全文获取类型
收费全文 | 1819篇 |
免费 | 276篇 |
国内免费 | 191篇 |
专业分类
电工技术 | 57篇 |
综合类 | 108篇 |
化学工业 | 164篇 |
金属工艺 | 31篇 |
机械仪表 | 172篇 |
建筑科学 | 10篇 |
矿业工程 | 5篇 |
能源动力 | 15篇 |
轻工业 | 27篇 |
水利工程 | 2篇 |
石油天然气 | 17篇 |
武器工业 | 2篇 |
无线电 | 928篇 |
一般工业技术 | 468篇 |
冶金工业 | 30篇 |
原子能技术 | 156篇 |
自动化技术 | 94篇 |
出版年
2024年 | 12篇 |
2023年 | 49篇 |
2022年 | 32篇 |
2021年 | 66篇 |
2020年 | 83篇 |
2019年 | 75篇 |
2018年 | 78篇 |
2017年 | 89篇 |
2016年 | 74篇 |
2015年 | 98篇 |
2014年 | 106篇 |
2013年 | 156篇 |
2012年 | 121篇 |
2011年 | 129篇 |
2010年 | 81篇 |
2009年 | 73篇 |
2008年 | 115篇 |
2007年 | 95篇 |
2006年 | 89篇 |
2005年 | 82篇 |
2004年 | 83篇 |
2003年 | 58篇 |
2002年 | 56篇 |
2001年 | 69篇 |
2000年 | 53篇 |
1999年 | 39篇 |
1998年 | 35篇 |
1997年 | 23篇 |
1996年 | 26篇 |
1995年 | 24篇 |
1994年 | 15篇 |
1993年 | 18篇 |
1992年 | 16篇 |
1991年 | 17篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 1篇 |
1985年 | 7篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1959年 | 2篇 |
1958年 | 1篇 |
排序方式: 共有2286条查询结果,搜索用时 15 毫秒
221.
Hameed A. Al‐Attar Gareth C. Griffiths Tom N. Moore Mustafa Tavasli Mark A. Fox Martin R. Bryce Andrew P. Monkman 《Advanced functional materials》2011,21(12):2376-2382
A new family of highly soluble electrophosphorescent dopants based on a series of tris‐cyclometalated iridium(III) complexes (1–4) of 2‐(carbazol‐3‐yl)‐4/5‐R‐pyridine ligands with varying molecular dipole strengths have been synthesized. Highly efficient, solution‐processed, single‐layer, electrophosphorescent diodes utilizing these complexes have been prepared and characterized. The high triplet energy poly(9‐vinylcarbazole) PVK is used as a host polymer doped with 2‐(4‐biphenylyl)‐5‐(4‐tert‐butyl‐phenyl)‐1,3,4‐oxadiazole (PBD) for electron transport. Devices with a current efficiency of 40 cd A?1 corresponding to an EQE of 12% can thus be achieved. The effect of the type and position of the substituent (electron‐withdrawing group (CF3) and electron‐donating group (OMe)) on the molecular dipole moment of the complexes has been investigated. A correlation between the absorption strength of the singlet metal‐to‐ligand charge‐transfer (1MLCT) transition and the luminance spectral red shift as a function of solvent polarity is observed. The strength of the transition dipole moments for complexes 1–4 has also been obtained from TD‐DFT computations, and is found to be consistent with the observed molecular dipole moments of these complexes. The relatively long lifetime of the excitons of the phosphorescence (microseconds) compared to the charge‐carrier scattering time (less than nanoseconds), allows the transition dipole moment to be considered as a “quasi permanent dipole”. Therefore, the carrier mobility is sufficiently affected by the long‐lived transition dipole moments of the phosphorescent molecules, which are randomly oriented in the medium. The dopant dipoles cause positional and energetic disorder because of the locally modified polarization energy. Furthermore, the electron‐withdrawing group CF3 induces strong carrier dispersion that enhances the electron mobility. Therefore, the strong transition dipole moment in complexes 3 and 4 perturbs both electron and hole mobilities, yielding a reduction in exciton formation and an increase in the device dark current, thereby decreasing the device efficiency. 相似文献
222.
Shaolong Gong Yonghua Chen Jiajia Luo Chuluo Yang Cheng Zhong Jingui Qin Dongge Ma 《Advanced functional materials》2011,21(6):1168-1178
A series of tetraarylsilane compounds, namely p‐BISiTPA ( 1 ), m‐BISiTPA ( 2 ), p‐OXDSiTPA ( 3 ), m‐OXDSiTPA ( 4 ), are designed and synthesized by incorporating electron‐donating arylamine and electron‐accepting benzimidazole or oxadiazole into one molecule via a silicon‐bridge linkage mode. Their thermal, photophysical and electrochemical properties can be finely tuned through the different groups and linking topologies. The para‐disposition compounds 1 and 3 display higher glass transition temperatures, slightly lower HOMO levels and triplet energies than their meta‐disposition isomers 2 and 4 , respectively. The silicon‐interrupted conjugation of the electron‐donating and electron‐accepting segments gives these materials the following advantages: i) relative high triplet energies in the range of 2.69–2.73 eV; ii) HOMO/LUMO levels of the compounds mainly depend on the electron‐donating and electron‐accepting groups, respectively; iii) bipolar transporting feature as indicated by hole‐only and electron‐only devices. These advantages make these materials ideal universal hosts for multicolor phosphorescent OLEDs. 1 and 3 have been demonstrated as universal hosts for blue, green, orange and white electrophosphorescence, exhibiting high efficiencies and low efficiency roll‐off. For example, the devices hosted by 1 achieve maximum external quantum efficiencies of 16.1% for blue, 22.7% for green, 20.5% for orange, and 19.1% for white electrophosphorescence. Furthermore, the external quantum efficiencies are still as high as 14.2% for blue, 22.4% for green, 18.9% for orange, and 17.4% for white electrophosphorescence at a high luminance of 1000 cd m?2. The two‐color, all‐phosphor white device hosted by 3 acquires a maximum current efficiency of 51.4 cd A?1, and a maximum power efficiency of 51.9 lm W?1. These values are among the highest for single emitting layer white PhOLEDs reported till now. 相似文献
223.
A new approach based on microcantilevers is presented to detect infrared photons with high sensitivity. Infrared photons are measured by monitoring the amplitude change of a vibrating microcantilever under light pressure force.The irradiating light is modulated into sinusoidal and pulsed waves,and to be in-phase and anti-phase with the cantilever driving signal.A linear relationship between the amplitude change of the cantilever and the light power distributing on the cantilever was observed.Under a vacuum of 10-4 Pa,an infrared light power of 7.4 nW was detected with the cantilever.The in-phase and anti-phase modulation to the cantilever vibration using a pulsed light results in an enhanced response of the cantilever. 相似文献
224.
225.
提出了一种利用玻色-爱因斯坦凝聚体中三能级原子与一束较弱的相干态探测光和一束较强的经典耦合光相互作用产生受激拉曼跃迁制备原子-光子杂化纠缠态的理论方案。研究了探测光场与原子间的相互作用强度、双光子失谐量和处在基态的原子间的相互作用强度对制备杂化纠缠态的影响。结果表明,通过增加探测光场与原子间的相互作用强度或减小双光子失谐量,能够更快地制备纠缠程度更高的原子-光子杂化纠缠态。 相似文献
226.
白色磷光OLEDs的制备及性能研究 总被引:3,自引:3,他引:0
采用蓝色、黄色磷光混色的发光方式实现白光有机电致发光器件(OLEDS),其中黄色发光层由红色和绿色磷光材料混合而成,器件的结构为ITO/MoO3(30nm)/NPB(40nm)/mCP:FIrpic(8%)(50nm)/CBP:R-4B(1%):GIrl(14%)(xnm)/BCP(10nm)/AlQ(40nm)/LiF(1nm)/Al(100nm)(x=2,3,4,5,6nm)。对器件的效率、亮度等对比发现,当x=5nm时,器件的性能最佳,最大亮度为9 471cd/cm2,效率为23.5cd/A,色坐标(0.32,0.35)。实验表明,影响器件色稳定性和效率低的原因是电子和空穴迁移随驱动电压变化响应不一致引发激子复合区域的移动。 相似文献
227.
激光过程中真空态和单光子叠加态的量子特性 总被引:2,自引:2,他引:0
采用热纠缠态表象和有序算符内的积分技术,通过求解密度矩阵主方程,导出了真空态和单光子叠加态在激光过程中的Wigner函数和光子数分布的解析表达式。采用数值计算方法,给出了腔场的增益和衰减常数等参数取确定值时真空态和单光子叠加态的Wigner函数、负部体积和光子数分布的演化曲线。通过比较Wigner函数负值区域的变化,讨论了耗散过程对该量子态量子特性的影响。研究结果表明:随耗散过程进行,态的Wigner函数负值范围和负值深度都在逐渐减小,直至负值消失。 相似文献
228.
Jun Ye Kai Wang Zhan Chen Fei-Fei An Yi Yuan Chi Zhang Xiao-Hong Zhang Chun-Sing Lee 《Organic Electronics》2014,15(12):3514-3520
A novel device concept was realized for simple single-layer small-molecule white organic light emitting devices. The single organic active layer here is simply comprised of a newly synthesized sky-blue fluorescent bipolar host (TPASO) and a common orange phosphorescent dopant. Suppressed singlet Föster energy transfer induced by a low-concentration doping and spontaneous high- to low-lying triplet energy transfer, respectively, lead to sky-blue fluorescence from TPASO and orange phosphorescence from the dopant. The resulting two-organic-component device exhibits a low turn-on voltage of 2.4 V, maximum current/power efficiencies up to 11.27 ± 0.02 cd A−1 and 14.15 ± 0.03 lm W−1, and a warm-white CIE coordinate of (0.42, 0.45) at 1000 cd m−2. 相似文献
229.
Solution‐Processible 2,2′‐Dimethyl‐biphenyl Cored Carbazole Dendrimers as Universal Hosts for Efficient Blue,Green, and Red Phosphorescent OLEDs 下载免费PDF全文
Xingdong Wang Shumeng Wang Zhihua Ma Junqiao Ding Lixiang Wang Xiabin Jing Fosong Wang 《Advanced functional materials》2014,24(22):3413-3421
A series of solution‐processible 2,2′‐dimethyl‐biphenyl cored dendrimers, namely G1MP, G2MP, and G3MP, is designed and synthesized by tuning the generation of periphery carbazole dendron. The resulting dendrimers all show excellent solubility in common organic solvents, and their high‐quality thin films can be formed via spin‐coating with a root‐mean‐square roughness in the range of 0.38–0.54 nm. G3MP, which contains the third‐generation carbazole dendron, has the greatest potential among those made here as an ideal universal host for multicolored triplet emitters. G3MP exhibits good thermal stability, with a glass transition temperature of 368 °C, a triplet energy as high as 2.85 eV enough to prevent the loss of triplet excitons, and suitable HOMO/LUMO levels of –5.30/–2.11 eV to facilitate both hole and electron injection and transport. When using G3MP as the host, highly efficient deep‐blue, blue, green, and red phosphorescent organic light‐emitting diodes (PhOLEDs) are successfully demonstrated, revealing a maximum luminous efficiency up to 18.2, 28.2, 54.0, and 12.7 cd A–1 with the corresponding Commission Internationale de L'Eclairage (CIE) coordinates of (0.15, 0.23), (0.15, 0.35), (0.38, 0.59), and (0.64, 0.34), respectively. The state‐of‐art performance indicates that dendritic hosts have a favorable prospect of applications in solution‐processed white PhOLEDs and full‐color displays. 相似文献
230.
Superparamagnetic Twist‐Type Actuators with Shape‐Independent Magnetic Properties and Surface Functionalization for Advanced Biomedical Applications 下载免费PDF全文
Christian Peters Olgaç Ergeneman Pedro D. Wendel García Michelle Müller Salvador Pané Bradley J. Nelson Christofer Hierold 《Advanced functional materials》2014,24(33):5269-5276
Directed nanoparticle self‐organization and two‐photon polymerization are combined to enable three‐dimensional soft‐magnetic microactuators with complex shapes and shape‐independent magnetic properties. Based on the proposed approach, single and double twist‐type swimming microrobots with programmed magnetic anisotropy are demonstrated, and their swimming properties in DI‐water are characterized. The fabricated devices are actuated using weak rotating magnetic fields and are capable of performing wobble‐free corkscrew propulsion. Single twist‐type actuators possess an increase in surface area in excess of 150% over helical actuators with similar feature size without compromising the forward velocity of over one body length per second. A generic and facile combination of glycine grafting and subsequent protein immobilization exploits the actuator's increased surface area, providing for a swimming microrobotic platform with enhanced load capacity desirable for future biomedical applications. Successful surface modification is confirmed by FITC fluorescence. 相似文献