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41.
Alexandre Szklo Giovani Machado Roberto Schaeffer Jacqueline Mariano Janaí na Sala Marina Tavares 《Catalysis Today》2005,106(1-4):123-128
This paper assesses the impacts of a GTL plant on the expansion of Brazil's oil refining segment. The GTL plant (50,000 bpd) was sized to start up operations in 2015, producing diesel and naphtha through the indirect route (FT-synthesis). This plant will consume the non-associated natural gas production from the recent discoveries at the Santos Basin (around 419 Bm3), and the associated gas production from the Campos Basin. Both basins are located in the Southeast of Brazil, the most populated, rich and industrialized region of the country. Two different criteria for refinery expansion were simulated in order to meet oil product demand scenarios. Findings show that depending on the refinery expansion criteria considered GTL will play a fundamental hole to meet the oil product demand forecast to Brazil in the next 10 years. 相似文献
42.
Thin layers of ceria were deposited on the surface of mica platelets in solution. The reaction of such particles with hydrogen sulfide yields a red colored special effect pigment. The ceria layer reacts with H2S to produce a variety of sulfide and oxysulfide phases. The reaction path discovered in situ by time and temperature resolved X-ray diffraction is CeO2→CeS2→C-Ce2S3→Ce10S14O. The reaction itself is extremely variable depending on gas flow, heating rates and decomposition atmospheres. Effects on the thin film are recorded by scanning electron microscopy (SEM) and revealed a destruction of the layer once red Ce10S14O was formed. The product layer then reveals the typical nonwetting behaviour of a liquid on a surface. 相似文献
43.
K Madhusudan Reddy Sunkara V Manorama R.D.K Misra 《Materials Research Bulletin》2004,39(10):1491-1498
A comparative study of gas sensing behavior of nanocrystalline nickel ferrite synthesized by micro-emulsion and hydrothermal method to liquefied petroleum gas (LPG) is presented. Nanocrystalline nickel ferrite synthesized by hydrothermal method indicated higher electrical conductivity and gas sensitivity at low operating temperature compared to nanocrystalline nickel ferrite synthesized by reverse micelle technique. This difference in the gas sensing behavior can be attributed to the presence of more oxygen vacancies (i.e. non-stoichiometry) in the hydrothermally synthesized nickel ferrite. Incorporation of palladium had a catalytic effect and the operating temperature was significantly reduced in both the samples. The higher operating temperature of the reverse micelle nickel ferrite material makes the sensor response speed faster (∼10 s) compared to the hydrothermally synthesized material (∼1 min). 相似文献
44.
The thick film of Zn-Sb-O was prepared by coating the paste of nanoparticles mixture (Sb2O3:ZnO=1:3) on the alumina substrate, followed by sintering at 500-900 °C for 2 h in air. The electrical resistance and gas-sensing properties to benzene, alcohol and acetone of Zn-Sb-O films were found to be dependent on the change of phase structure caused by sintering temperature. 相似文献
45.
介绍了钻孔灌注桩成孔质量的影响因素 ,详细叙述了钢筋笼的制作和吊放处理步骤 ,阐述了断桩发生的原因 ,提出了具体的防治措施 ,经实践效果良好 相似文献
46.
G. N. Churilov R. B. Weisman N. V. Bulina N. G. Vnukova A. P. Puzir L. A. Solovyov S. M. Bachilo D. A. Tsyboulski G. A. Glushenko 《Fullerenes, Nanotubes and Carbon Nanostructures》2003,11(4):371-382
The addition of metallic Ir and Pt to a fullerene-forming, atmospheric-pressure plasma reactor was found to influence the generation of carbonaceous products. It was observed that the added metals were efficiently dispersed into the plasma and that their presence increased the yield of fullerenes. The addition of Ir led to a noticeable shift in the fullerene distribution towards C60, whereas the addition of Pt increased the proportion of C60 oxides and decreased the proportion of higher fullerenes. Addition of Ir also caused a reduction of the soot particle size and the formation of a considerable quantity of carbon nanotubes. 相似文献
47.
Todd M. Alam Joshua U. Otaigbe Dave Rhoades Gregory P. Holland Brian R. Cherry Paul G. Kotula 《Polymer》2005,46(26):12468-12479
Nanostructured polymer blends prepared via anionic ring opening polymerizations of cyclic monomers in the presence of a pre-made polymer melt exhibit a number of special properties over traditional polymer blends and homopolymers. Here, we report on a simple and versatile method of in situ polymerization of macrocyclic carbonates in the presence of a maleic anhydride polypropylene (mPP) matrix and a surface-active compatibilizer (i.e. PC grafted onto a mPP backbone generated in situ) to yield a micro- and nanostructured polymer blends consisting of a polycarbonate (PC) minor phase, and a polypropylene (PP) major phase. By varying the processing conditions and concentration of the macrocyclic carbonate it was possible to reduce the size of the PC dispersions to an average minor diameter of 150 nm. NMR and TEM characterizations indicate that the PC dispersions do not influence crystal content in the PP phase. Overall, the results point to a simple strategy and versatile route to new polymeric materials with enhanced benefits. 相似文献
48.
周明 《徐州工程学院学报》2008,23(3):44-47
张仲谋教授的新著《宋词欣赏教程》,是南京大学出版社出版的“江苏省高等学校精品教材系列”中的一种。该书共8章,既构成一个严谨的教学体系,又多有创新出彩之处;对于词的艺术个性有深刻的把握和精当的阐发;又善于引导学生,循循善诱。该书既是教材,亦具有学术专著的品格。 相似文献
49.
Lei Liu Ying Kong Hong Xu Jin P. Li Jin X. Dong Zhi Lin 《Microporous and mesoporous materials》2008,115(3):624-628
A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO4-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P2O5-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO4-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO4-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn3(PO4)2 · 4H2O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO4-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C). 相似文献
50.
Mirna Suárez-Quiroz Béatrice De Louise Oscar Gonzalez-Rios Michel Barel Bernard Guyot Sabine Schorr-Galindo & Joseph-Pierre Guiraud 《International Journal of Food Science & Technology》2005,40(6):605-611
Roasting coffee led to a drop in the ochratoxin A (OTA) concentration, as measured by the reference method, especially for dark type roasts. The way the beverage was prepared also affected the OTA content, which could paradoxically be higher than that of the initial roasted coffee. Assays on the thermal stability of pure OTA showed that it ought to be found in larger quantities in roasted coffee. This suggested that OTA was masked by reactions with the substrate during roasting. The absence of OTA in green coffee is therefore the best guarantee of safety. 相似文献