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991.
M. Victoria Ruiz‐Mndez lvaro E. Ramos‐Hinojosa 《European Journal of Lipid Science and Technology》2003,105(7):346-350
Two‐phase decanter olive pomace (TPOP) is the by‐product of a centrifugation system, used to produce olive oil, that separates olive oil and moist pomace. The water content in these olive pomaces is about 70%, while it was 45‐50% in the olive pomace stemming from three‐phase systems (oil, water, and pomace) and 30% in the old press system. The aim of this work is focused on quantification and changes undergone during olive pomace storage in ponds of esters of fatty acids with short‐chain linear alcohols, which can be considered as a refining loss. The results indicate that oil deterioration increases very rapidly, in particular when oil is extracted from the TPOP surface. Special attention should be paid to the storage of TPOP, establishing a maximum of 2 months in all cases. 相似文献
992.
氯醇化管道反应新工艺是环氧丙烷生产过程中关键步骤,该反应属气液非均相系统,但装有Kenics型静态混合构件的管道反应器用于气液系统还缺乏大量的基础数据。研究以N2-H2O2作为实验系统,测定了不同工况下压降和氧含量,并应用一心均相模型救是了相应的摩擦系数和传质系数。 相似文献
993.
Wei Zhang Zhao-Jun Mo ZhiHong Hao Jun Shen Jia-Wei Luo Rui-Jiang Chang Lan Li 《International Journal of Applied Ceramic Technology》2019,16(4):1606-1611
The magnetic properties and magnetocaloric effect for EuTi1-xFexO3 (x = 0.05, 0.1) compounds are investigated. When a part of Ti4+ions were substituted by Fe ions, the AFM ordering can be significantly changed to be FM. The EuTi1-xFexO3 (x = 0.05, 0.1) compounds exhibit a PM to FM transition with decreasing temperature and the Curie temperature is 6 K. Under the field changes of 1 T, and RC are valued to be 10.1 J/kg K and 50.2 J/kg for EuTi0.95Fe0.05O3; 9.6 J/kg K and 47.7 J/kg for EuTi0.9Fe0.1O3, without magnetic and thermal hysteresis. RC is almost twice as much as EuTiO3 (27 J/kg) as substitution of Fe3+ ions for Ti4+ions, which may be attributed to the magnetic transition (AFM to FM). Therefore, the giant and large RC suggest the EuTi1-xFexO3 compounds are good materials for magnetic refrigerant. 相似文献
994.
To study the effect of the molecular architecture of a copolymer on its miscibility with corresponding homopolymers a series of block copolymers of styrene and isoprene with diblock, triblock and four-arm star architectures have been prepared and the morphologies of the blends of the copolymers and polyisoprene with different molecular weights have been examined by electron microscopy. The results show that miscibility varies in the sequence diblock>triblock>four-arm star copolymers. This sequence is in the opposite direction to the variation of the architectural complexity of the block copolymers, i.e. the more complex is molecular architecture, the greater is conformation restriction in microdomain formation and the less is solubility of homopolymer in corresponding domains. 相似文献
995.
A series of ethylene oxide(EO)-propylene oxide (PO) random co-polymers (EOPO) were used to form aqueous two-phase systems (ATPS) with ammonium sulfate.Effects of EOPO′s properties on the phase separation behaviors and on the partition of cephalexin and 7-aminodesacetoxicephalosporanic acid(7-ADCA) in ATPS were investigated.Both the molar mass and molar ratio of EO to PO of EOPO could greatly influence partition behaviors of cephalexin and 7-ADCA as well as the binodal curve of ATPS. With the increase of molar mass of co-polymer or the decrease of molar ratio of EO to PO,the critical point of ATPS decreased,the binodal curve became more asymmetry,and both cephalexin and 7-ADCA followed the same tendency to partition into the polymer-poor bottom phase.The experimental results shows that it is feasible to partition cephalexin and 7-ADCA in either the polymer-rich top phase or the polymer-poor bottom phase by choosing a specific phase-forming EOPO. 相似文献
996.
Studies on Macro-kinetics of Gas Phase Polymerization of Butadiene with Rare-earth Catalyst 下载免费PDF全文
The study of the kinetics of gas phase polymerization of butadiene with heterogeneous catalyst based on neodymium (Nd) was carried out. The effects of reaction temperature, reaction pressure, dispersing medium, and types of catalyst on kinetics of polymerization were investigated. A kinetic model with two kinds of active sites was proposed. The results show that the effects of the reaction temperature and the types of dispersing medium and catalyst on the kinetic performance of polymerization are significant, and that the combined model of first and second order decay of active site of catalyst can be used to describe the phenomena. 相似文献
997.
LiNi0.5Mn1.5O4 thin films were prepared by pulsed laser deposition (PLD) on stainless steel substrates. The growth of the films has been studied as a function of substrate temperature and oxygen partial pressure in deposition, using X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM). Electrochemical properties of LiNi0.5Mn1.5O4 thin film cathodes were investigated using cyclic voltammetry and galvanostatic charge/discharge against a lithium anode. The initial capacity and capacity retention of the films are highly dependent on the crystallinity and purity of the films. LiNi0.5Mn1.5O4 thin films grown at 600 °C in an oxygen partial pressure of 200 mTorr are well crystallized with high purity, exhibiting excellent capacity retention between 3 and 5 V with a LiPF6-based electrolyte. 相似文献
998.
Blends of statistical copolymers containing ethylene/hexene (PEH) and ethylene/butene (PEB) exhibited the behavior of upper critical solution temperature (UCST). The interplay between the early and intermediate stage liquid-liquid phase separation (LLPS) and crystallization of the PEH/PEB 50/50 blend was studied by time-resolved simultaneous small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD) techniques. Samples were treated by two different quench procedures: in single quench, the sample was directly quenched from 160 °C to isothermal crystallization temperature of 114 °C; while in double quench, the sample was firstly quenched to 130 °C for 20 min annealing, where LLPS occurred, and then to 114 °C. It was found that in the early stage of crystallization, the integrated values of Iq2 and crystallinity, Xc, in the double quench procedure were consistently higher than those in the single quench procedure, which could be attributed to accelerated nucleation induced by enhanced concentration fluctuations and interfacial tension. In the late stage of crystallization, some morphological parameters were found to crossover and then reverse, which could be explained by retardation of lamellar growth due to phase separation formed during the double quench procedure. This phenomenon was also confirmed by DSC measurements in blends of different compositions at varying isothermal crystallization temperatures. The crystal lamellar thickness determined by SAXS showed a good agreement with TEM observation. Results indicated that the early stage LLPS in the PEH/PEB blend prior to crystallization indeed dictated the resulting lamellar structures, including the average size of lamellar stack and the stack distribution. There seemed to be little variation of lamellar thickness and long period between the two quenching procedures (i.e., single quench versus double quench). 相似文献
999.
A novel macroporous resin was prepared from epoxy resin and triethylenetetramine through a polymerization with phase separation. In this experiment, the polyethylene glycol (PEG‐1000) plays a very important part. It was used as solvent, as phase‐separation reagent in the preparation processes, and as the pore‐forming reagent through removing PEG‐1000 from polymer by water‐cleaning process after completing polymerization. The prepared resin was modified by carbon bisulfide and soaked in 1 mol L?1 NaOH. Its structure was characterized by Fourier transform‐infrared spectra, scanning electron microscopy, and elemental analysis. The adsorption characteristic of the chelating resin was studied by series of experiments. The results show that the chelating resin possesses excellent adsorption characteristic toward trace Hg(II). The recovery can come to 100% when the concentration of Hg(II) is only 0.05 ppm, and the average maximum adsorption capacity of the chelating resin for Hg(II) is 122 mg g?1. The precision (relative standard deviation) for six replicate adsorbent extraction of 0.01 μg mL?1 Hg(II) was 1.1%. The accuracy of the proposed procedure was verified by analyzing a standard reference material. Moreover, the chelating resin was applied to two natural samples and also got satisfactory results. That is to say, the chelating resin modified by carbon bisulfide exhibits a high chelating ability toward Hg(II) and can be used as adsorbent for preconcentration and removal of trace Hg(II) in aqueous solution. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102:2372–2378, 2006 相似文献
1000.
Francesca Giuffrida Pierre‐Alain Golay Frdric Destaillats Bernadette Hug Fabiola Dionisi 《European Journal of Lipid Science and Technology》2005,107(11):792-798
Lipid oxidation has great impact on the quality of food products through flavor and taste deterioration, reduction in nutritive value, and potential toxicity of the oxidized food components. Flavor and taste deterioration can be easily perceived and it represents one of the major causes of consumer complaints in the food industry. The deterioration of sensory properties is due to the decomposition products of hydroperoxides that easily isomerize and degrade into volatile compounds. Volatile products are responsible for flavor and taste deterioration. In this study, we present the development of the solid‐phase microextraction gas chromatography‐mass spectrometry (SPME‐GC‐MS) technique to quantify low amounts (μg/g range) of secondary oxidation products, i.e. hexanal. The optimization of SPME parameters is a difficult task because of the possibility of further formation of volatile products during analysis. Different parameters such as type of fiber, exposure time of the fiber to the sample headspace and the optimal temperature of absorption have also been investigated. The complete validation of the method was achieved by the determination of linearity, limits of detection and quantification and repeatability. We demonstrated that the SPME method is a valuable tool for the quantification of low amounts of secondary oxidation products such as hexanal. Therefore, this technique can be used to detect early formation of volatiles. 相似文献