高效空气电极的制备

空气极是整个空气电池中的关键所在，空气极的性能受着防水层的性能、催化层的性能、制备工艺等多种因素的影响．本实验对比了不同含量的聚四氟乙烯、活性碳颗粒等做成的防水层的特性及不同的催化剂(银粉、La-Ca-Co-O等催化剂)做成的催化层的特性．用电化学工作站研究了空气电极的析氧和氧还原特性，认为用碳酸氢铵为造孔剂、用银粉做催化剂的空气电极效果最好．     

Benchmark solution of imperfect angle-ply laminated rectangular plates in cylindrical bending with surface piezoelectric layers as actuator and sensor

The static and dynamic responses of simply supported adaptive angle-ply laminates in cylindrical bending are considered. The interlaminar bonding of the host elastic laminate is assumed to be imperfect, described by a spring-layer model, while the bonding between the host elastic laminate and the surface piezoelectric actuator and sensor layers is perfect. The state-space approach, which is directly based on the three-dimensional exact elasticity (piezoelasticity) equations and very effective in analyzing laminated structures, is employed. The numerical results should provide a useful means of comparison in the development of simplified analyses or numerical methods.     

南京市冬季市区和郊区晴天大气边界层结构对比分析

应用2008年12月24—31日南京市区和郊区同步大气边界层观测资料,对晴天大气边界层结构进行对比分析．结果表明：南京地区冬季晴天,市区近地面层气温高于江北郊区近地面层的气温,市区热岛效应明显,且热岛强度夜间大于白天;市区逆温出现的时间滞后于郊区,逆温层高度也大于郊区．夜间,市、郊区风速随高度不断增大,并在一定的高度出现一个8m／s的极值中心．市区空气相对干燥．通过典型日分析,市区14：00干岛效应显著,相同高度上相对湿度一直低于郊区．在市、郊区近地面层中,愈近地面风速愈小;近地面层中白天风速最大,夜间最小;白天,大气层结不稳定,湍流混合作用强,上下层风速的差别趋于减小．市区风速在低层受建筑物影响．相同高度上小于郊区风速．     

孔内深层超强夯法处理厚层人工回填土的应用研究

介绍了孔内深层超强夯法（SDDC）的基本原理,并将SDDC工法运用于处理某机场内厚层人工回填土地基,对无机固体废料进行了资源化回收利用。通过复合地基载荷试验、标准贯入试验和重型动力触探试验对SDDC施工质量进行检测,对SDDC桩体和桩间土的承载力效果进行评价。结果表明,经SDDC工法处理后的复合地基均匀性较好,承载力显著提高,达到工程使用要求。     

In-Situ Nitrogen Doping of the TiO2 Photocatalyst Deposited by PEALD for Visible Light Activity

In this paper, an N-doped titanium oxide （TiO2） photocatalyst is deposited by a plasma-enhanced atomic layer deposition （PEALD） system through the in-situ doping method. X-ray photoelectron spectroscopy （XPS） analysis indicates that substitutional nitrogen atoms （-395.9 eV） with 1 atom% are effectively doped into TiO2 films. UV-VIS spectrometry shows that the in-situ nitrogen doping method indeed enhances the visible-activity of TiO2 films in the 425-550 nm range, and the results of the performance tests of the N-doped TiO2 films also imply that the photocatalysis activity is improved by in-situ doping. The in-situ doping mechanism of the N-doped TiO2 film is suggested according to the XPS results and the typical atomic layer deposition process.     

熔融池氧化物层自然对流的数值模拟

本文以BALI试验段为对象建模,对其中有内热源的湍流自然对流流体进行了二维数值模拟。模拟工况的瑞利数Ra高达10¹²～10¹⁵。流体的湍流运动用大涡模拟模型来捕捉。通过对下边界局部热流密度的面积加权积分,计算了三维下边界换热量。结果表明,Ra对流场、温度场与下边界局部热流密度分布均有显著影响。计算所得上下边界的Ra-Nu关系与试验结果符合较好。对不同物理机理导致的下边界热流密度分布规律进行了分析。     

Temperature Dependence of Cobalt Release Rate from Stainless Steel in Neutral Water

In order to evaluate the release source of Co from heated tubes of the feedwater line of BWR, Co release rate measurements were carried out by measuring ⁶⁰Co released from irradiated stainless steel in contact with neutral water at an oxygen concentration of 20 ppb. The temperature- and time-dependences on Co release rate were studied for 670 h release experiments; the rate was found to decrease in proportion to t ^?frac12 (t ^?frac12 (t: exposure time) and to have its maximum value around 240°C. An empirical equation was obtained for the Co release rates in the temperature range of 150~240°C.

R_Co = 1.9 × 10⁶ exp (-14,300/(RT)) t ^?frac12

where R _co Co release rate (mg/(dm²·month)), R: Gas constant (cal/(mol·deg.)), T: Exposure temperature (K) and t: Exposure time (h). Decrease in the Co release rate with temperatures over 250°C, seemed to be ascribed to the formation of a protective oxide layer on the surface of stainless steel.     

D2、M2、S5模具扁钢脱碳特性实验研究

开展了在空气和氮气两种气氛下,采用Gleeble-1500热模拟机与普通电炉两种热方式、不同加热温度、加热时间对D2、M2、S5钢脱碳层深度影响的试验研究。依据试验结果,结合现场实际制定了较为合理的生产工艺并在现场成功应用,使上述模具扁钢脱碳层指标达到了美国ASTM－A681技术标准。     

正电子湮没研究Al、Nb共掺CaCu3Ti4O12陶瓷高介电常数机理

关于CaCu₃Ti₄O₁₂陶瓷的高介电常数机理,目前广泛接受的是非本征的内阻挡层电容模型。该模型认为在多晶中元素变价、缺陷和非化学计量比等导致的半导化晶粒被绝缘晶界层,即内阻挡层所包围。其中内阻挡层的厚度对材料的介电性能影响较大,而扫描电子显微镜（SEM）测试表明样品晶界呈稀烂的果酱状,SEM难以测量晶界区域绝缘内阻挡层厚度。本文采用正电子湮没技术表征其厚度,通过对CaCu₃Ti₄O₁₂陶瓷共掺不同浓度的Al、Nb（CaCu₃Ti_4-xAl_0.5xNb_0.5xO₁₂,x=0.2%、0.5%、5.0%）改变其晶粒和晶界的微观结构,研究CaCu₃Ti₄O₁₂陶瓷高介电常数机理。正电子湮没结果显示,掺杂样品符合多普勒展宽谱S参数的变化趋势与平均寿命的变化趋势一致。x=0.5%掺杂样品的介电常数最高,其平均寿命、S参数和湮没长寿命成分均最小,阻挡层最薄。实验结果验证了描述CaCu₃Ti₄O₁₂陶瓷高介电常数机理的内阻挡层电容模型的预测。     

Comparison between fluctuation of floating potential gradient and velocity of blob structure on HL-2A tokamak

Several results based on the Langmuir probes' data on the HL-2A tokamak are presented. The blob structures' radial and poloidal drift velocities, estimated by the gradient of floating potential and by time delay evaluation, are compared in different line-averaged density and electron cyclotron resonance heating conditions. A positive correlation is observed in the comparison between blobs' radial velocity estimated by the two methods mentioned above, regardless of the situation differences mentioned above. Correlation is also observed in the comparison between the blobs' poloidal velocity estimated by the two methods in different situations, while a shift due to the different line-averaged density is observed. These results imply that the radial gradient of floating potential may have some value as a reference during data analysis in low-parameter discharge.