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31.
利用导电高分子聚(3,4-二氧乙基噻吩)/聚(对苯乙烯磺酸)(PEDOT/PSS)作保护剂,制备了银纳米颗粒,用UV-Vis和TEM对其进行了表征.结果表明,选择合适量的PEDOT/PSS保护剂可以得到大小分布较窄银纳米颗粒. 相似文献
32.
33.
Preparation of methanol oxidation electrocatalysts: ruthenium deposition on carbon-supported platinum nanoparticles 总被引:3,自引:0,他引:3
Methanol oxidation electrocatalysts were prepared from Ru electrochemical or spontaneous deposition on commercial-grade carbon-supported Pt nanoparticles (Pt-Vulcan XC72, E-TEK). The resulting Ru coverage was estimated by cyclic voltammetry in supporting electrolyte. The maximum electrocatalytic activity for methanol oxidation at room temperature was observed at lower Ru coverage for spontaneous deposition than for electrodeposition;
Ru 10% vs 20%, respectively. On the other hand, higher current densities for methanol oxidation were obtained in the case of electrodeposited Ru. These two results were related to the presence of non-reducible ruthenium oxides in the spontaneous deposit. The present work provides evidence that (i) efficient DMFC electrocatalysts can be achieved by Ru deposition on Pt nanoparticles, and (ii) formation of a PtRu alloy is not a required condition for effective methanol electrooxidation. 相似文献
34.
Structural characterization by transmission electron microscopy of metal nanoparticle coatings on oxide nanospheres has been
employed to point out the potential of such materials for use as porous support model catalysts. On silica and titania nanospheres
of various origins surface-mediated metal deposition at mild temperature conditions has been utilized to fabricate Pt, Pd,
Ag, and Au nanoparticle coatings on the oxide supports. Promising coating characteristics have been achieved for Ag and Au
nanoparticles by direct reduction on terminating hydroxyl-rich St?ber silica. A high-resolution electron microscopy analysis
directed to surface stress, lattice contraction and planar lattice defects of the latter particles revealed no strong metal-support
interaction. 相似文献
35.
The binary lanthanide catalyst for 1,3‐butadiene was invented for 40 years ago. However, it has not been employed in commercial application due to its poor solubility and low activity. Nanosized neodymium chloride (NdCl3) was prepared in tetrahydrofuran (THF) medium through dissolution, chelation, and colloidal formation steps. Anhydrous NdCl3 was dissolved in THF, and ca. 1.5 THF molecules were coordinated. In the colloidal formation step, THF was slowly replaced with the addition of cyclohexane, and pale blue nuclei, nanosize below 200 nm, were formed. The structural studies for NdCl3 · xTHF using X‐ray powder diffraction (XRD) and scanning electron microscope (SEM) indicate that high ordered crystallinity is decreased with reduced particle size from trigonal prismatic to porous sphere structure. Nano NdCl3, obtained as colloidal state in cyclohexane, was activated with Al(iBu)3 and Al(iBu)2H at room temperature and employed for 1,3‐butadiene solution polymerization. The nanosized Nd catalysts showed high activity (1.0 ~ 1.3 × 105 g/Nd mol · h), which is comparable to that of the ternary neodymium catalyst Nd(neodecanoate)3/AlEt2Cl/Al(iBu)3. The microstructures of polybutadiene, cis, trans, and vinyl, are about 96.0, 3.5, and 0.5%, respectively. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1279–1283, 2005 相似文献
36.
针对森林调查对便携式测量设备自动化和集成化的需求,设计了一种集测高器、角规和标准蓄积量计算功能于一体,具有测量、数据存储、计算等多种功能的手持式多功能电子测树仪GForest。该仪器通过采样控制算法实现对测高器防抖动设计,采用计数器存储并控制角规计数结果,提供USB接口同PC和移动智能终端设备进行数据共享,旨在解决目前森林地面调查数据采集硬件设备信息化与数据采集软件发展不同步的问题,大幅减少了外业调查中手工数据记录和录入的工作,提高了野外数据采集的效率。经实测验证:GForest测得的立木高度与实际值的平均误差为4%,与进口同类设备精度持平,同时还具有角规绕测计数与控制等实用功能,且具有明显的成本优势,适合在行业内推广应用。 相似文献
37.
38.
Carlos Díaz María Luisa Valenzuela 《Journal of Inorganic and Organometallic Polymers and Materials》2006,16(2):123-128
Pyrolysis in air at 800°C of [{NP(OC12H10)}0.6{NP(OC6H4PPh2·(π-CH3C5H4)−Mn(CO)2)2}0.4]
n
(1) in the solid state affords product 2 containing nanoclusters of Mn2P2O7 with sizes ranging from 50 to 90 nm and averaging about 74 nm. The egg-shape of the unpyrolyzed organometallic polymer is
retained but with increased particle size after pyrolysis. The pyrolytic material shows near-infrared photoluminescence attributed
to the emission of tetrahedral Mn2+ embedded in a matrix of Mn2P2O7. The solid-state pyrolysis of organometallic derivatives of polyphosphazenes may be a useful and general route to nano-structured
Mn2P2O7.
An erratum to this article can be found at 相似文献
39.
Uniform polyaniline (PANI) nanoparticles with typical sizes of about 50 nm were electropolymerized on indium tin oxide surfaces in the presence of Co2+, Ni2+, Cu2+, or Zn2+. According to shaping theory, we first suggest the reason forming PANI spherical particles. Their conductivity, UV‐vis spectra, FTIR spectra, X‐ray diffraction, and thermogravimetric analysis were investigated. The conductivities and crystallinity of PANI doped with these ions are higher than those of PANI doped with HCl (PANI/HCl). Both UV‐vis absorption spectra and FTIR spectra indicate the interactions between Co2+, Ni2+, Cu2+, or Zn2+ and PANI chains. TG analysis also shows that the thermal stability of PANI doped by Co2+, Ni2+, Cu2+, or Zn2+ is lower than that of PANI/HCl. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
40.
Kwang‐Pill Lee Anantha Iyengar Gopalan See‐Hee Lee Ali Md Showkat Young Chang Nho 《应用聚合物科学杂志》2006,102(4):3912-3918
Conducting polydiphenylamine was used to encapsulate silica nanoparticles through the oxidative polymerization of diphenylamine in the presence of ultrasonic irradiation. The polymerization was performed in the presence of sodium lauryl sulfate as a surfactant. Experiments performed in the absence of ultrasound clearly demonstrated that the application of ultrasonication played multiple roles in the preparation of a composite of polydiphenylamine with silica nanoparticles. Ultrasonication dispersed the silica nanoparticles, converted sodium lauryl sulfate to lauryl alcohol, and augmented the dispersion of the silica‐nanoparticle/polydiphenylamine composite in an organic medium. Silica‐nanoparticle/polydiphenylamine composites were also prepared in the absence of ultrasound and/or sodium lauryl sulfate. The silica‐nanoparticle/polydiphenylamine composites were characterized with Fourier trans form infrared spectroscopy, ultraviolet–visible/near‐infrared spectroscopy, and thermogravimetric analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3912–3918, 2006 相似文献