Hydrogen incorporation in Ni–P films prepared by electroless deposition

Electroless NiP films, with 12 to 16 wt % P, were deposited from a moderately acid solution. Thermogravimetric analysis indicates the presence of occluded hydrogen in the layers, which desorbs upon heating. The amount of incorporated hydrogen decreases when the pH of the solution or the nickel sulfate concentration is increased; by contrast it increases with hypophosphite concentration. Cyclic voltammetry, using an electrochemical quartz crystal microbalance, confirms the existence of parasitic reactions, namely the reduction of protons of the solvent during the cathodic process and oxidation of hydrogen during the dissolution of the layers. This behaviour is in qualitative agreement with the proposed reaction scheme.     

An efficient assumed strain element model with six DOF per node for geometrically non-linear shells

The present paper describes an assumed strain finite element model with six degrees of freedom per node designed for geometrically non-linear shell analysis. An important feature of the present paper is the discussion on the spurious kinematic modes and the assumed strain field in the geometrically non-linear setting. The kinematics of deformation is described by using vector components in contrast to the conventional formulation which requires the use of trigonometric functions of rotational angles. Accordingly, converged solutions can be obtained for load or displacement increments that are much larger than possible with the conventional formulation with rotational angles. In addition, a detailed study of the spurious kinematic modes and the choice of assumed strain field reveals that the same assumed strain field can be used for both geometrically linear and non-linear cases to alleviate element locking while maintaining kinematic stability. It is strongly recommended that the element models, described in the present paper, be used instead of the conventional shell element models that employ rotational angles.     

纵向零序电压保护新方案及其应用

由于结构设计的原因，综合性能较好的一些保护方案如横差保护和不完全纵差保护等将不能应用于大型超临界汽轮发电机。文中重点讨论了纵向零序电压保护方案的改进及其在应用中的问题。研究表明，发电机发生匝间短路故障时3次谐波电势减小，而机组外部故障时发电机3次谐波电势增大。因此，为了提高纵向零序电压保护方案的性能，可以根据故障时3次谐波电压增量的特性作为选取制动量的依据，从而提高保护性能。亦即:当3次谐波电压表现为负增量时，制动量取为0或接近0;而当3次谐波电压表现为正增量时，以该增量值作为制动量。此外，对匝间保护纵向零序电压元件增加一个小延时是可行的，它可以提高保护躲暂态3次谐波影响的能力。仿真计算表明，比例制动式纵向零序电压保护能可靠区分内外部故障，符合大型超临界汽轮发电机的保护要求。     

Quantity,controls and functions of large woody debris in Midwestern USA streams

Large woody debris (LWD) can increase stream habitat heterogeneity by providing structure, altering flow patterns, enhancing sediment deposition, forming pools and retaining organic matter. In North America, the role of LWD has been studied extensively in streams of mature forests (e.g. Pacific Northwest), but few studies have assessed LWD in streams of younger forests (e.g. Midwestern USA). Our objectives were to: (1) quantify the volume and abundance of LWD in a set of Midwestern streams; (2) evaluate possible factors influencing LWD quantity; (3) identify the functional roles of LWD; and (4) compare LWD levels in the upper Midwest to those elsewhere in North America. In 2002 and 2003, we measured LWD and geomorphological variables in 15 low‐gradient streams draining previously logged watersheds in the Upper Peninsula of Michigan. Mean (±SE) LWD volume (0.77 ± 0.12 m³ 100 m⁻²) and abundance (33 ± 3 pieces 100 m⁻¹) were 71% and 10% lesser, respectively, than in streams of similar gradient elsewhere in North America. Channel shape (width:depth ratio) explained 30% of the variation in LWD volume (multiple stepwise regression, P = 0.015) while LWD length and length:channel width combined, explained 72% of the variation in LWD density (multiple stepwise regression, P < 0.0001). About 50% of the LWD either stored sediment or stabilized banks and 14% of the LWD formed pools, although pool density was not significantly related to LWD volume or density. LWD levels, overall, were low in upper Midwestern streams, but the relative importance of that LWD to ecosystem function may be magnified in these wood‐poor systems. Copyright © 2006 John Wiley & Sons, Ltd.     

钢结构稳定设计——理论与实践

本文提出了实际工程结构的非线性理论设计和分析方法(NIDA),并以澳门回归纪念馆的设计为例,展示了本方法的优越性.在设计过程中,设计者无需假设K系数和有效长度,在结构分析完成后便可迅速完成设计,因此本文提出的方法既经济又便利.尽管对于钢框架在往复荷载及动力荷载作用下的弹塑性大位移分析已经非常成熟,但本文的方法开创了结构的非线性分析及设计的新纪元,能够对现行的设计方法理论起到巨大的推动作用.     

氟化活性炭纤维对极性分子的吸附

将活性炭纤维（ACF）与氟气反应制备出氟化活性炭纤维（FACF），根据将FACF与参照试样XPS的对比，碳原子是以sp^3杂化轨道同氟原子形成共健键。αs图分析氮吸附等温线的线果表明，ACF氟化后其比表面积和微孔容积都显著降低，微孔宽度基本不变，ACF的水吸附等温线呈V型，而FACF对水的吸附量极小；FACF的微孔表面具有完美的憎水性和高稳定性，乙醇和甲醇在ACF上的吸附等温线是Ⅰ型，在FACF上接近于Ⅰ型，但吸附量显著降低。     

蜂窝梁在大跨度走廊设计中的应用

介绍仪征化纤股份有限公司大跨度走廊中蜂窝梁的设计。     

大中型风力发电机组可靠性研究

研究了大中型风力发电机组的可靠性，讨论了可靠性指标的分配，可靠性设计的四个重要方面、可靠性试验计算机模拟。     

大型焦炉计算机优化控制系统

本文介绍一个大型焦炉计算机优化控制系统，它不仅实现了燃烧系统的ＤＤＣ控制，而且完成了结焦终点的在线预报和以焦炉能耗最小为目标的优化控制。     

大规模集成电路浮栅ROM器件总剂量辐射效应

提出了一种大规模集成电路总剂量效应测试方法:在监测器件和电路功能参数的同时,监测器件功耗电流的变化情况,分析数据错误和器件功耗电流与辐射总剂量的关系.根据该方法利用60Co γ射线进行了浮栅ROM集成电路(AT29C256)总剂量辐照实验,研究了功耗电流和出错数量在不同γ射线剂量率辐照下的总剂量效应,以及参数失效与功能失效时间随辐射剂量率的变化关系,并利用外推实验技术预估了电路在空间低剂量率环境下的失效时间.