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121.
122.
Rafael S. Pinto João P. Serra João C. Barbosa Renato Gonçalves Maria M. Silva Senentxu Lanceros-Méndez Carlos M. Costa 《大分子材料与工程》2021,306(11):2100372
Considering the high levels of materials used in the fields of electronics and energy storage systems, it is increasingly necessary to take into consideration environmental impact. Thus, it is important to develop devices based on environmentally friendlier materials and/or processes, such as additive manufacturing techniques. In this work, poly(vinylidene fluoride) (PVDF) and poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) are prepared by direct-ink-writing (DIW) by varying solvent evaporation temperature and fill density percentage. Different morphologies for both polymers are obtained, including dense films and porous membranes, as well as different electroactive β-phase content, thermal and mechanical properties. The dielectric constant and piezoelectric d33 coefficient for dense films reaches up to 16 at 1 kHz and 4 pC N−1, respectively for PVDF-HFP with a fill density of 80 and a solvent evaporation temperature of 50 °C. Porous structures are developed for battery separator membranes in lithium-ion batteries, with a highest ionic conductivity value of 3.8 mS cm−1 for the PVDF-HFP sample prepared with a fill density of 100 and a solvent evaporation temperature of 25 °C, the sample showing an excellent cycling performance. It is demonstrated that electroactive films and membranes can be prepared by direct-ink writing suitable for sensors/actuators and energy storage systems. 相似文献
123.
Wei Zhang Chang Ma Ling-Zhi Huang Wen-Yan Guo Dan-Dan Li Jing Bian Ming-Guo Ma 《大分子材料与工程》2021,306(12):2100549
Conductive hydrogels have received widespread attention in the applications of biosensors, human–machine interface, and health recording electrodes. Herein, the conductive hydrogels integrated with antifreezing, water retention, reusable, and sensing performances are fabricated by introducing polyvinyl alcohol, cellulose nanofibril, MXene nanosheets, and glycerol. The as-prepared hydrogels present prominent electrical conductivity (2.58 mS cm−1) and flexibility even at −18 °C. In addition, the hydrogels have favorable water retention performance and can reuse after heating and cooling. When used as sensors, the hydrogels illustrate high sensitivity (gauge factor of 2.30), fast response time (0.165 s), wide working strain range (559%), favorable linearity (R2 = 0.999), and wide operating temperature range (−18 to 60 °C). The hydrogels can detect not only large strains of 10–200%, but also small strains of 1–5%, making them promising candidates for wearable sensors to monitor large and subtle movements. 相似文献
124.
采用液相氧化法制备二氧化锡纳米颗粒,并利用浸渍法制备Pd负载二氧化锡纳米材料,通过丝网印刷得到气敏传感膜并在其表面印刷分子筛层。基于动态气敏测试系统探究传感器对甲烷气体的灵敏度及其在CO和乙醇干扰气体下的选择性。研究结果表明,在Pd-SnO2敏感层表面印刷Pd-HZSM5层后,传感器对甲烷的响应能力显著提高,并且在体积分数为5×10-4的CO存在时,对甲烷的选择性也得到明显的提升。同样,在质量分数为2×10-5乙醇的存在下,传感器对甲烷的响应也没有受到干扰。通过对分子筛进行表征和催化分析,发现Pd-HZSM5对CO的催化效率可达100%,使得CO在扩散过程中被催化氧化,这可能是印刷Pd-HZSM5分子筛膜从而提高传感器选择性的主要原因。同时研究还表明,在敏感层表面印刷分子筛层并不会影响传感器的响应和恢复速率。 相似文献
125.
Margarida Taborda Duarte H. Y. Liu S. Q. Kou P. -A. Lindqvist K. Miskovsky 《Journal of Materials Engineering and Performance》2005,14(1):104-111
The importance of the microstructural parameters in rock mechanical behavior has been investigated by several authors. Moreover,
the Weibull statistical model has been used to characterize the heterogeneity of several materials on the basis of the concept
that the microscopic defects within the material determine their mechanical strength. The modeling of different rocks is a
topic that is fundamental for the prediction of rock fragmentation. In this article, the analysis of rock microstructure is
performed using the microstructural modeling approach, which consists of the simplification, quantification, and modeling
of the main properties of rock microstructure. The grain size, grain shape, and microcracks are modeled by means of statistical
density functions, namely, Cauchy, chi-squared, exponential, extreme value, gamma, Laplace, normal, uniform, and Weibull.
It is found that the Weibull distribution is the most appropriate statistical model of the grain size and grain shape, when
compared with the other eight statistical models. Regarding microcracks, the results show that the gamma distribution is the
most appropriate model. The Weibull and gamma distributions are then used to analyze the heterogeneity of the microstructure.
This is done by comparison of the statistical models of each microstructural property evaluated in several thin sections of
the same rock. It is found that with respect to grain size and grain shape, the rock is homogeneous, while the size distribution
of the microcracks shows a clear trend toward less homogeneity. The microstructural modeling approach is important for modeling,
characterizing, and analyzing the microstructure of rock material. Among other applications, it can be used to explain differences
in the mechanical behavior obtained in testing several specimens. 相似文献
126.
剖析网络评价文本能为景观规划设计提供科学的依据支撑,弥补因快速城镇化建设发展而导致的公众参与不足,对于景观设计而言是非常重要的。以重庆市弹子石老街为例,基于网络文本内容分析法,利用rostcm6、excel及python等分析和数据抓取软件,采集大众点评的相关评论数据,以山地景观设计视角结合相关数据分析软件进行定性定量分析并制作可视化分析图,最终从多维度分析游客评论得出结果及改进建议,总结针对重庆弹子石老街及山地景观设计的6条设计策略:(1)交通可达的组织方式;(2)垂直上下的衔接转换;(3)对景远眺的外向空间;(4)本土文化的特色彰显;(5)城市事件的策划安排;(6)游览夜景的慢行系统,期望对今后的类似山地景观空间规划设计提供一定参考和借鉴价值。 相似文献
127.
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129.
研究了煤块的Harr小波变换和幅度投影分析,在对原始图像进行特征判别分析的基础上,建立了煤块和煤矸石的统计模型,提出了用Bayes判别函数分选煤块和煤矸石的算法,实现了用计算机视觉系统对样本进行了识别检验.并运用神经网络BP算法进行训练识别,检验其正确性,最后通过实验验证了算法有效性. 相似文献
130.
Chengjun Yao Yixun Liu Jianhua Yao Dongxiao Zhuang Jinsong Wu Zhiyong Qin Ying Mao Liangfu Zhou 《Computer methods and programs in biomedicine》2014