改性催化裂化催化剂研究进展

对催化裂化催化剂的活性组分Y型分子筛的脱铝改性及抗重金属污染改性方法和改性后的含Y型沸石的性能进行了详细介绍。重点介绍了经特殊改性的催化裂化催化剂在脱硫、多产柴油及多产丙烯等方面的用途,指出应在现有技术基础上重点开发性能更为优良的多用途催化裂化催化剂。     

区域烧结法制备高温气体清洁用大尺寸陶瓷过滤管

用区域烧结在1 d内可完成高温气体清洁用1.5 m陶瓷过滤管的制备过程,区域烧结的优势是缩短研究和开发周期.目前,经过认真设计,已经完成区域烧结设备.多孔陶瓷件比致密陶瓷件更容易烧结成型,原因是多孔陶瓷在区域烧结期间可免除其收缩和变形.     

Synthesis of Sn-Incorporated Folded Sheets Mesoporous Materials (Sn-FSM-16)

Sn-incorporated folded sheets mesoporous materials (Sn-FSM-16) with various contents of Sn were synthesized by using a mixture of water glass, SnCl₄ and NaOH as starting materials. Hexadecyltrimethyl-ammonium chloride (surfactant) was used to intercalate into the layered silicate. The reaction process was followed by measurements of XRD patterns of intermediates. The Sn-FSM-16 was formed via the following mechanism: (1) layered silicates such as - - and -Na₂Si₂O₅ were formed as intermediates by the calcination of the mixture of the starting materials; (2) the surfactant was intercalated into the layered silicates; (3) the surfactant-silicate complex with hexagonal structure was obtained as a precursor of Sn-FSM-16; (4) the precursor was calcined to decompose the surfactant in the interlayer and was changed to Sn-FSM-16. The structural aspect of Sn in Sn-FSM-16 was studied by XPS profiles of Sn 3d _5/2 and Si_2p, ²⁹ Si MAS NMR and FTIR. The content of Sn in Sn-FSM increased with increasing concentrations of both Sn and NaOH in the starting materials. The surface area of Sn-FSM-16 decreased with an increase of Sn content in Sn-FSM (1160–620 m²/g).     

大面积水域浓度场测试方法及系统研究

针对大面积水域浓度场难以实现实时测量、测量精度不高等问题,采用了一种多通道荧光测试系统和方法。首先,基于单色光诱导荧光检测浓度(LIF)原理,使用探头获取离散点的浓度参数。然后,经总线或通信网络技术,将数百个测点连接起来。最后,通过数据总线或网络将采集的数据输送到中央测控计算机中,处理离散的数据后形成完整的浓度场。在恒定流浓度场中的试验结果表明,污染物测量相对误差均值不超过5%,单次测量相对误差最高值为8.33%,传感器线性度不超过5%,可检测的荧光素钠溶液浓度分辨率为0.001 ppm,系统测量稳定、精度较高。相较于其他浓度测量方法,该系统具有测量面积大、实时测量的优势,可为水污染防治等领域提供可靠的技术支撑。     

Geomorphic diversity as a river management tool and its application to the Ganga River,India

Understanding of geomorphic processes and the determination of geomorphic diversity in catchments are prerequisites for the sustainable rehabilitation of river systems and for reach‐scale assessment of river health. The Ganga River system in India is a large, complex system consisting of several long tributaries, some >1,000 km, originating from 2 distinct hinterlands—the Himalaya to the north and the cratons to the south. Traversing through a diverse climatic regime across the Plain and through precipitation zones ranging from 600 mm/year near Delhi to 1,200 mm/year in the eastern plains, the Ganga River system has formed very diverse landform assemblages in 3 major geomorphic domains. We have recognized 10 different river classes for the trunk river from Gangotri (source) to Farakka (upstream of its confluence with the Brahmaputra) based on (a) landscape setting, (b) channel and active floodplain properties, and (c) channel planform parameters. The mountainous stretch is characterized by steep valleys and bedrock channels and is dominated by large‐scale sediment production and transport through hill slope processes. The alluvial part of the river is characterized by 8 different river classes of varying reach lengths (60–300 km) many of which show sharp transitions in landscape setting. We have highlighted the application of this approach for the assessment of habitat suitability, environmental flows, and flood risk all of which have been significantly modified during the last few decades due to large‐scale anthropogenic disturbances. We suggest that the diversity embedded in this geomorphic framework can be useful for developing a sustainable river management programme to “work with” the contemporary character and behaviour of rivers.     

Synthesis of polyethylene oxide end‐capped with perfluoroalkyl groups/polystyrene prototype brushes

Polystyrene (PS)/poly(ethylene oxide) (PEO) prototype brushes were prepared by alternating free‐radical copolymerization of methacryloyl‐terminated PS and α‐vinylbenzyl‐ω‐hydroxy or α‐vinylbenzyl‐ω‐perfluoroalkyl (R_f) PEO macromonomers with the addition of Lewis acid (SnCl₄). It was found from their dilute‐solution properties that PS/PEO end‐capped with R_f (PBR_f), and PS/PEO having OH groups at terminal ends (PBOH) prototype brushes formed a single molecule in benzene and aggregates in chloroform, respectively. However, the brush PBOH formed a single molecule in N,N‐dimethylformamide. Such aggregation behaviors seemed to be caused by the interaction between hydroxy groups of PEO chain ends. The brush PBOH was also converted into PBR_f‐type brush by chemical modification, using corresponding acid chloride. The substitution of R_f groups was ～70% due to slipping of terminal hydroxy groups into PEO internal domains. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 772–778, 2006     

岩体结构面对大跨度隧道工程稳定性影响初步研究

基于对沈阳至大连（简称沈大）高速公路扩建工程韩家岭隧道区域调查和分析，研究了岩体结构面对隧道施工过程的影响，围岩失稳方式及可能遇到的问题，并提出了解决这些问题的措施。     

包结拆分在手性药物分离中的机理与应用

对外消旋体药物进行分离拆分是获取手性药物的重要方法。探讨了环糊精体系包结拆分法的机理，并对运用其机理于手性药物分离中的应用作了探讨。     

On the robust control of stable minimum phase plants with large uncertainty in a time constant. A fractional-order control approach

This paper addresses the problem of designing controllers that are robust to a great uncertainty in a time constant of the plant. Plants must be represented by minimum phase rational transfer functions of an arbitrary order. The design specifications are: (1) a phase margin for the nominal plant, (2) a gain crossover frequency for the nominal plant, (3) zero steady state error to step commands, and (4) a constant phase margin for all the possible values of the time constant (T$T$): 0<T<∞$0<T<\infty$. We propose a theorem that defines the structure of the set of controllers that fulfil these specifications and show that it is necessary for these robust controllers to include a fractional-order PI$PI$ term. Examples are developed for both stable and unstable plants, and the results are compared with a standard PI$PI$ controller and a robust controller designed using the QFT$QFT$ methodology.     

引水工程大流量渡槽结构型式选择

针对工程等级高、过水流量大、抗震设防要求高的引水工程,渡槽结构型式选择存在工程技术难题,根据引水工程渡槽槽墩较高、荷载大、结构断面大、沉降变形影响因素较为复杂特点,进行了渡槽支承型式、槽身截面形式、渡槽墩身的比选。结果表明:简支结构具有减少施工难度和不均匀沉降对槽体结构应力影响,简化结构受力条件,简支结构较为有利优点。空心重力墩具有节省材料,充分利用材料强度,刚度较大,墩身质量较轻,抗震能力和抗冲击强,高度较大优点,对类似工程设计具有参考意义。