铜电解生产用短路铜导体的设计及改进实例

简要介绍铜电解工业生产的特点及使用短路导体的原因,分析电解槽上使用的短路导体之技术要求,提出铜电解槽短路导体的设计注意事项,并给出改进设计实例。     

Thermal spray coating on conductor rolls in electroplating line

In electroplating lines,many conductor rolls are installed in electroplating bath.Typical electroplatings are tin plating(ETL) and zinc plating(EGL),and from required product qualities,a vertical cell for the former and a horizontal cell for the latter is often used.Generally,chrome plating or WC cermet thermal spray coating is applied to stainless steel conductor roll in ETL for prolonging service life by improvement of wear resistance and corrosion resistance.On the other hand,Hastelloy type alloy subs...     

输电线路激光除冰技术试验分析及工程应用设计

为防止覆冰对输电线路的危害,从理论分析、模拟试验、工程应用设计等方面系统研究了输电线路激光除冰技术,分别得出了CO2、Nd:YAG激光除冰特性:1.5kW CO2激光融冰体速度约为728.5mm3/s,单位能耗为2.08J/mm3;Nd:YAG固体激光融冰效果稍高于CO2激光,突出优点在于其热应力除冰;激光除冰时瓷绝缘子安全阈值约20.5～54.4J/mm2,复合绝缘子远小于该值,导线安全阈值很高,几乎不会损伤。结果表明激光可用于输电线路除冰,具有热融冰效应和热应力效应,如结合机械除冰可大大提高除冰效率和效果。根据研究结果提出了其工程应用设计方案:工程化车载式激光除冰系统选用固体激光器,输出功率1～1.5kW,光斑直径15～20mm,发散角3mrad,作用距离为100～1000m,激光电源采用车载发电机,总功耗≤50kW。预计未来3～5a激光除冰速度将可提高3～4倍,激光除冰系统可向小型化、便携式方法发展。     

单芯电缆热时间常数的理论计算与试验研究

由于电缆热容的存在,当施加阶跃电流时,电缆温度随时间逐渐变化,经一段时间后达到热稳态,导体温度变化的速度一般用热时间常数来反映。为此,以单芯电缆为研究对象,介绍了电缆热时间常数;建立了电缆本体及周围介质的暂态热路模型并进行简化等效;计算了空气敷设和直埋敷设单芯电缆的热时间常数;并在试验现场进行了阶跃电流下的单芯电缆温升试验,通过对实测导体温度暂态过程的曲线拟合求得了电缆实际的热时间常数,验证了理论计算的正确性。电缆的热时间常数可用于估算阶跃电流作用下的导体暂态温度响应、以及到达最高允许温度所需要的升温时间,为电缆的运行状态监测及故障预警提供理论支持。     

直流融冰过程中覆冰导线表面最高温度试验研究

输电线路短路融冰是目前最为有效的一种除冰方法,而融冰过程中导线温升过快可能会超过导线允许温度使导线损伤。为此,以LGJ-240/30和LGJ-400/35导线为试品,在人工气候室进行了大量的融冰试验。试验结果表明,融冰过程中,导线表面最高温度决定于冰层厚度和融冰电流的大小,不受外界环境温度和风速的影响。并推导出导线最高温度的计算公式。     

Enhanced electrode kinetics and electrochemical properties of low-cost NaFe2PO4(SO4)2 via Ca2+doping as cathode material for sodium-ion batteries

In recent years,sodium-ion batteries(SIBs)have been considered as one of the most promising alterna-tives to lithium-ion batteries(LIBs).Here,a new Na-super-ionic conductor(NASICON)cathode material NaFe2PO4(SO4)2 is successfully prepared through solid state method for SIBs.While the poor electronic conductivity of iron-based materials results in its poor rate and cycle performance.Then the electro-chemical is effectively promoting via Ca2+doping.Na0.84Ca0.08Fe2PO4(SO4)2 have achieved considerable electrochemical properties.The first discharge specific capacity is 121.6mAhg-1 at 25mAg-1 with the voltage platform(～3.1 V)corresponding to Fe2+/3+.After 100 cycles,the capacity retention is 55.1％.The excellent electrochemical performance is caused by some Na+is substituted by Ca2+and leading to the fast sodium kinetics,which is well proved by the powder X-ray diffraction pattern and well corresponding to the galvanostatic intermittent titration technique and cyclic voltammetry testing result(the diffusivity values are around at 10-12 cm2 s-1).     

Spatial mapping of electronic states in κ-(BEDT-TTF)2X using infrared reflectivity

Abstract

We review our recent work on spatial inhomogeneity of the electronic states in the strongly correlated molecular conductors κ-(BEDT-TTF)₂X. Spatial mapping of infrared spectra (SMIS) is used for imaging the distribution of the local electronic states. In molecular materials, the infrared response of the specific molecular vibration mode with a strong electron–molecular vibration coupling can reflect the electronic states via the change in the vibration frequency. By spatially mapping the frequency shift of the molecular vibration mode, an electronic phase separation has been visualized near the first-order Mott transition in the bandwidth-controlled organic conductor κ-(BEDT-TTF)₂Cu[N(CN)₂]Br. In addition to reviewing SMIS of the phase separation, we briefly mention the electronic and optical properties of κ-(BEDT-TTF)₂X.     

Nanostructured MIEC Ba0.5Sr0.5Co0.6Fe0.4O3−δ (BSCF5564) cathode for IT-SOFC by nitric acid aided EDTA–citric acid complexing process (NECC)

Ba_0.5Sr_0.5Co_0.6Fe_0.4O_3−δ(BSCF5564) was synthesized by nitric acid aided EDTA–citric acid complexing sol-gel method (NECC). Both, the phase formation temperature and time of BSCF5564 synthesized NECC were found to be low i.e. single perovskite phase formation temperature is 200 °C less as compared to the conventional method of synthesis. The orthorhombic perovskite structure has been formed after calcination at 800 °C for 5 h. Scanning electron microscopy reveals the formation of porous material constituting nano-sized and irregularly shaped rod-like structure with particle size approximately ranges from 90 to 160 nm. The total weight loss of the BSCF5564 sample comes out to be 6.6%, indicating that quadrivalence state Co⁴⁺ and Fe⁴⁺ in the sample have been completely reduced to the trivalent state Co³⁺ and Fe³⁺ due to thermal analysis. The value of E_a for BSCF5564 prepared by NECC was 0.2288 eV. The electrical conductivity of BSCF5564 synthesized by NECC is observed to be steady at high temperature (above 700 °C).     

Oxygen permeation of various archetypes of oxygen membranes based on BSCF

Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3‐δ tubes, capillaries, capillary modules, and asymmetric membranes were prepared and tested for oxygen permeation in a dead‐end vacuum operation mode at temperatures up to 850^°C. The capillary module was built up by reactive air brazing using seven capillaries and a supply tube. Two machined discs were used as an end cap and as a connector plate. The oxygen permeation behaves according to Wagner at small driving forces, but significant negative deviations were observed for asymmetric membranes and single capillaries at higher ones. This is caused by pressure drops at the vacuum side for single capillaries. The highest oxygen flux was revealed for the capillary module with 175.5 mL(STP)/min at a low‐vacuum pressure of 0.042 bar at 850^°C, but the asymmetric membrane showing a little bit higher flux at moderate vacuum pressures above 0.07 bar. © 2012 American Institute of Chemical Engineers AIChE J, 58: 3195–3202, 2012     

Pulse-modulation eddy current probes for imaging of external corrosion in nonmagnetic pipes

Since the nonmagnetic pipe is normally utilized in corrosive and hostile environment, it is prone to the external corrosion which occurs on the outer surface of the pipe and severely undermines the structural integrity and safety. Although Pulsed Eddy Current technique (PEC) is currently preferred for detection and evaluation of subsurface defects in tubular conductors, it is subject to technical drawbacks. In light of this, Pulse-modulation Eddy Current technique (PMEC) is intensively investigated in the paper for enhancement of the evaluation sensitivity to external corrosion and accuracy of corrosion imaging. Closed-form expressions of the PMEC response and its sensitivity to external corrosion in tubular conductors are formulated via the Extended Truncated Region Eigenfunction Expansion (ETREE) modeling. Following simulations for analysis and comparison of field signals and evaluation sensitivities of PMEC and PEC, experiments of PMEC for evaluation and imaging of external corrosion are carried out. Through theoretical and experimental investigation, it has been found that regarding the evaluation and imaging of external corrosion in nonmagnetic pipes, the PMEC-based probe have higher sensitivity and imaging accuracy than that based on PEC. The superiority of PMEC to PEC in inspection of tubular conductors is further identified.