焦炭颗粒的粒度分布及其微观结构研究

焦炭颗粒是生产碳石墨制品的主要原料，它的粒度组成、分布及其微观结构不仅对碳石墨制品的机械性能和理化性能有一定的影响，而且还直接影响到各生产工序的成品率．为此，主要对粉碎后几种焦炭颗粒的粒度组成、分布及其微观结构进行了研究．并通过分析，确立了焦炭颗粒的粒度组成及其分布规律与粉碎方式和焦炭强度之间的内在关系．     

钛酸铝基复合陶瓷的研究

提出了钛酸铝陶瓷研究中存在的问题．论述了颗粒弥散强化陶瓷基复合陶瓷的机理，叙述了第二相颗粒补强钛酸铝基复合陶瓷的国内外研究状况．认为钛酸铝基复合陶瓷是一种很有前途的抗热震冲击且耐高温的材料，并指出了今后的研究方向。     

Variability of light absorption properties in optically complex inland waters of Lake Chaohu,China

Absorption coefficients of phytoplankton, colored detrital matter (CDM), non-algal particles (NAP), colored dissolved organic matter (CDOM), and their relative contributions to total non-water absorption (a_t ? w) are essential variables for bio-optical and radiative transfer models. Light absorption properties showed large range and variability sampled at 194 stations throughout Lake Chaohu between May 2013 and April 2015. The a_t ? w was dominated by phytoplankton absorption (a_ph) and NAP absorption (a_d). The contribution of CDOM absorption to a_t ? w was lower than 30%. Phytoplankton and NAP were the primary sources of spatial and vertical variability in absorption properties. Light absorption by CDOM, though significant in magnitude, was relatively constant. CDM absorption (a_dg) was dominated by NAP. The spatial variation of the absorption coefficients from each of the optically active constituents were driven by several main inflow rivers in the western and middle part of Lake Chaohu. Algal blooms and bottom resuspension contributed to vertical variability as observed by phytoplankton and NAP profiles. Specific absorption of phytoplankton had significant spatial and seasonal variations without vertical variation. The spectral slope of absorption showed no significant spatial variability (p > 0.05). Variations of absorption affected different ranges of remote sensing reflectance (R_rs) spectrum, thereby increasing the difficulty of applying the remote sensing algorithm in optically complex waters. Parameters and relationships presented in this study provide useful information for bio-optical models and remote sensing of lakes similar to Lake Chaohu in terms of optical properties.     

Regeneration of zinc particles for zinc–air fuel cells in a spouted-bed electrode

Fuel cells wherein zinc particles form a negative electrode and a gas-diffusion electrode (air electrode) is the positive electrode, are under development. Such cells are dependent on the regeneration of the zinc particles (and electrolyte). This paper describes experiments on electrolytic cells equipped with spouted bed cathodes for use in this application. Experiments have been carried out on laboratory scale cells to determine the operability of cells for growing 'seed particles in the range from 0.4 to 1 mm to measure cell voltage and current efficiency (and thereby energy consumption rate), and to identify a suitable material that could be used as a diaphragm (separating the spouted bed from the oxygen evolving anode). A larger cell, capable of producing up to 10 kg Zn per day, was designed and built. The larger cell was run successfully fifteen times and showed cell voltages and energy consumption rates comparable with those of smaller cells.     

A new test for cleaning efficiency assessment of cleaners for hard surfaces

A new test was developed to assess the efficiency of no-wiping hard-surface cleaning. The test allows cleaner comparisons according to their ability to remove greasy soils. The chosen approach minimizes the mechanical forces applied while cleaning so that the interactions between a detergent solution and the soil to be removed can be characterized. For this, immersion cleaning was chosen, with coated stainless steel as substrate and pigmented oils as the model soil. Several parameters were studied in defined ranges using the Experimental Design method and systematic comparisons. The test shows high reliability on degreasing assessments and is there-fore especially suited to optimization of nonionic surfactant mixes. The originality of the test lies in the possibility of keeping a visual trace of the cleaned substrate appearance by imprinting it on a piece of paper. The validation of the test leads to corroboration of several practical observations. Temperature and agitation play a major role in cleaning efficiency. Detergent solution concentration is a more relevant parameter than pH. Sodium carbonate is shown to have a higher buffering effect than pentahydrated sodium metasilicate. The test is easy to set up, highly sensitive, and can be adapted to solve the problems encountered by formulators of detergent cleaners, such as screening the best ethoxylated fatty alcohol mix for better degreasing properties.     

淤浆鼓泡床中固体粒子的悬浮特性

研究了三相鼓泡床中的临界固含率,以空气作气相,水、乙醇-水、丙酮-水、萜松醇-二甲苯作液相,石英砂、煤、雷奈镍作为固相。分析了鼓泡柱的高径比、气体速度、固体粒子的大小和比重、液体的粘度对临界固含率的影响,提出了含有这些参数的无因次数群的关联式,讨论了本文提出的关联式和文献报导的差别。     

脲醛树脂乳液干燥成粉末的试验研究

进行了用惰性粒子流化床干燥器将脲醛树脂乳液干燥成粉末的试验研究，产出了品质好的干粉，得出了在试验条件下的干燥强度和热效率，并作了经济性评价。     

冷冻凝聚工艺生产CR322的研制

对原电解质凝聚工艺生产CR322(混合调节型氯丁橡胶)进行了改进，实现了冷冻凝聚新工艺法生产切块CR322，即主乳化剂由松香皂／脂肪酸皂复合型代替了单一松香皂。新工艺解决了冷冻转鼓装置生产CR322过程中“黏杆”及干胶门尼黏度控制等问题。产品无焦烧粒子。且焦烧时间明显延长。     

Settling velocities of particles in bubbly gas-liquid mixtures

The axial dispersion-sedimentation model is commonly used to describe the axial concentrations of solids in three phase bubble columns at low liquid velocities. When the two parameters of this model, the particle settling velocity and the solids axial dispersion coefficient, are uncoupled by the use of various assumptions, physically unrealistic values of these parameters often result. Direct experimental measurements of solids settling rates in bubbly gas-liquid mixtures were carried out. The measured mean settling velocities decreased slightly with gas flow rate and were equal to or slightly less than the single particle free settling velocity in the liquid alone. Solids axial dispersion coefficients were also obtained from the solids settling rate distribution data, and gave values considerably less than the experimental liquid axial dispersion coefficient.     

The tribological behavior of micrometer and nanometer TiO2 particle‐filled poly(phthalazine ether sulfone ketone) composites

Micrometer and nanometer TiO₂ particle‐filled poly(phthalazine ether sulfone ketone) (PPESK) composites with various filler volume fractions from 0.5 to 7.5 vol % were prepared by heating compression molding. The friction and wear behaviors of the PPESK composites were evaluated using the block‐on‐ring test rig by sliding PPESK‐based composite blocks against a mild carbon steel ring under dry friction conditions. The wear debris and the worn surfaces of the PPESK composites filled with micrometer and nanometer TiO₂ particles were investigated by using a scanning electron microscope (SEM), while the structures of PPESK composites and wear debris were analyzed with IR spectra. Experimental results show that antiwear properties of the PPESK composites can be improved greatly by filling nanometer TiO₂ particles, and the friction coefficient decreases when the filler volume fraction is below 2.5%, but when the filler volume fraction is above 2.5% the friction coefficient increases gradually with increasing filler volume fraction. In the case of micrometer TiO₂ filler, wear rates increase with increasing filler volume fractions under identical test conditions, and the friction coefficients are less sensitive to the filler volume fraction. It was also found that the wear mechanism of micrometer TiO₂ particle‐filled PPESK is mainly severe adhesion and abrasive wear, while that of nanometer TiO₂ particle‐filled PPESK is mainly slight abrasive wear. In the former case, there are no transfer film formed on the surface of the counterpart steel, and wear debris are in the form of long and large ribbon. While in the latter case, the wear debris was granule and their size was about 10 μm. In case of 1 vol % nanometer TiO₂ particle‐filled PPESK composites, the transfer film was fairly thinner and smoother, and the transfer film provided better coverage on the surface of steel ring, while that of 7.5 vol % was thicker and discrete. These account for the different friction and wear behavior of micrometer and nanometer TiO₂ particle‐filled PPESK composite. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 906–914, 2004