Ammonia is a key component of many industrial processes where it is used in very high concentrations. The applications range from high quality steel production and fertiliser manufacture, to the refrigeration of food products and ice ring leisure facilities. Ammonia escapes have been identified as a large and serious problem by both government and industry. Simple and robust ammonia sensors for remote monitoring applications remain an area of continuous interest.
Polyaniline is a conducting polymer used in ‘electronic nose’ instrumentation and has been shown to be electronically sensitive to ammonia. In this paper, we report on the application of electrochemically-prepared polyaniline films for the measurement of gaseous ammonia at 1300 nm. This wavelength corresponds to a region of high optical transmission for optical fibres and is also compatible with telecom devices and technology. A simple and robust measurement system based on a standard telecom 1300 nm LED is described and remote sensing using 100 m of duplex multimode fibre is demonstrated.
Typically, the transmission of the polyaniline films at 1300 nm increases by approximately 1% in response to gaseous ammonia levels of 6 ppm in 50% RH. This represents the lower limit of detection in our study. Although initially the sensors react to the presence of ammonia very fast it takes over several hours for the output to reach the equilibrium. Clearly this is impractical however, it is possible to differentiate between different concentrations of ammonia by taking two readings at fixed intervals. A calibration curve for the sensors was obtained using two readings 15 s apart. The response time of the polyanaline films was found to be insensitive to the humidity variations in the range of 30–70% RH, however, over the 10–90% variation the changes were of the same order of magnitude as those induced by 6 ppm of ammonia. 相似文献
This paper presents a 3D active contour model for boundary detection and tracking of non-rigid objects, which applies stereo vision and motion analysis to the class of energy-minimizing deformable contour models, known as snakes. The proposed contour evolves in three-dimensional space in reaction to a 3D potential function, which is derived by projecting the contour onto the 2D stereo images. The potential function is augmented by a kinetic term, which is related to the velocity field along the contour. This term is used to guide the inter-image contour displacement. The incorporation of inter-frame velocity estimates in the tracking algorithm is especially important for contours which evolve in 3D space, where the added freedom of motion can easily result in loss of tracking. The proposed scheme incorporates local velocity information seamlessly in the snake model, with little computational overhead, and does not require exogenous computation of the optical flow or related quantities in each image. The resulting algorithm is shown to provide good tracking performance with only one iteration per frame, which provides a considerable advantage for real time operation. 相似文献
Fluorinated amorphous carbon films (a-C:F) were prepared at different temperatures using a microwave electron cyclotron resonance chemical vapor deposition (ECR-CVD) reactor with CHF3 and C2H2 as source gases. Films were annealed at 500℃ in vacuum ambience inorder to investigate the relationship of their thermal stability, optical and electrical propertieswith deposition temperature. Results indicate that the films deposited at high temperature have a less CFx bonding and a more cross-linking structure thus a better thermal stability. They also have a lower bandgap, higher dielectric constant and higher leakage current. 相似文献