Increasing Heavy Metal Tolerance by the Exogenous Application of Organic Acids

Several metals belong to a group of non-biodegradable inorganic constituents that, at low concentrations, play fundamental roles as essential micronutrients for the growth and development of plants. However, in high concentrations they can have toxic and/or mutagenic effects, which can be counteracted by natural chemical compounds called chelators. Chelators have a diversity of chemical structures; many are organic acids, including carboxylic acids and cyclic phenolic acids. The exogenous application of such compounds is a non-genetic approach, which is proving to be a successful strategy to reduce damage caused by heavy metal toxicity. In this review, we will present the latest literature on the exogenous addition of both carboxylic acids, including the Kreb’s Cycle intermediates citric and malic acid, as well as oxalic acid, lipoic acid, and phenolic acids (gallic and caffeic acid). The use of two non-traditional organic acids, the phytohormones jasmonic and salicylic acids, is also discussed. We place particular emphasis on physiological and molecular responses, and their impact in increasing heavy metal tolerance, especially in crop species.     

用MasterCAM加工双金属材料链轮硬齿表面

运用MasterCAM软件对双金属材料链轮硬齿表面进行曲面三维造型,编程,并对链轮双金属材料硬齿表面进行曲面合理工艺设计,加工出了符合图纸要求的产品零件。阐述了MasterCAM软件在加工实例产品时编程的基本步骤,重点突出了其加工工艺和加工参数等关键问题。     

浅谈外墙外保温外饰面砖施工技术

结合工程实例从粘结机理、保温层受力情况、安全系数等方面进行了讨论,初步分析了墙体外墙外保温外饰面贴砖的安全性,提出了在施工中应采取的质量控制措施。     

现行焦炭强度指标在太钢高炉的适用性探讨

重点论述了焦炭反应性在高炉碱金属循环富集条件下的变化,并根据国内外研究提出的反应性会发生逆转的概念,分析了太钢高炉生产的实际情况,明确了现行焦炭强度指标对太钢高炉生产的指导意义。     

有色金属新材料项目风险管理探析

从安徽鑫科新材料股份有限公司面临的实际问题出发。通过建立系统模型,研究有色金属新材料项目的风险管理问题。     

金属铕制备工艺的研究

本文采用正交实验的方法,研究了金属铕的制备工艺条件。实验结果表明,还原－蒸馏温度１１００℃,还原剂过量系数０．３,保温时间１．５小时,金属铕的纯度大于９９．９％,直收率大于９０％     

Effects of Technical Conditions on Structure, Morphology and Crystalline Size of Nanocrystalline Nd-Doped Ceria Powders

Nanocrystalline solid solution CeO2-Nd2O3 powders were prepared by low temperature combustion process.Special attention was paid to the influence of the glycine/metal ratio and calcination temperature on the powders phase structure, morphology and particle size.TG-DSC curves and XRD peaks of different glycine/metal ratio show that smaller particle size can be obtained with a slightly fuel-deficient ratio.XRD results indicate that the as-prepared powders are crystallized in a single fluorite structure.The crystalline size ranges from 9 to 24 nm, which increases with the increase of calcination temperature.The lower SEM images were characterized by the spongy and form-like microstructure of the powders.Organic agent may be gradually eliminated by high temperature calcination process.     

4A和13X分子筛去除水中重金属Cd2＋及其吸附性能研究

以4A和13X分子筛为吸附材料,考察废水pH值和Cd2＋初始浓度等对Cd2＋去除率的影响,并研究了分子筛对Cd2＋的吸附性能。结果表明,4A和13X分子筛投加量为0．16 g/L、废水pH值为5、Cd2＋浓度为20 mg/L时,Cd2＋去除率达到95％以上;分子筛对Cd2＋的去除机理以离子交换吸附为主,交换出来的Na＋与分子筛吸附的Cd2＋摩尔浓度比为2;在吸附热力学和动力学方面,4A和13X分子筛均符合Langmuir吸附等温模型和Lagergren二级速率方程,计算的饱和吸附容量 Q0分别为150．15、163．67 mg/g ,二级反应速率常数K2分别为2．45＆#215;10-3、3．96＆#215;10-4 g/（mg ＆#183; s）。该吸附反应是一种单分子层反应速度较快的化学吸附过程。     

液态金属实验回路(LMEL)的总体设计和运行

液态金属实验回路（ＬＭＥＬ）是国内唯一用于聚变堆磁流体动力学（ＭＨＤ）效应和材料相容性研究的大型实验装置。与国外同类先进的装置相比，回路流程和运行方式均有重大改进，使其更先进、安全并具有多功能。回路运行分为两个阶段：第一阶段以钠－钾低共熔合金（２２Ｎａ７８Ｋ）为工质，研究ＭＨＤ效应，ＬＭＥＬ的最大哈特曼（Ｈａｒｔｍａｎｎ）数Ｍ和相互作用参数Ｎ分别为０．７５×１０４和２．５×１０４；第二阶段以液态锂为工质，研究结构材料与锂的相容性，最高温度和流速分别为５２０℃和１．３８ｍ／ｓ。