凝胶成型法制备加氢催化剂载体的研究与工业化生产

采用凝胶成型法制备加氢催化剂载体，并进行了工业放大试验。通过BET、NH3-TPD、H2-TPR等表征手段及实际的加氢反应性能评价对凝胶成型法制备的载体及加氢催化剂与常规方法进行对比分析，结果表明，采用凝胶成型法所制得的载体及催化剂均具有较高的孔体积和比表面积、较低的堆密度，其机械强度可满足工业要求，总酸量及中强酸酸量得到提升，催化剂活性组分与载体强结合力得到削弱，金属利用率提高，应用性能明显优于传统方法制备的加氢催化剂载体。通过该方法完成了加氢催化剂载体的工业生产，所生产的载体应用于天津院THDS-3加氢精制催化剂取得了良好的工业应用效果。     

Measurement Problems in Optical Monitoring Systems

A probabilistic image model is proposed. According to the model, the noise of the boundaries has the principal effect on the precision with which the dimensions of optical monitoring objects are measured. Results of theoretical and experimental investigations of measurement precision are presented. An approach to the determination of monitoring reliability and the selection of the resolution of a machine vision system based on structural requirements is formulated.     

线光栅扫描实现衍射图形的矢量化直写

在双光束激光直写系统中,衍射光变图像的光刻是逐像素点进行的.本文提出在该系统中采用狭缝获得光栅线来进行衍射图形的直写,利用一种改进的矢量文件格式,使平台沿着垂直光栅线的方向运动,获得连续的多光点同时直写,直写后的衍射光栅线是连续的,系统的运行效率是逐点光刻的几十倍.编写了与DXF文件的接口直写控制程序,给出了实验结果.     

DXDK-70型包装机常见故障分析处理

我公司使用天津华特DXDK-70型包装机4台，在生产中出现的主要问题及解决方法作了详尽阐述，以供同行探讨。     

一种有效的并行汉字／字符串相似检索技术

本文提出了一种有效的并行汉字／字符串相似检索技术．通过引入搜索状态向量及字符一模式匹配向量，该技术将字符串匹配比较转化为简单的整数字位运算，通过对字符串方向相反的搜索有效地实现了多处理机对汉字／字符串的并行相似检索．文中也给出了并行实现算法，同时分析了算法的复杂性．     

中低速率语音波形编码

提出了一种波形编码的新方法，阐述了其编码原理。该编码算法简单，恢复的语音质量较好。由于利用了矢量量化技术，所以该编码速率较低。     

辊式拉拔模用于连续拉拔机组的新技术

针对进口连续拉拔机组，独创设计了可配套使用的二连式辊模，并首次很好地解决了惯用模在辊模后的安装问题，是一种很有前途的新技术。     

青霉素发酵过程的智能优化控制

本文在分析青霉素发酵补糖工艺的要求和存在的问题基础上,设计出智能控制算法,采用集散系统实现在线优化控制,经实际应用,效果明显。     

Nitric oxide reduction and carbon monoxide oxidation over carbon-supported copper-chromium catalysts

Carbon supported copper-chromium catalysts are shown to be very active for both the reduction of nitric oxide with carbon monoxide and the oxidation of carbon monoxide with oxygen. Mixed copper-chromium oxide active phases have good activity in the simultaneous removal of nitric oxide and carbon monoxide from exhaust gases. The influence of several catalyst variables has been investigated. The activity per volume of catalyst increases with increasing loading, while the intrinsic activity shows a maximum around C/M=100−50. An optimum catalyst for nitric oxide reduction and carbon monoxide oxidation has a copper/chromium ratio of 2/1. The apparent activation energy for the carbon monoxide oxidation over carbon supported copper-chromium catalysts is 77 kJ/mol, suggesting that the Cu---O bond rupture is the rate-limiting process. The reduction of nitric oxide takes place at higher temperatures. Since all catalysts have a low selectivity for molecular nitrogen formation at lower temperatures, the dissociation of nitric oxide is probably rate determining, resulting in a slightly reduced catalyst system. In an excess of carbon monoxide the reaction is first-order in nitric oxide and zero-order in carbon monoxide. Moisture inhibits the reaction by reversible competitive adsorption, whereas carbon dioxide does not. Oxygen completely inhibits the reduction of nitric oxide due to the more rapid reoxidation of the catalytic sites compared to nitric oxide. Therefore, the reduction of nitric oxide takes place only when all oxygen has been converted and, hence, is shifted to higher temperatures. As a possible consequence, the production of nitrous oxide is reduced. Nitric oxide and molecular oxygen react preferentially with carbon monoxide, so, in an excess of oxidizing component, gasification of the carbon support occurs at higher temperatures after carbon monoxide has been completely consumed.     

LMG200型可调高滚筒式露天采煤机

介绍了可调高滚筒式露天采煤机的结构特点及在露天煤矿应用所产生的效益和其广 阔的发展前景。