Accurate low complexity modeling of twisted pairs suitable for G.fast frequencies

As the higher and higher frequency bands of existing metallic cables in access networks are being continuously exploited by modern transmission technologies, such as the G.fast, the necessity of providing accurate and suitable modeling of their transmission characteristics is evident. Therefore, this paper is focused on modeling of a propagation constant of twisted pairs and metallic cables at high frequencies up to 250 MHz, and an innovative arsinh model is proposed and described. This new model is based on an idea of adopting inverse hyperbolic sine function for modeling of both secondary line coefficients, attenuation constant and phase constant, and its main motivation is to provide their accurate estimations for G.fast frequencies up to 250 MHz for various types of metallic cables while maintaining a low computational complexity. The proposed model was compared with numerous characteristics measured for various real metallic cables as well as with several existing models in order to illustrate its potential. The results, which are presented within this paper, clearly illustrate that the proposed arsinh model generally outperforms existing standard models based on the equal number of required parameters. Copyright © 2015 John Wiley & Sons, Ltd.     

Polyaniline sensitized Pt@TiO2 for visible-light-driven H2 generation

Polyaniline is a typical conducting polymer with high migration electron rate, good stability, eco-friendly properties, and high absorption coefficients for visible light. In the present study, polyaniline decorated Pt@TiO₂ for visible light-driven H₂ generation is reported for the first time. The above-mentioned nanocomposite is prepared through a simple oxidative-polymerization and characterized by infrared spectroscopy, transmission electron microscopy, X–ray diffraction, thermogravimetric analysis, and ultraviolet–visible diffuse reflectance spectra. Polyaniline modification improves the absorption of the nanocomposite in visible light region via a photosensitization effect similar to dye–sensitization but does not influence the crystal structure and size of Pt@TiO₂. The polyaniline modified Pt@TiO₂ exhibits a remarkable visible light activity (61.8 μmol h⁻¹ g⁻¹) and good stability for H₂ generation (with an average apparent quantum yield of 10.1%) with thioglycolic acid as an electron donor. This work provides new insights into using conducting polymers, including polyaniline, as a sensitizer to modify Pt@TiO₂ for visible-light hydrogen generation.     

428XL光缆交叉线的工作原理及故障检修方法

428XL光缆交叉线是428XL仪器的重要组成部分,它的问世有效提高了采集数据的传输速度,满足了随着野外采集道数的增加采集数据的数据量越来越大的数传要求。本文从428XL光缆交叉线的基本组成入手,详细剖析了428XL光缆交叉线的传输原理,并介绍了光缆交叉线应用于428XL仪器施工时的工作流程及其在施工中可能出现的故障和相应的检修方法。     

Thermo- and pH-Responsive Polymersomes of Poly(α,β-N-substituted-DL-aspartamide)s

Materials that can respond to multiple stimuli, such as temperature and pH changes, are of considerable interest for applications in drug delivery systems. Notably, α,β-[poly(2-hydroxyethyl)-DL -aspartamide] is a potentially useful material for such applications. This study investigated the temperature and pH responsiveness of polymers structurally similar to α,β-[poly(2-hydroxyethyl)-DL -aspartamide], namely, poly(α,β-N-substituted-DL -aspartamide)s, in aqueous media. These polymers were derived from polysuccinimide (PSI), which was first synthesized via acid-catalyzed bulk polycondensation of L -aspartic acid (L-ASP) in the presence of 85% o-phosphoric acid under N2. Two primary amino alcohols, 4-aminobutanol (4AB) and 6-aminohexanol (6AH), were then respectively utilized to modify PSI to form poly (α,β-N-substituted-DL -aspartamide)s via aminolysis. Different ratios of these two amino alcohols were used to modify the polymer to produce a series of copolymers with lower critical solution temperatures ranging from 53–28°C when dispersed in aqueous media. Moreover, the properties of the poly(α,β-N- substituted-DL -aspartamide)s in aqueous solution were affected by pH changes. The morphology of the particles formed by these amphiphilic polymers was observed using scanning electronic microscopy and transmission electronic microscopy, and the particles were found to be polymersomes with shell and hollow core structures and diameters of 0.5–1 μm. Other properties of this series of self-assembly copolymers were also characterized. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Maximization of average number of correctly received symbols over multiple channels in the presence of idle periods

In this study, optimal channel switching (time sharing) strategies are investigated under average power and cost constraints for maximizing the average number of correctly received symbols between a transmitter and a receiver that are connected via multiple flat-fading channels with additive Gaussian noise. The optimal strategy is shown to correspond to channel switching either among at most three different channels with full channel utilization (i.e., no idle periods), or between at most two different channels with partial channel utilization. Also, it is stated that the optimal solution must operate at the maximum average power and the maximum average cost, which facilitates low-complexity approaches for obtaining the optimal strategy. For two-channel strategies, an upper bound is derived, in terms of the parameters of the employed channels, on the ratio between the optimal power levels. In addition, theoretical results are derived for characterizing the optimal solution for channel switching between two channels, and for comparing performance of single channel strategies. Sufficient conditions that depend solely on the systems parameters are obtained for specifying when partial channel utilization cannot be optimal. Furthermore, the proposed optimal channel switching problem is investigated for logarithmic cost functions, and various theoretical results are obtained related to the optimal strategy. Numerical examples are presented to illustrate the validity of the theoretical results.     

Influence of zirconium content on microstructure and creep properties of Mo–9Si–8B alloys

Mo–Si–B alloys with a molybdenum solid solution accompanied by two intermetallic phases and Mo₅SiB₂ are a prominent example for a potential new high temperature structural material. In this study the influence of 1, 2 and 4 at.% zirconium on microstructure and creep properties of Mo–9Si–8B (at.%) alloys produced by spark plasma sintering is investigated. Creep experiments have been carried out at temperatures of 1100 °C up to 1250 °C in vacuum. The samples exhibit sub-micron grain sizes as small as 450 nm due to the chosen production route. With addition of 1 at.% zirconium, formation of SiO₂ on the grain boundaries can be prevented, thereby enhancing grain boundary strength and creep properties significantly. Moreover ZrO₂ particles also enhance creep resistance of the molybdenum solid solution. Creep deformation is a combination of dislocation creep in the grains including dislocation-particle interaction and grain boundary sliding leading to intergranular fracture surfaces. It is promising to use grain size adjustments in order to balance the creep and oxidation resistance of the investigated material.     

大体积混凝土温度远程智能监测系统设计及应用

为了对大体积混凝土工程施工全过程进行实时的温度监测,设计开发了混凝土温度监测系统。该系统一次充电可在无外部供电的情况下实现对混凝土温度持续长达30d的实时采集,用无线传输方式把数据发送到工地附近监测室的主控计算机中,并将数据通过互联网同步到公司总部的服务器数据库中,实现了更加智能化的混凝土监测方法。     

Phase transformation and interface segregation behavior in Si3N4 ceramics sintered with La2O3–Lu2O3 mixed additive

Microstructure and mechanical property of silicon nitride (Si₃N₄) ceramic are strongly dependent on the selection of sintering additives. When rare‐earth (RE) oxide is used as the sintering additive, segregation of RE ions at interface between Si₃N₄ grain and intergranular glassy film (IGF) is believed to play a critical role. Although the ionic radius of RE ion is known to be an empirical parameter to modify the mechanical property, the correlation between the segregated ions and their ionic radii is still under controversy. In order to address this issue, (i) rate of α‐β phase transformation and (ii) segregation behavior at the interface were studied for Si₃N₄ ceramics sintered using mixture of La₂O₃ and Lu₂O₃ as additives in this study. Specimens of Lu content 30% and higher exhibited lower activation energies for the α‐β phase transformation as compared with those of Lu content 20% and lower. In terms of the segregation behavior, La was preferably segregated at one site and Lu at the other site along β‐Si₃N₄/IGF interface in the specimens of Lu content 30% and higher. It is understood from these results that Lu segregation site should be more closely related with grain growth.     

Effects of microstructure and C and Si additions on elevated temperature creep and fatigue of gamma TiAl alloys

The creep properties of K5 (Ti-46Al-3Nb-2Cr-0.2W) based alloys were analyzed in wrought processed microstructure forms. The brittle–ductile-transition-temperature (BDTT) depends distinctly on microstructure as well as strain rate, with the minimum value for each microstructure achieved at ∼10⁻⁶/s being about 680 °C and 780 °C, respectively. The greatest creep resistance is achieved in coarse-grained fully lamellar (FL) material and is related to the strong anisotropy of lath structure, large grain size and consequently high BDTT. Additional significant resistance improvement is realized with additions or increases of refractory elements (Nb or W) and decrease in Al content. The most remarkable improvements in primary as well as the minimum creep resistance are realized when small amounts of C or C + Si are added to generate incoherent (to gamma) carbide and silicide particles along γ/γ_T interfaces. The significance of primary creep is assessed for controlling subsequent creep behavior and discussed for its crucial role in satisfying the stringent design creep requirements for advanced rotational components. The accelerated or tertiary creep is used to explain the high temperature (870 °C) high cycle fatigue deformation that exhibits two-stage SN curves with the rapidly softening second stage.     

Transmissivity testing of multilayer insulation at cryogenic temperatures

The problem of degraded emissivity of thin films at low temperatures has been a long observed phenomena. Previous efforts at measuring properties have suggested that transmission of energy through the films may play a key role in the thermal performance of multilayer insulation systems at low temperatures. Similarly, recent testing on tank applied systems has suggested a radiative degradation at low temperatures. Two different approaches were used to attempt to measure the transmission of energy through MLI at low temperatures. A laser based measurement system was set up to directly measure transmittance and a calorimetric based measurement system was used to measure relative emittance of a single layer between aluminum foil and double aluminized Mylar. Minimal transmission at long wavelengths were observed through standard MLI blanket materials at deposition thicknesses of even 35 nm. Where transmission was measured, it was too low to effect the performance of a multilayers system. Similarly, the calorimeter showed similar increases of emissivity for both standard blanket materials and aluminum foils. Multiple different methodologies of measurement have all yielded the same result: that there is no transmission through standard MLI blanket materials at wavelengths associated with temperatures as low as 2 K.