituting the inorganic phase was produced by the hydrolysis and condensation of tetramethoxysilane. The bonding between the phases involved aminophenyl-trimethoxysilane, in which the amino group can react with the phthaloyl chloride end-capped polymer, and the methoxysilane groups undergo hydrolysis. The composition of these composites was varied by changing the linear polymer chain length and relative amount of tetramethoxysilane. The gelation time was found to range from a few minutes to several days. Thermogravimetric analyses showed that decomposition starts at approximately 450 °C. Thin films cast from materials having a relatively high silica content were opaque and rigid, but those with low silica content were flexible and transparent.     

灰色—支持向量机的空调负荷预测

对空调负荷进行准确预测不仅对空调优化控制的意义重大,而且也是实现空调经济运行与节能的关键所在。为了提高建筑空调负荷的预测精度,在分析灰色模型和支持向量机建模特点基础上提出了一种空调负荷组合预测算法。该方法综合了灰色建模计算过程简单以及支持向量机自学习和泛化能力强的优点,能够更加有效地利用样本数据的有效信息,提高模型预测精度。首先,通过灰色建模过程弱化了样本数据的随机因素。然后,对灰色模型输出进行归一化处理及数据重构,以作为支持向量机的输入。最后,通过支持向量机模型的预测得到最终预测结果。将本文所提出的方法应用于福州一栋办公建筑的逐时空调负荷预测中,并与灰色模型及支持向量机模型作比较,证明了组合模型的预测值与实际运行值拟合度最高,平均绝对误差比灰色模型和支持向量机模型分别降低了47.84%和17.39%。该组合预测模型具有较高的预测精度和更好的泛化能力,具有较强的可行性和实用性。