Corrosion resistance of poly p-phenylenediamine conducting polymer coated 316L SS bipolar plates for Proton Exchange Membrane Fuel Cells

The usage of conducting polymers as coating materials for bipolar plates to prevent corrosion is the recent trend in Proton Exchange Membrane Fuel Cell (PEMFC) technology. Paraphenylenediamine (pPD) monomer was electropolymerized to poly p-phenylenediamine (PpPD) over 316L SS. The characterization of PpPD, the conducting polymer coating, over 316L SS was done using attenuated total reflectance infra-red (ATR-IR) spectroscopy to confirm the formation of PpPD. The surface morphology and topography were studied by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The corrosion protection performance of the coating was evaluated using open circuit potential (OCP) measurement, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization studies in PEMFC environment. EIS studies revealed that the charge transfer resistance for the coated substrates has increased by one order of magnitude than the bare substrate. Potentiodynamic polarization studies have registered lower corrosion current density by one order magnitude for the 0.06 M pPD coated substrate than the bare substrate and the polarization resistance values for the coated substrates have increased by two and a half time than the bare substrate. These results showed that PpPD coated substrates exhibited enhanced corrosion resistance in PEMFC environment.     

不同产地坡缕石粘土对高吸水树脂吸水性能的影响

以玉米秸秆,丙烯酸,不同产地坡缕石粘土为原料合成复合高吸水树脂MS-g-PAA/PGS。通过红外光谱,X射线衍射,扫描电镜和热重分析来研究坡缕石粘土的结构和形态。通过红外光谱和扫描电镜对复合高吸水树脂形貌及结构进行了表征。研究了各地坡缕石粘土形态,结构及组成对高吸水树脂吸水保水性能的影响.结果显示添加靖远坡缕石粘土的复合高吸水树脂有着最佳吸水保水性能。     

热丝化学气相沉积法制备钛基 BDD 电极及苯酚降解性能研究

目的研究硼掺杂对改善金刚石膜的电阻率的影响,制备掺硼金刚石膜。方法采用热丝化学气相沉积系统,以CH4,H2,(CH3O)3B混合气体为反应气,在钛片衬底上沉积制备掺硼金刚石膜电极。对不同生长阶段沉积出的电极进行扫描电镜、EDX光电子能谱、激光Raman光谱、X射线衍射、电化学性能表征及废水降解应用研究。结果制备出的掺硼金刚石膜呈现出均匀的(111)晶面,Raman光谱图中金刚石特征峰与硼原子特征峰峰型显著,具有较低的背景电流和更宽的电位窗口(3.5 V),对苯酚废水COD降解效果显著。结论有机污染物的吸附量与电极表面的粗糙度正相关,实验室制备的BDD/Ti电极表面粗糙度小,不利于析氢和析氧等副反应的发生,能降低直接电化学氧化作用,从而得到更宽的电势窗口。     

Evaluation of Some Nonionic Surfactants Derived From Vanillin as Corrosion Inhibitors for Carbon Steel During Drilling Processes

Four eco‐friendly nonionic surfactants based on vanillin were investigated as corrosion inhibitors against carbon steel dissolution during the drilling process in the oil field. The corrosion inhibition efficiencies of the tested compounds were determined using weight loss, electrochemical polarization, and electrochemical impedance techniques. The data obtained show that the nonionic surfactants prevent the corrosion of drilling tools and their inhibition efficiency increased with an increase in their concentration. Tafel curves revealed that the surfactants under study act as mixed inhibitors. The adsorption of the inhibitors on carbon steel surface decreases the double‐layer capacitance. The inhibition efficiencies of the surfactants were influenced by their chemical structure and surface activity.     

天然气管道泄漏扩散云团光谱检测研究进展

天然气管道泄漏易造成环境污染、爆炸等事故,目前检测天然气管道泄漏方法众多,而光谱检测技术具有非接触、快速、可高空测量等优点受到行业人士的关注。首先分析了天然气管道光谱检测技术特点,然后综述了天然气管道光谱检测技术涉及到的天然气管道泄漏扩散特性和天然气光谱性质,论述了现有研究的不足以及发展趋势。     

变压器供电系统电动机启动电压降计算

简介与变压器供电系统电机启动电压计算有关的参数和概念;运用"功率法"和"阻抗法"对工程案例进行计算;对工程设计中常遇到的问题进行讨论。     

不同裂缝尺度下水泥净浆的交流阻抗特性研究

在论述交流阻抗谱法(ACIS)在水泥净浆裂缝检测中应用的可行性基础上,基于电化学原理和Randles电路,提出了描述带裂缝水泥净浆试件ACIS行为的等效电路模型.以预设不同长度裂缝的水泥净浆试件和无裂缝水泥净浆试件为研究对象,基于交流阻抗谱技术,将钢筋作为电极,测试了各组试件在变化频率的正弦波脉冲作用下的电压信号峰峰值,计算了相应的阻抗幅模量,用试验数据对等效电路模型进行了验证.研究表明,有、无预设裂缝水泥净浆试件的阻抗幅模量差异明显,基于交流阻抗谱来检测水泥净浆内部裂缝是可行的;阻抗特性值与裂缝长度之间存在量化关系.     

基于自适应虚拟阻抗和相位补偿的改进下垂控制

由于微网中线路阻抗呈非纯感性,且线路阻抗与分布式电源容量不匹配,导致有功功率和无功功率之间强耦合且功率不能按容量进行分配。文中在利用下垂控制时,在传统虚拟阻抗的基础上进行改进,提出了一种自适应虚拟阻抗控制策略,降低了功率之间的耦合关系,并可使无功功率按容量分配。但由于下垂控制的特性和虚拟阻抗的利用,导致了电压和频率的偏移,因此增加了电压补偿控制和改进的相位补偿控制,使输出电压、相位、频率均和参考值一致,最后通过小信号稳定性分析和仿真验证了文中所提控制策略的合理性和有效性。     

基于改进型虚拟同步发电机的功率控制

针对传统虚拟同步发电机(Virtual Synchronous Generator,VSG)控制中逆变器输出阻抗和线路阻抗不同而引起的功率环流问题,提出一种改进型虚拟同步发电机功率控制方法。首先,在VSG电磁方程中引入虚拟电抗,解决低压线路阻抗模型中阻性成分带来的功率耦合问题,使得逆变器输出功率能够独立控制。其次,在VSG励磁控制器中附加公共连接点电压(Voltage at the Point of Common Coupling,VPCC)调节器,抑制因线路阻抗不同而引起的无功环流,并可在负荷突增情况下维持VPCC稳定。最后在孤岛运行的低压微电网中进行了仿真,仿真结果证明了该控制策略的可行性与有效性。     

六导联胸部阻抗图的初步探讨

目的探讨六导联胸部阻抗图的波形和波幅。方法用12个电压电极和3个电流电极组成的六导联方式测量63例正常健康成人的胸部阻抗容积图,按性别分组统计测量结果。结果各导联阻抗波的基本形态相似,基础阻抗Z0、C波幅度△ZC基本一致（P〉0.05）;第1导联（E1-E1′）的V波幅度△ZV和比值V/C最大,而第4导联（E4-E4′）的最小,两者比较差异有显著性（P〈0.01）;第1导联（E1-E1′）的FT最小,而第5导联（E5-E5′）的最大,其中男性组差异有显著性（P〈0.05）,女性组差异无显著性意义（P〉0.05）;女性的Z0、△ZC均显著地高于男性（P〈0.05）。结论六导联胸部阻抗图可为心阻抗图波形重建提供原始数据。