Synthesis, Characterization and Luminescence Properties of Rare Earth Complexes with Bis （Pyridinyl-Amide）

A ligand, N^1, N^4-di （ pyridin-2-yl ） succi- namide （L） and its lanthanide（ IH ） complexes （RE = La, Eu, Tb, Gd, Yb ） were synthesized and characterized in detail. The results indicate that the composition of the binary complexes is determined as [ REL （H2O）2（NO3）2] NO3, that the complexes are 1 ： 1 electrolytes in DMF, and that the Tb^3＋ complex has brightly green fluorescence in a solid state. At the same time, the energy levels of the excited triplet states for the six ligands were determined to be 22989 -1 cm . The fact that the ligand sensitize Tb^3＋ complexes was explained by the relative energy gap between the lowest triplet energy level of the ligand （T） and ^5Dj of Tb^3＋ or Eu^3＋ . When 2000 cm^-1 〈 △E（T-^5D4） 〈 3000 cm^-1, the luminescent intensity of the Tb^3＋ complex is stronger. When 3000 cm^-1〈 △E （T-^5D1）, the luminescent intensity of the Eu^3＋ complex is weak- er or close to nil. This means that the triplet energy level of the ligand is a chief factor that dominates RE^3＋ luminescence.     

Quantum Communication and Information Processing with Quantum Dots

This paper reviews the single photon sources based on semiconductor quantum dots and their applications to quantum information systems. By optically pumping a system consisting of a semiconductor single quantum dot confined in a monolithic microcavity, it is possible to produce a single photon pulse stream at the Fourier transform limit with a negligible jitter. This single photon source is not only useful for BB84 quantum key distribution (QKD), but also find applications in other quantum information systems such as Ekert91/BBM92 QKD and quantum teleportation gate linear optical quantum computers.     

双光子B-J模型中类克尔介质对量子态保真度的影响

研究了充满类克尔介质的高 Q腔中二能级原子与单模相干光场发生双光子相互作用 (双光子 B- J模型 )时 ,类克尔介质对该体系量子态保真度的影响。结果表明 :当类克尔介质与光场耦合较强时 ,原子的量子态保真度为 1,即原子处于退纠缠状态 ,此时光场对原子的作用被类克尔介质所屏蔽。     

LDA中光压对散射粒子跟随特性的影响

本文利用Ｍｉｅ散射理论和量子光学的方法对ＬＤＡ中强激光作用在散射粒子上的光压以及由此产生的粒子速度漂移进行了理论推导，并对在ｑ《１和γ》λ的情形下粒子速度的漂移进行了详细的计算。其结果表明：若入射激光的功率较大、散射粒子的尺度相对于激光波长较小时，光压将对沿入射光轴线方向的速度测量产生不可忽视的系统误差。     

应用单光子计数器测量尼龙－11的热释光

本文给出了一种适用于热蜂光测量的单光子计数器，并用该计数器对奇数尼龙－１１薄膜进行了实际测量．结果表明，本计数器完全满足测量微光（光功率＜１０－１５Ｗ）要求．     

光子学的内涵、发展与突破

论述了光子学、光子技术的产生、发展和突破，阐明了光子学的定义、内涵、范畴和前沿，提出了关于第Ⅰ类和第Ⅱ类光子产业的设想．     

高负载脉宽可调双池受激布里渊散射系统的实验研究

为了提高双池受激布里渊散射(SBS)系统的能量转换效率和负载能力,在布里渊放大池和产生池中选用布里渊频移接近的不同介质,利用Nd：YAG调Q激光对其特性进行了实验研究。与同种介质的双池系统相比,不仅能保持足够的能量转换效率,而且能够有效地提高其负载能力和稳定性。分析和讨论了双池间距对受激布里渊散射性能的影响。     

Sub-glassy relaxation modes in PMMA and PMMA + SiO<Subscript>2</Subscript> hosts of non-polar perylene derivatives

The dielectric response of poly(methyl methacrylate) (PMMA) in solid solutions of perylene derivative laser dyes in PMMA and PMMA + SiO₂ has been studied by means of the thermally stimulated depolarization currents (TSDC) technique, with the aim to isolate molecular and phase interactions in the dye blends. The changes in characteristics of the β-relaxation mode of PMMA are interpreted with respect to the dissimilar local environments of the polar carboxy-methyl pendant groups of PMMA. An important "chemical" effect on the β relaxation mechanism recorded in the organic-inorganic composites, is the formation of hydrogen bonds between the acidic pore surfaces of SiO₂ and the acetate side-groups. Several "physical" effects produced by the chromophores and the geometrical confinement, like the modification of the monomer-to-polymer conversion rates, the polymer's free volume and the extent of the PMMA-SiO₂ interaction, are discussed.     

气管滴注99mTc-C60(OH)x大鼠的SPECT显像观察

为了解C60(OH)x经呼吸道进入体内后的分布情况,用放射性标记技术和单光子发射计算机断层(Single photon emission computed tomography,SPECT)成像技术,研究了99mTc-C60(OH)x经气管滴注后在SD大鼠体内分布、吸收和代谢的情况,及其与纳米颗粒粒径的依赖关系.用99mTc标记了富勒烯多羟基衍生物C60(OH)x(x=22,24),标记率为93%.标记物在体外和体内都有良好的稳定性.比较了99mTc-C60(OH)x和Na99mTcO4经气管滴注后在SD大鼠体内的SPECT成像.结果表明,与水溶性的小分子Na99mTcO4不同,纳米尺度的99mTc-C60(OH)x标记物大多滞留于肺中,且清除缓慢;少部分99mTc-C60(OH)x能迅速通过肺泡-毛细管屏障进入血液,主要分布于肝、骨和脾中,并通过肾代谢排泄,显示了纳米颗粒生物分布的主要特征.由此可见,纳米颗粒穿越气血屏障的能力与颗粒物的粒径相关.研究结果为纳米颗粒的呼吸毒性研究提供了重要基础资料.