Synthesis and characterization of Li ion conducting La2/3−xLi3xTiO3 by a polymerizable complex method

Ultrafine lithium ion conducting La_2/3−xLi_3xTiO₃ (x = 0.11, LLT) powder was synthesized by a simple polymerizable complex method based on the Pechini-type process. The formation mechanism, homogeneity and microstructure of the samples were investigated by thermal analysis (TG/DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). XRD analysis indicated the formation of pure perovskite-type phase. The powder synthesized at a temperature as low as 900 °C in a much shorter time than solid-state reaction method was well crystallized. The lithium ion conductivity of the LLT ceramics sintered at 1200 °C was found to be 9 × 10⁻⁴ S/cm at room temperature.     

Electrochemical micromachining using a solid electrochemical reaction at the metal/β″-Al2O3 microcontact

A simple solid state technique for electrochemical micromachining of metal substrates using a metal ion conductor (Na-β″-Al₂O₃) was proposed. The fundamental solid electrochemical cell consists of a (anode) metal substrate (M = Ag, Cu, Zn, and Pb)/pyramidal Na-β″-Al₂O₃/Ag (cathode) system, where the contact diameter between M/Na-β″-Al₂O₃ was extremely small, on the order of a few micrometer. Under an applied electric field, the metal substrate was electrochemically oxidized to metal ions (Mⁿ⁺) at the M/Na-β″-Al₂O₃ microcontact. These Mⁿ⁺ ions migrated into the Na-β″-Al₂O₃. As a result of continuous electrolysis, the metal substrate was locally consumed at the microcontact, and thus solid state electrochemical micromachining was accomplished. As expected, the machining size or depth depended on the electrolysis conditions (current, operating time) and the apex configuration of pyramidal Na-β″-Al₂O₃. Moreover, the scanning of the Na-β″-Al₂O₃ pyramid during electrolysis produced a fine patterned metal substrate. In the present paper, solid state electrochemical micromachining was performed for several metal substrates, and its advantages and disadvantages vis-a-vis the conventional electrochemical micromachining method are discussed in detail.     

一种极化选择多频带的低雷达截面积反射屏简

A novel radar reflection screen composed of the polarization-dependent mutiband artificial magnetic conductor (PDMAMC) and perfect electric conductor cells is proposed. The PDMAMC is realized by etching a complementary split ring resonator (CSRR) on the patch of a conventional artificial magnetic conductor. Around the two/three operational frequencies of the PDMAMC-elements for different electric field polarizations, the reflection of the PDMAMC and perfect electric conductor have opposite phases, so for any normal incident plane wave the reflections cancel out. The basic principle is discussed and a sample is measured. The results show that the proposed method is feasible and effective for polarization-dependent mutiband RCS reduction.     

基于六边形AMC结构的60 GHz片上天线的设计

介绍一种基于六边形人工磁导体结构采用标准CMOS工艺的60 GHz片上天线的设计。标准CMOS工艺以金属硅为衬底,但衬底硅的低电阻率(10Ω·cm)和低的电子迁移率特性对天线辐射有较大影响。AMC结构通过合理的设计具有类似于理想磁壁的同相位反射特性。通过在天线与硅衬底之间周期加载AMC结构,可以有效地提高天线的增益、辐射效率等。重点讨论了采用人工磁导体结构的天线优化设计,并基于三维电磁仿真软件Ansoft HFSS仿真比较了不同排列的人工磁导体结构对天线性能的影响。     

220kV枣林Ⅱ回线路导线防舞分析与措施

通过气象条件、地形以及线路结构参数等特点对将建的220 kV枣林Ⅱ回线路荆门段,可能导致线路导线舞动的原因进行了分析,并根据线路的自身特点和总结出的防舞经验,提出了该工程的导线防舞设计思路和措施,以便更好的应用到工程实例中进行检验.     

220kV变电站三相短路电流计算及结果应用

文章阐述了220 kV变电站的三相短路电流计算的重要性,并结合工程实例介绍了三相短路电流的计算过程及计算结果在变电站设计中的应用.     

复合型导电高分子材料研究进展

简述了复合型导电高分子材料的研究及发展,并对其导电机理、基体树脂、导电填料的研究概况进行了述评,介绍了其在各领域中的应用．     

尖端导体电晕放电试验研究

电晕放电是高压电力工程及航空航天领域研究的重点及难点问题;为研究尖端导体电晕放电的辐射特点,设计了电晕放电试验模拟系统;利用测试系统及天线在微波暗室内进行了不同测试距离、不同放电电压及不同尖端导体长度条件下的试验;通过对试验数据的分析可知,电晕放电辐射信号呈衰减振荡模式;电晕放电脉冲重复率随着充电电压的增大而增加;天线接收的辐射信号能量与测试距离成反比;随着充电电压的增加,信号辐射功率呈增加趋势;试验研究结果为输变电工程、航空航天装备的电磁环境分析提供参考。     

Light scattering from anisotropic, randomly rough, perfectly conducting surfaces

An approach is introduced for performing rigorous numerical simulations of electromagnetic wave scattering from randomly rough, perfectly conducting surfaces. It is based on a surface integral technique, and consists of determining the unknown electric surface current densities from which the electromagnetic field everywhere can be determined. The method is used to study the scattering of a p-polarized beam from an anisotropic Gaussian, randomly rough, perfectly conducting surface. It is demonstrated that the surface anisotropy gives rise to interesting and pronounced signatures in the angular intensity distribution of the scattered light. The origins of these features are discussed.     

Potentiometric CO2 gas sensor with lithium phosphorous oxynitride electrolyte

Potentiometric cell, Au/LiCoO₂ 5 m/o Co₃O₄/Li_2.88PO_3.73N_0.14/Li₂CO₃/Au, has been fabricated and investigated for monitoring CO₂ gas. A LiCoO₂–Co₃O₄ mixture was used as the solid-state reference electrode instead of a reference gas. The idea is to keep the lithium activity constant on the reference side using thermodynamic equilibrium at a given temperature. The thermodynamic stability of the reference electrode was studied from the phase stability diagram of Li–Co–C–O system. The Gibb’s free energy of formation of LiCoO₂ was estimated at 500°C from the measured value of the cell emf. The sensors showed good reversibility and fast response toward changing CO₂ concentrations from 200 to 3000 ppm. The emf values were found to follow a logarithmic Nernstian behavior in the 400–500°C temperature range. CH₄ gas did not show any interference effect. Humidity and CO gas decreased the emf values of the sensor slightly. NO and NO₂ gases affect this sensor significantly at low temperatures. However, increased operating temperature seems to reduce the interference.