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991.
Composites made from ground tire rubber (GTR) and waste fiber produced in tire reclamation were prepared by mechanical milling. The effects of the fiber content, pan milling, and fiber orientation on the mechanical properties of the composites were investigated. The results showed that the stress‐induced mechanochemical devulcanization of waste rubber and the reinforcement of devulcanized waste rubber with waste‐tire fibers could be achieved through comilling. For a comilled system, the tensile strength and elongation at break of revulcanized GTR/fiber composites reached maximum values of 9.6 MPa and 215.9%, respectively, with 5 wt % fiber. Compared with those of a composite prepared in a conventional mixing manner, the mechanical properties were greatly improved by comilling. Oxygen‐containing groups on the surface of GTR particles, which were produced during pan milling, increased interfacial interactions between GTR and waste fibers. The fiber‐filled composites showed anisotropy in the stress–strain properties because of preferential orientation of the short fibers along the roll‐milling direction (longitudinal), and the adhesion between the fiber and rubber matrix was improved by the comilling of the fiber with waste rubber. The proposed process provides an economical and ecologically sound method for tire‐rubber recycling. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 4087–4094, 2007 相似文献
992.
Two surface modification methods—plasma surface treatment and chemical agent treatment—were used to investigate their effects on the surface properties of ultrahigh‐molecular‐weight polyethylene (UHMWPE) fibers. In the analyses, performed using electron spectroscopy for chemical analysis, changes in weight, and scanning electron microscope observations, demonstrated that the two fiber‐surface‐modified composites formed between UHMWPE fiber and epoxy matrix exhibited improved interfacial adhesion and slight improvements in tensile strengths, but notable decreases in elongation, relative to those properties of the composites reinforced with the untreated UHMWPE fibers. In addition, three kinds of epoxy resins—neat DGEBA, polyurethane‐crosslinked DGEBA, and BHHBP‐DGEBA—were used as resin matrices to examine the tensile and elongation properties of their UHMWPE fiber‐reinforced composites. From stress/strain measurements and scanning electron microscope observations, the resin matrix improved the tensile strength apparently, but did not affect the elongation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 655–665, 2007 相似文献
993.
Chang Seok Ki Ki Hoon Lee Doo Hyun Baek Masahiro Hattori In Chul Um Dae Woo Ihm Young Hwan Park 《应用聚合物科学杂志》2007,105(3):1605-1610
Regenerated silk fibroin (SF) filaments could be prepared by wet spinning in common solvent/coagulation system. SF was directly dissolved in mixture solvent of phosphoric acid and formic acid (20/80–30/70 ratio) and coagulated in methanol bath. The concentration and stability of SF dope solution have been studied by varying the mixture ratios of these solvents in accordance with elucidating the role of formic acid in the mixture solvent system. Morphological structure as well as crystalline structure of the regenerated filament was examined using SEM and XRD analyses. As a result of tensile test, the regenerated SF filament, which was made by one‐step dissolution and coagulation process, had good mechanical properties, 2.3 gf/d tenacity and 18% breaking strain. In this study, a simple wet spinning method which enables to apply to practical production has been reported for the preparation of the regenerated SF filament. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
994.
Organosolv pulps usually have high kappa number. This research investigated an alkaline extraction method prior to bleaching for reducing the kappa number of organosolv pulp. Ethanol wheat straw pulp with a kappa number of 58.2 was extracted with 1% NaOH solution. The results show that the ethanol pulp has a large amount of lignin particles on the fiber surface. After 1 min alkali extraction, the kappa number of the ethanol pulp is reduced by 60%, to 22.2, and both the number and the size of the lignin particles on the fiber surface are significantly reduced. In comparison with a further ethanol washing/extraction, the alkali extraction is much more effective in terms of lignin removal. X‐ray photoelectron spectroscopy results show that a thin layer of lignin remained on the fiber surface after alkli extraction, but this did not reduce the internal bond strength. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
995.
The evolution of structure, the changes of properties during the preoxidation, precarbonization, and carbonization of different polyacrylonitrile (PAN) precursors were firstly studied in detail by means of using high‐temperature differential scanning calorimetry (DSC) to characterize with continuous heating from 25 to 1400°C. It was essential to study the thermal behavior of PAN precursors so that proper temperature was determined. Three precursors with different composition, P1: acrylonitrile/itaconic acid (AN/IA) = 98/2 (wt/wt); P2: acrylonitrile/acrylamide (AN/AM) = 98/2 (wt/wt); P3: acrylonitrile/ammonium salt of itaconic acid (AN/AIA) = 98/2 (wt/wt) were, respectively, selected in this study. Comparative results of the DSC curves showed that the heating history influenced greatly the heat quantities released and exothermic position at low temperature of DSC curve, but influenced slightly at higher temperature. Aromatic index, carbon yield (Wc) and weight loss (η) can be calculated. After adjusting the temperature in preoxidation and precarbonization and carbonization technology depending on high‐temperature DSC, the high performance carbon fibers were obtained that tensile strength is 3.56–4.16 GPa, modulus is 235–243 GPa. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
996.
Chang Seok Ki Jong Wook Kim Jin Ho Hyun Ki Hoon Lee Masahiro Hattori Dong Kyun Rah Young Hwan Park 《应用聚合物科学杂志》2007,106(6):3922-3928
Practical application to three‐dimensional (3‐D) tissue culture has been limited by the structural restriction of two‐dimensional (2‐D) nature of electrospun nanofiber mat. In this study, for constructing 3‐D nanofibrous structure as real 3‐D tissue engineering scaffold, we developed new fabrication process with silk fibroin (SF) by electrospinning and evaluated the features of this SF nanofiber scaffold (SFNS) through morphological and cell‐culture analyses. Foam type of the SFNS exhibited high porosity as well as large pores and its cell proliferation well occurred inside (inner spaces of pores), which makes this suitable for 3‐D cell‐culture scaffold. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
997.
Panu Sukitpaneenit Tuspon Thanpitcha Anuvat Sirivat Christoph Weder Ratana Rujiravanit 《应用聚合物科学杂志》2007,106(6):4038-4046
Electrically conducting elastomer fibers based on natural rubber (NR) and up to 10% w/w polyaniline (PANI) in its emeraldine base (EB) form were fabricated by a wet spinning process. The resulting fibers at various PANI contents were doped by immersion in aqueous HCl solution, which converted the PANI to the electrically conductive emeraldine salt (ES) form. The morphology of the composite fibers was studied by scanning electron microscopy (SEM). PANI particles were inhomogeneously distributed in the NR matrix. The electrical conductivity of the fibers increased with the increasing PANI‐ES content and leveled off at a value of around 10?3 S/cm at PANI‐ES concentration of 5% w/w. The fibers retained most of their elasticity upon doping, while the tenacity was somewhat reduced. Gratifyingly, the electrical conductivity of the new elastomer fibers was preserved upon elongational deformation, even if strains as large as 600% were applied. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
998.
In this study, poly(ethylene terephthalate) (PET)/SiO2 nanocomposites were synthesized by in situ polymerization and melt‐spun to fibers. The superfine structure and properties of PET/SiO2 fibers were studied in detail by means of TEM, DSC, SEM, and a universal tensile machine. According to the TEM, SiO2 nanoparticles were well dispersed in the PET matrix at a size level of 10–20 nm. The DSC results indicated that the SiO2 nanoparticles might act as a marked nucleating agent promoting the crystallization of the PET matrix from melt but which inhibited the crystallization from the glassy state, owing to the “crosslink” interaction between the PET and SiO2 nanoparticles. The tensile strength of 5.73 MPa was obtained for the fiber from PET/0.1 wt % SiO2, which was 17% higher than that of the pure PET. The fibers were treated with aqueous NaOH. SEM photographs showed that more and deeper pits were introduced onto PET fibers, which provided shortcuts for disperse dye and diffused the reflection to a great extent. According to the K/S values, the color strength of the dyeing increased with increasing SiO2 content. It is found that the deep dyeability of PET fibers was improved greatly. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
999.
Julia A. King Ibrahim Miskioglu Debra D. Wright‐Charlesworth Charles D. Van Karsen 《应用聚合物科学杂志》2007,103(1):328-335
In a composite material, the degree of adhesion between the fiber and the matrix plays an important role in the overall performance of the material. Because the load between the fiber and the matrix is realized throughout the interphase region material, a lot of effort has gone into characterizing the strength of the interphase. In this study, nanoscratch tests on the composite samples were used to provide a relative measure of adhesion in different composite materials. Carbon‐filled nylon 6,6 and polycarbonate resins were evaluated with this method. The carbon fillers we used were polyacrylonitrile‐based carbon fibers sized and surface‐treated for the respective matrix and pitch‐based carbon fibers without any sizing or surface treatment. Tensile and X‐ray photoelectron spectroscopy data for the composites we considered are also presented to compare to the nanoscratch results. It is shown that nanoscratch testing on the composites, with the proposed data analysis, can be an effective tool for determining the relative degree of adhesion between different composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 328–335, 2007 相似文献
1000.
The research was conducted to evaluate the effects of cellulose and polyester fibers on the properties of porous asphalt mixes, using the tests of draindown, abrasion, volumetric properties, rutting, and moisture damage. Images of scanning electron microscopy and X-ray computerized tomography were adopted to identify the microstructure of the fiber and inner stone skeleton of porous asphalt. The influence of rutting parameter (G*/sin δ) of asphalt modified by different fibers on the rutting resistance of the mixes was investigated. Based upon MOHR-COULOMB theory, the cohesion and the angle of internal friction of the mixes were derived from both indirect tension and unconfined compression strength. The experimental results indicate that fibers mainly stabilize asphalt binder and thicken asphalt film around aggregates. Furthermore, they result in the improved mechanical strength of porous asphalt mixes at high temperature slightly. From comparison analysis, cellulose fibers appear to perform better than polyester fibers in porous asphalt mixes. 相似文献