Structural and electrical properties of mixed oxides of manganese and vanadium: A new semiconductor oxide thermistor material

Binary oxides of manganese and vanadium have been synthesized by solid state sintering, in which the mass ratio of the individual components Mn₂O₃ and VO₂ have been varied from 90:10 to 5:95. The bulk ceramic samples were characterized by X-ray diffraction and scanning electron microscopy with energy dispersive X-ray analysis. The initial compositions either rich in Mn₂O₃ or in equi-proportion by mass with VO₂ yield β-Mn₂V₂O₇ or a new crystalline form of Mn₂V₂O₇, with unit cell parameters: a = 7.73091 Å, b = 6.640788 Å, c = 6.70779 Å α = γ = 90° and β = 98.7086° which is designated as γ-Mn₂V₂O₇. The compositions, richer in VO₂ produce MnV₂O₆ co-existing with V₂O₅ the proportion of which increases with increase in VO₂. The surface microanalysis shows a spherical-granular morphology in Mn₂V₂O₇ structure and plate/rod-like structures co-existing with granular morphology in case of MnV₂O₆ together with V₂O₅. The electrical parameters of the negative temperature coefficient thermistors were determined. Depending on the constituent oxide composition, the NTC thermistors showed room temperature resistivity in the range of 6.52 × 10² to 6.1 × 10⁶ Ω-cm. The thermistor constant and activation energy are in the range of 0.12–0.458 eV and 1393–4801 K, respectively.     

电能质量智能在线监测系统设计

论述了电能质量问题的内容及其对电力系统的影响,设计了一种基于嵌入式技术的电能质量在线监控系统,给出了系统的硬件结构图和软件结构图及流程图,进行了样机的功能性验证试验,证明该系统对于构成具有智能化的监控及通信系统具有一定的应用价值。     

金属化合物在分子筛上自发分散的研究进展

金属盐和氧化物在分子筛孔穴中及内外表面自发形成原子水平的分散,这种自发分散现象已被多种现代仪器分析所证实，并在国内外得到广泛认同。总结相关文献，结合部分研究工作，对金属化合物在分子筛上自发分散的研究作了综述。     

Machinability of Metal Matrix Composites Reinforced by 3-D Network Structure

Metal matrix composites reinforced by three-dimensional (3-D) continuous network structure reinforcement (3DCNRMMC) are difficult to machine due to serious tool wear and poor surface roughness caused by the brittle and hard reinforcement which interpenetrate into ductile matrix. In order to achieve the approach of low cost of 3DCNRMMC, the machinability of it needs to be understood. The influences of three cutting parameters and volume fraction of reinforcement on cutting force were analyzed in detail. The results indicate that: (1) Due to the brittle phase(s) introduced into ductile matrix of composites, there is a large fluctuation of cutting force causing deterioration of machinability. The fluctuation ranges of cutting forces, initially increase rapidly with the increase of volume fraction of reinforcement and then decrease finally, are largest at the range of the volume fraction of 55–65%; (2) The influence of cutting parameters on cutting force is obvious. With the increases of cutting speed, cutting force decreases gradually unless cutting speed exceeds the value of 209 m/min. Cutting forces increase with increasing feed rate and depth of cut; (3) Owing to the large fluctuation of cutting force, there were some cratered surfaces caused by Si₃N₄ reinforcement pulling-out and flaking-off. Some brittle phase protruding from the machined surface caused the deterioration of machined surface.     

New Application of Stainless Steel

Several rigid substrates such as stainless steel, titanium alloy, aluminum alloy, nickel foil, silicon, and sodium lime glass have been employed for manufacturing high quality TiO2 films by metal organic chemical vapor deposition （MOCVD）. The as-deposited TiO2 films have been characterized with SEM/EDX and XRD. The photocatalytic properties were investigated by decomposition of aqueous orange Ⅱ. UV VIS photospectrometer was employed to check the absorption characteristics and photocatalytic degradation activity. The results show that films synthesized on metal substrates display higher photoactivities than that on absolute substrates such as silicon and glass. It is found that solar light is an alternative to UV-light used for illumination during photodegradation of orange Ⅱ. TiO2 film on stainless steel substrate was regarded as the best one for photocatalysis.     

Heat regulating strategy in numerical control end milling for hard metal machining

The trend in die/mold manufacturing at present is towards the hard machining at high speed to replace the electron discharge machining. Failure forms of the A1TiN-coated micro-grain carbide endmill when used for the machining of/IS SKD61 (HRC 53), a widely used material in die/mold manufacturing, are investigated. The endmill shows a characteristic that tool life decreases greatly due to the chipping when overload occurs or the rapid increase of wear when over-heat accumulation in cutting edges. As a consequence of the investigation, a strategy to regulate heat generation in the end milling process is proposed. This is accomplished by controlling the cutting arc length, i.e. the length of each flute engaging workpiece in a cutting cycle. Case studies on the slot end milling and comer rounding are conducted. The results show that the proposed strategy suggests the optimal tool path as well as the optimal pitch between successive tool paths under the cutting time criterion.     

Process Modeling for Precision Forming of Discrete Parts – State of the Technology and Critical Issues

This paper presents an overview on the application of FE simulation as a virtual manufacturing tool in designing manufacturing processes for precision parts. The processes discussed include forging, sheet metal forming and hydroforming. Determination of reliable input parameters to simulate a process is a key element in successful application of process simulation for process design in all the mentioned areas. These issues are discussed in detail. Practical examples of application of FE simulation are presented for improvement of the existing metal forming process and/or designing new metal forming process for manufacturing discrete precision parts in forging, sheet metal forming and hydroforming.     

液态金属离子源发射系统电场的模拟分析

发射系统是液态金属离子源的关键部件之一，它的性能的优劣直接影响到整个离子源的工作稳定性和可靠性。因而对其发射系统进行仿真分析，可以很好地指导液态金属离子源的设计制造。本文采用国际上重视的动态喷流柱模型，利用模拟电荷法对液态金属离子源的发射系统的电场进行了计算分析，画出了发射尖端电场强度随不同参数变化的曲线，得出发射尖端表面场强与球冠半径、发射体突出臂长度密切相关，而与引出电极的结构关系甚小的结论，因此液态金属离子源发射特性（如角电流强度）的改善，必须在发射尖的设计制作上下功夫。从而为液态金属离子源的设计提供了一个有效的辅助工具。     

Stresses in bent copper tubing: Application to fatigue and stress-corrosion cracking failure mechanisms

The residual and applied stresses in u-bent copper tubing are addressed in the context of both cyclic fatigue and stress-corrosion cracking. Failures as a result of fatigue and stress corrosion cracking in u-bent copper tubing have been observed to initiate at nonintuitive locations when only the applied stresses on the component are considered. This paper presents both qualitative classical and quantitative finite-element stress analysis results for the forming of u-bends. The resulting residual stress distributions are compared to fracture patterns generated by both fatigue and stress-corrosion cracking mechanisms.