婴幼儿用纸尿裤(片)及隔尿垫巾中荧光增白剂的研究

总结了婴儿纸尿裤(片/垫)和隔尿垫巾的相关标准,通过不同方法方式对婴儿纸尿裤(片/垫)和隔尿垫巾中荧光增白剂进行研究,结果发现有部分婴儿纸尿裤(片/垫)和隔尿垫巾有荧光现象;隔尿垫巾通过擦拭和尿液浸泡时发现荧光迁移的现象;并且检出FWA393(4,4’-双(苯并噁唑-2-基)二苯乙烯)和FWA1842,2’-(2,5-二苯基硫代)双[5-(1,1-二甲基乙基)苯并噁唑])两种荧光增白剂,且大部分的检出值较高。婴幼儿纸尿裤/片、隔尿垫巾等产品其使用对象为免疫系统未发育完善、皮肤较为薄弱且社会关注度极高的婴幼儿,且使用部位非常敏感,该类产品中荧光增白剂含量如此之高应引起有关部门的关注。     

Morphology and failure in nanocomposites. Part II: surface investigation

Polymer composites filled with calcium carbonate (CaCO₃) nanofillers (<100 nm), and kaolin filler of layered structure, both well suited to create nanocomposites, were analysed. The aim of this study was to investigate the influence of surface properties of the filler and matrix on the adhesion parameters at the interface in composites. The inverse gas chromatography, contact angle and capillary measurements were used for the surface characterization of filler and matrix. Although these methods are based on different assumptions, we found the same trends in the effects of filler surface treatment and/or matrix chemical structure on the changes in the dispersive and polar components of the surface energy. The energetics of the filler and matrix was varied in order to investigate the work of adhesion, interfacial energy and coefficient of spreading, and their influence on the composite properties. We found that the surface treatment of calcium carbonate filler lowered the filler surface energy and the work of adhesion in the composite with poly (vinyl acetate) matrix. The mechanical, thermal and morphological properties of the composite with treated CaCO₃, measured in the first part of this paper, indicated a weak and thin interphase. In the composite with kaolin filler the higher interaction with the polyacrylate copolymer matrix based on styrene as compared to the one based on methyl methacrylate, was confirmed by the higher work of adhesion in the interphase, resulting in a stronger reinforcing of the composite.     

SNIPPET ON DRYING

ABSTRACT

When regarding the atmospheric contact drying of granular beds wetted with a liquid mixture, both the drying rate and the selectivity of the process, i.e. the change of moisture composition, are of interest. The batch drying of a free flowing ceramic substance, wetted with a 2-propanol-water mixture, is investigated in a rotary dryer with heated wall and air flow.

The theoretical analysis is based on physical models for heat and mass transfer, moisture migration and particle transport, which are presented in examples.

The experimental and theoretical results show that higher selectivities can be achieved by reducing the particle size because of the lower liquid-phase mass-transfer resistance. An increase of the rotational speed leads to a higher drying rate with slightly decreased selectivity if the particles are sufficiently small, since contact heat transfer is enhanced.     

A DYNAMIC,ADAPTIVE, LOCALLY CONSERVATIVE,AND NONCONFORMING SOLUTION STRATEGY FOR TRANSPORT PHENOMENA IN CHEMICAL ENGINEERING

A family of discontinuous Galerkin (DG) methods are formulated and applied to chemical engineering problems. They are the four primal discontinuous Galerkin schemes for space discretization: symmetric interior penalty Galerkin, Oden-Babu?ka-Baumann DG formulation, nonsymmetric interior penalty Galerkin, and incomplete interior penalty Galerkin. Numerical examples of DG to solve typical chemical engineering problems, including a diffusion-convection-reaction system in a catalytic particle, a problem of heat transfer in a fixed bed, and flow and contaminant transport simulations in porous media, are presented. This article highlights the substantial advantages of DG on adaptive mesh modification over traditional methods. In particular, we propose and investigate the dynamic mesh modification strategy for DG guided by mathematically sound a posteriori error estimators.     

Physicochemical Investigation of Biocompatible Mixed Surfactant Reverse Micelles: III. Aqueous NaCl Solubilization, Thermodynamic Parameters of Desolubilization Process and Conductometric Studies

Solubilization of water and aqueous NaCl in mixed reverse micelles (RMs) comprising sodium bis(2‐ethylhexyl) sulfosuccinate (AOT), and polyoxyethylene (20) sorbitan trioleate or polyoxyethylene (20) sorbitan monooleate has been studied at different compositions (X_nonionic = 0–1.0) at a total surfactant concentration, S_T = 0.10 × 10³ mol m^?3 in biocompatible oils of different chemical structures; viz., ethyl oleate (EO), isopropyl myristate (IPM) and isopropyl palmitate (IPP) at 303 K. The enhancement in water solubilization (i.e., synergism) has been evidenced by the addition of nonionic surfactant to dioctyl sulfosuccinate/oil(s)/water systems. Addition of NaCl in these systems at different X_nonionic enhances their solubilization capacities further until a maximum, ω_NaCl,max is reached. ω_NaCl,max and [NaCl]_max (concentration at which maximization of NaCl solubilization occurs) depend on type of nonionic surfactant, its content (X_nonionic) and oil. A new solubilization efficiency parameter (SP*_water or SP*_NaCl) has been proposed to compare solubilization phenomena in these oils. The energetic parameters of the desolubilization process of water or aqueous NaCl in single and mixed RMs have been estimated. Energetically, the water dissolution process in oil has been found to be more exothermic as well as more organized in IPP. Overall, the dissolution of water and aqueous NaCl in mixed RMs is entropically driven process. Conductance behavior of these systems in the presence of NaCl has been investigated under different [NaCl] at 303 K. An attempt has been made to give an insight to the mechanism of solubilization phenomena, percolation in conductance and microstructures vis‐à‐vis role of biocompatible oils in these systems.     

Understanding the structure of the first atomic contact in gold

We have studied experimentally jump-to-contact (JC) and jump-out-of-contact (JOC) phenomena in gold electrodes. JC can be observed at first contact when two metals approach each other, while JOC occurs in the last contact before breaking. When the indentation depth between the electrodes is limited to a certain value of conductance, a highly reproducible behaviour in the evolution of the conductance can be obtained for hundreds of cycles of formation and rupture. Molecular dynamics simulations of this process show how the two metallic electrodes are shaped into tips of a well-defined crystallographic structure formed through a mechanical annealing mechanism. We report a detailed analysis of the atomic configurations obtained before contact and rupture of these stable structures and obtained their conductance using first-principles quantum transport calculations. These results help us understand the values of conductance obtained experimentally in the JC and JOC phenomena and improve our understanding of atomic-sized contacts and the evolution of their structural characteristics.     

Microfluidic modeling and simulation of flow in membrane microreactors

We study the development of a mathematical model that describes isothermal microfluidic steady flow in a membrane microreactor, i.e., a silicon microreactor that houses a permeable membrane in one wall. The model employs the Navier-Stokes equation with appropriate boundary conditions for fluid permeation through the membrane and velocity slip at the walls to account for high Knudsen number. The model equations are solved analytically using finite Fourier transforms. The model solution is used to evaluate the effect of fluid permeation through the membrane and the Knudsen number on the velocity profile and pressure drop. For the simplified cases of no permeation and/or no slip, the derived solution is in excellent agreement with published experimental and theoretical results available in the literature. The utility of the model is illustrated by applying the results to a membrane microseparator used to separate hydrogen from the other effluents in a microreformer.     

Wettability and interfacial phenomena in the liquid-phase bonding of refractory diboride ceramics: Recent developments

Joining and integration technologies are integral to manufacturing of components based on ultrahigh-temperature ceramics (UHTCs) such as transition metal diborides. Brazing is a particularly attractive joining technique because of its simplicity and versatility, but its use to join the UHTCs demands knowledge of the complex interplay among high-temperature wettability, interfacial reactions, and chemical and thermoelastic compatibilities. This paper summarizes the research and development activities carried out over the last two decades to characterize the wettability and interfacial phenomena in brazing of refractory diboride ceramics. The contact angle data of various metal alloys on diboride-based ceramics have been collected and critically evaluated in conjunction with an analysis of the chemistry and structure of the interface to understand the underlying mechanisms and phenomena that govern interface formation. It explores how solid–liquid interactions impact and are impacted by physical, chemical, and mechanical properties of joined materials. It also describes how this knowledge has been successfully utilized to create liquid-phase bonded diboride-based joints. The paper concludes with a summary of the current state of the art and highlights integration challenges and future research and technology development needs in the area.     

汽车把手面盖表面浮纤解决方案

分析了汽车把手面盖制品的结构和成型工艺特点,介绍了其表面浮纤现象的形成原因和改善措施。重点探讨了通过调整模具结构、优化注射成型工艺条件来有效改善浮纤现象的技术要点。结果表明,通过合理调整模具浇注系统和注射成型工艺参数,可有效改善表面浮纤现象。     

The effect of evaporation on size and shape evolution of faceted gold nanoparticles on sapphire

We studied the size and shape evolution of about 180 faceted gold nanoparticles attached to a sapphire substrate during annealing at 950 °C in air. We employed the scanning force microscopy and interrupted annealing techniques to track the changes in size and shape of individual nanoparticles. The height of all single-crystalline nanoparticles was constant up to the longest cumulative annealing time of 65 h. The lateral dimensions of ∼20% of all nanoparticles shrunk during anneals, while all three dimensions of the remaining 80% of nanoparticles remained constant. Only the nanoparticles with the height below the average (for all particles) were laterally shrinking. We formulated a kinetic model relating the lateral shrinkage of the nanoparticles to the evaporation of Au atoms adsorbed on sapphire. We also assumed that the process controlling particles shrinkage is the slow self-diffusion of Au atoms along the lateral facets of the nanoparticles toward the substrate. The model predicted a power law dependence of the shrinkage rate on the particle height, with the exponent n = 3. The corresponding exponent determined from the experimental data was n = −2.9 ± 0.3, in excellent agreement with the theory. The low value of the effective self-diffusion coefficient along the lateral facets determined with the aid of our model (3.2 ± 0.2 × 10⁻¹⁷ m² s⁻¹) was attributed to the difficulties of step nucleation on atomically flat facets.