金属拱型屋面板的开发与应用

简要介绍了武钢Ｗ６６６金属拱型层面板的开发、设计、试验研究及应用情况,探讨了理论分析的方法和应用前景。     

Cobalt Ferrite Magnetic Nanoparticles for Tracing Mesenchymal Stem Cells in Tissue: A Preliminary Study

Therapy with mesenchymal stem cells (MSCs) is promising in many diseases. Evaluation of their efficacy depends on adequate follow-up of MSCs after transplantation. Several studies have shown that MSCs can be labeled and subsequently visualized with magnetic nanoparticles (NPs). We investigated the homing of MSCs labeled with magnetic cobalt ferrite NPs in experimentally induced acute kidney injury in mice. To explore the homing of MSCs after systemic infusion into mice, we developed a pre-infusion strategy for optimal tracing and identification of MSCs with polyacrylic acid-coated cobalt ferrite (CoFe₂O₄) NPs by light and transmission electron microscopy (TEM) in various organs of mice with cisplatin-induced acute kidney injury and control mice. By correlative microscopy, we detected MSCs labeled with NPs in the lungs, spleen, kidney, and intestine of cisplatin-treated mice and in the lungs and spleen of control mice. Our results confirm that labeling MSCs with metal NPs did not affect the ultrastructure of MSCs and their ability to settle in various organs. This study demonstrates the usefulness of cobalt ferrite NPs in ex vivo visualization of MSCs and offers correlative microscopy as a useful method in routine histopathology laboratories for tracing MSCs in paraffin-embedded tissue.     

铜冶炼渣的资源化利用

介绍了铜冶炼渣的资源现状,分析了其化学组成和矿物学性质,从化学利用和物理利用两方面阐述了铜冶炼渣的资源化利用方法和途径,根据当前铜冶炼渣的资源化现状,对其利用前景和利用中存在的问题进行了分析。     

超导磁体脉冲冲击下MOV的破坏特性微观分析

为了将氧化锌电阻阀片(MOV)用于超导磁体的保护,研究了MOV在高温超导磁体产生的脉冲下的冲击破坏过程中的电气特性变化;还通过破坏后MOV的金相分析、SEM微观分析以及成分分析,研究了MOV破坏前后的微观特性的变化;最后讨论了MOV在超导磁体脉冲破坏下的机理,并针对MOV用于在超导磁体保护提出了改进建议,认为保护用阀片应该采取低压大通流氧化锌压敏陶瓷材料,且应该在配方确定的基础上,探索先进的工艺技术改善阀片的性能。     

基于低温直接键合的血细胞计数芯片结构制备

研究了一种新颖的微流管道血细胞计数器的结构及其工作原理,采用流体动力学对其液体分层流动特性进行了仿真分析,结合图形制备和低温直接键合工艺制作了硅基微流体管道血细胞计数器结构,并采用红外透射方法对微流体管道结构进行了检测.对封闭管道的流通性及结构的键合强度也进行了测量.研究分析表明,采用上述工艺制备的微流体芯片结构与电子器件兼容性好,具有良好的化学惰性和热稳定性,而且管道结构规则,精度高,键合界面层薄,具有较好的应用前景.     

中空海胆状结构的碳包覆Fe2O3用作锂离子电池的高性能负极材料

Fe2O3由于成本低廉,储量丰富和理论比容量高(1007 mA hg^-1)等特点,在锂离子电池负极材料的应用中极具发展前景.然而一些问题仍然存在,如:充放电过程中比容量的迅速衰减,不可逆的体积膨胀以及较短的循环寿命等.这些问题严重制约了Fe2O3在锂离子电池中的实际应用.为了突破这些局限,本文以金属-有机骨架(MOF...     

攀钢转炉渣选矿工艺实践

攀钢转炉渣经过热焖预处理后,分解为块度不同、品位不等的渣钢产品,通过打砸切割、筛分磁选以及自磨球磨深加工,可最大限度地回收金属铁,实现循环再利用。     

Development of a novel metal hydride–air secondary battery

A laboratory metal hydride/air cell was evaluated. Charging was via a bifunctional air gas-diffusion electrode. Mixed nickel and cobalt oxides, supported on carbon black and activated carbon, were used as catalysts in this electrode. At 30mAcm–2 in 6m KOH, the air electrode potentials were –0.2V (oxygen reduction) and +0.65V (oxygen evolution) vs Hg/HgO. The laboratory cell was cycled for 50 cycles at the C/2 rate (10mAcm–2). The average discharge/charge voltages of the cell were 0.65 and 1.6V, respectively. The initial capacity of the metal hydride electrode decreased by about 15% after 50 cycles.     

Theoretical studies of CO hydrogenation to methanol over Cu, Pd, and Pt metals

Theoretical studies of CO hydrogenation to methanol over Cu, Pd, and Pt metals have been carried out using a quasi‐relativistic density‐functional method. The metal surface is simulated by a M₁₀ cluster model. Reaction energies for the elementary steps involved are determined. The activation energies are estimated by the analytic BOC‐MP formula. The results support that these metals are active in CO hydrogenation to methanol. The rate‐determining steps are shown to be different for the metals. The highest activation energies of reaction on the metals fall in the order Cu < Pd < Pt, which corresponds to the order of the catalytic activities of the metals in CO hydrogenation. This revised version was published online in July 2006 with corrections to the Cover Date.     

贵金属对TiO2悬浮液光照过程中H2O2形成的促进作用

众所周知,ＴｉＯ２是一种能进行光能化学能转换的半导体材料．７０年代初期,日本的Ｆｕｊｉｓｈｉｍａ等人［１］发现ＴｉＯ２电极能利用光能将水分解为氢气和氧气．从此,ＴｉＯ２作为光能转换材料,在太阳能利用,环境保护,卫生医疗等许多领域逐渐引起研究人员的注...