一种高效的大功率宽带整流电路

提出了一种由π型匹配枝节、整流二极管、直通滤波器组成的高效大功率宽带整流电路。采用2只HSMS-282P肖特基二极管桥设计单级倍压整流电路,使电路在整流效率不下降的情况下提升输入的功率容量;采用π型匹配枝节实现阻抗匹配,使电路具有宽频特性,同时其并联短路枝节可以作为输入滤波器,实现小型化和整流效率的提高。直通滤波器用于抑制基频和二极管非线性产生的高次谐波,以提高整流效率。实测结果表示：在2.05~2.6 GHz带宽内整流效率大于60%;在2.45 GHz工作频率和35 dBm输入功率下,整流电路在330 Ω负载上获得70%的整流效率。该整流电路具有整流效率高、功率容量大、频带宽的特性,可为工程人员设计大功率微波整流电路提供设计指导。     

通信波段稀土离子掺杂固态量子存储进展

量子互联网是实现多方量子通信、分布式量子计算等量子信息技术的重要基础,量子存储器作为实现互联网的重要部件,对量子信息技术的发展、应用具有举足轻重的作用。如今遍布全球的光纤网络已经是信息传输的有力载体,通信波段的量子存储器因容易嵌入到当前的光纤网络中而备受重视。聚焦于稀土离子掺杂固态体系的通信波段光量子存储,首先介绍稀土离子掺杂固态量子存储的基本原理,包括稀土掺杂材料特性以及存储协议等,然后介绍目前的研究现状,最后简要分析其未来的发展趋势,并对量子互联网的构建做出展望。     

W波段64通道相控阵微系统设计与实现

相控阵微系统的主要特征是电路与天线的高度融合集成,将三维微纳集成技术和微电子技术紧密地结合在一起,切合相控阵高频化、小型化和低成本的发展需求。本文设计了一款W波段的封装天线相控阵微系统,该相控阵采用硅基三维集成的方式将T/R多功能芯片、天线阵列集成在一个微系统模块中,并详细介绍了基于硅工艺的多功能收发芯片设计和相控阵封装天线设计。给出了相控阵微系统的测试结果。该微系统具有高集成度、高性能、低成本的特点,可以为高速无线通信、高精度探测和成像等应用提供一个较优的技术路径。     

Engineering Bimetallic Ag–Cu Nanoalloys for Highly Efficient Oxygen Reduction Catalysts: A Guideline for Designing Ag‐Based Electrocatalysts with Activity Comparable to Pt/C‐20%

Development of highly active and stable Pt‐free oxygen reduction reaction catalysts from earth‐abundant elements remains a grand challenge for highly demanded metal–air batteries. Ag‐based alloys have many advantages over platinum group catalysts due to their low cost, high stability, and acceptable oxygen reduction reaction (ORR) performance in alkaline solutions. Nevertheless, compared to commercial Pt/C‐20%, their catalytic activity still cannot meet the demand of commercialization. In this study, a kind of catalysts screening strategy on Ag_x Cu_100?x nanoalloys is reported, containing the surface modification method, studies of activity enhancement mechanism, and applied research on zinc–air batteries. The results exhibit that the role of selective dealloying (DE) or galvanic displacement (GD) is limited by the “parting limitation”, and this “parting limitation” determines the surface topography, position of d‐band center, and ORR performance of Ag_x Cu_100?x alloys. The GD‐Ag₅₅Cu₄₅ and DE‐Ag₂₅Cu₇₅ catalysts alloys present excellent ORR performance that is comparable to Pt/C‐20%. The relationship between electronic perturbation and specific activity demonstrates that positive shift of the d‐band center (≈0.12 eV, relative to Ag) for GD‐Ag₅₅Cu₄₅ is beneficial for ORR, which is contrary to Pt‐based alloys (negative shift, ≈0.1 eV). Meanwhile, extensive electrochemical and electronic structure characterization indicates that the high work function of GD‐Ag₅₅Cu₄₅ (4.8 eV) is the reason behind their excellent durability for zinc–air batteries.     

Insights into the Influence of Work Functions of Cathodes on Efficiencies of Perovskite Solar Cells

Though various efforts on modification of electrodes are still undertaken to improve the efficiency of perovskite solar cells, attributing to the large scope of these methods, it is of significance to unveil the working principle systematically. Herein, inverted perovskite solar cells based on indium tin oxide (ITO)/poly(3,4‐ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS)/CH₃NH₃PbI₃/phenyl‐C61‐butyric acid methyl ester (PC₆₁ BM)/buffer metal/Al are constructed. Through the choice of different buffer metals to tune work function of the cathode, the contact nature of the active layer with the cathode could be manipulated well. In comparison with the device using Au/Al as the electrode that shows an unfavorable band bending for conducting the excited electrons to the cathode, the one with Ca/Al presents a dramatically improved efficiency over 17.1%, ascribed to the favorable band bending at the interface of the cathode with the active layer. Details for tuning the band bending and the corresponding charge transfer mechanism are given in a systematic manner. Thus, a general guideline for constructing perovskite photovoltaic devices efficiently is provided.