光子晶体的研究与应用

光子晶体是一种具有光子能带及能隙的新型材料。其特有的性质,使光子晶体具有广阔的应用前景。本文基于固体物理学的基本原理,对光子晶体的理论基础进行了简单介绍,根据其特有结构,对光子晶体的特性做了一定分析,并结合现实需要,综述了光子晶体在光学等方面的应用。     

光子晶体的研究与应用

光子晶体是一种具有光子能带及能隙的新型材料。其特有的性质,使光子晶体具有广阔的应用前景。本文基于固体物理学的基本原理,对光子晶体的理论基础进行了简单介绍,根据其特有结构,对光子晶体的特性做了一定分析,并结合现实需要,综述了光子晶体在光学等方面的应用。     

光子“四端管”模型实验研究及其应用──新事滤波器的模型研究

在文献［１］的积分型光子“晶体管”的模型研究的基础上,利用螺塞喃光致色变材料进行了积分型“光子四端管”的模型实验研究,并对其应用器件之一——新事滤波器进行了详细的模型论证与研究。     

光纤电压传感器传感头优化与热致非互易误差抑制

针对普通光纤电压传感器在外界温度扰动下其输出精度和稳定性会受到严重影响这一问题,本文提出了一种采用保偏光子晶体光纤(polarization maintaining photonic crystal fiber,PM-PCF) 作为传感光纤的传感头优化方法抑制温度扰动下的系统非互易误差。在综合考虑PM-PCF与传统熊猫型保偏光纤(panda polarization maintaining fiber,panda-PMF) 尾纤间的熔接损耗、传输损耗以及现有工艺条件下的光纤制备等问题的基础上,优化得到了与panda-PMF间的熔接损耗低至0.14 dB的PM-PCF;并对比分析了这两种保偏光纤的双折射温度依赖特性,建立了全光纤类型的光学电压传感器(fiber optic voltage sensor,FOVS) 热致系统误差输出模型,分析验证了PM-PCF在解决反射式逆压电型FOVS热致非互易问题的可行性。结果表明,采用PM-PCF优化后的FOVS热致非互易误差约是传统保偏光纤电压传感器 的10-2量级。这在提高系统输出精度和稳定性等方面具有显著优势,同时这种低损耗的优化方法在光纤传感及通信等领域具有重要的应用价值。     

Nanoheterojunction Engineering Enables NIR-II-Triggered Photonic Hyperthermia and Pyroelectric Catalysis for Tumor-Synergistic Therapy

Photodynamic therapy (PDT) as a non-invasive strategy shows high promise in cancer treatment. However, owing to the hypoxic tumor microenvironment and light irradiation-mediated rapid electron–hole pair recombination, the therapeutic efficacy of PDT is dramatically discounted by limited reactive oxygen species (ROS) generation. Herein, a multifunctional theranostic nanoheterojunction is rationally developed, in which 2D niobium carbide (Nb₂C) MXene is in situ grown with barium titanate (BTO) to generate a robust photo-pyroelectric catalyst, termed as BTO@Nb₂C nanosheets, for enhanced ROS production, originating from the effective electron–hole pair separation induced by the pyroelectric effect. Under the second near-infrared (NIR-II) laser irradiation, Nb₂C MXene core-mediated photonic hyperthermia regulates temperature variation around BTO shells facilitating the electron–hole spatial separation, which reacts with the surrounding O₂ and H₂O molecules to yield toxic ROS, achieving a synergetic effect by means of combinaterial photothermal therapy with pyrocatalytic therapy. Correspondingly, the engineered BTO@Nb₂C composite nanosheets feature benign biocompatibility and high antitumor efficiency with the tumor-inhibition rate of 94.9% in vivo, which can be applied as an imaging-guided real-time non-invasive synergetic dual-mode therapeutic nanomedicine for efficient tumor nanotherapy.     

Electret Molecular Configuration Induced Programmable Photonic Memory for Advanced Logic Operation and Data Encryption

Nonvolatile organic photonic transistor (OPT) memories have attracted widespread attention due to their nondestructive readout, remote controllability, and robust tunability. Developing electrets with similar molecular structures but different memory behaviors and light-responsive features is crucial for light-wavelength-modulated data encryption. However, reported OPT memories have yet to meet this challenge. Here a new electret molecule (“H-PDI”) is developed via reconfiguring the linear perylene diimide molecule (“L-PDI”) to a helical shape. Respectively incorporating H-PDI and L-PDI into the floating gate layer results to H-PDI OPT and L-PDI OPT. Attributing to their remarkably different electronic structures and energy bandgaps, H-PDI OPT and L-PDI OPT preferably respond to 405 and 532 nm light irradiation, respectively. Upon electrical programming, data can be written and stored in both memories with good retention features and a high “1”/“0” state current ratio over 10⁵, though the data can only be erased by light with correct wavelengths, rather than the electrical field. Moreover, data stored in a memory array consisting of both H-PDI OPT and L-PDI OPT can only be read out by correct inputs, and wrong inputs will lead to highly deceptive outputs. This study provides a general design strategy of OPT for advanced data encryption and protection.     

基于太赫兹布拉格光纤的表面生物传感器

空心布拉格光纤在传感领域应用极为广泛。本文提出了一种基于带有缺陷层的太赫 兹(terahertz,THz)空心布拉格光纤的表面生物传感器,并对该传感器在太赫兹频段的细菌种类检测性能进行 分析。在太赫兹布拉格光纤中,高折射率光敏树脂层和低折射率空气层以纤芯为中心周期性 排列,在纤芯内壁沉积分析物引入缺陷模式。本文对提出的传感器性能进行了数值研究。仿 真结果表明,该传感器有很高的纤芯功率比,限制损耗在0.3 THz和0.45 TH z频 段有损耗峰,能得到可识别的特征频率,此特征频率用于细菌种类检测。当频率大于0.7 TH z时,该传感器可实现厚度无关的表面生物传感。本文所提出的基于太赫兹空心布拉格光纤 的 表面生物传感器可用于检测细菌种类,在微生物检测方面有很大的应用潜力。     

新型星载超宽带微波光子变频技术

传统的星载变频通道存在易受电磁干扰、动态范围受限、带宽瓶颈等不足,将微波光子技术引入卫星通信系统中,可克服电域信号变频的局限性,提升星载变频通道的性能。文章提出了一种基于并联马赫-增德尔调制器(MZM)与相干接收的宽带微波光子变频技术,通过采用相干接收方法,能够实现较好的共模噪声抑制,并降低谐波失真的影响,同时结合抑制载波调制方式所带来的优势,有效改善了变频无杂散动态范围等指标。通过实验验证,其杂散抑制比优于60 dB,无杂散动态范围优于100 dB·Hz2/3,为新型星载微波光子变频方案设计、实际应用提供了必要的理论依据与技术支撑。     

Photonic Crystal Palette of Binary Block Copolymer Blends for Full Visible Structural Color Encryption

Structural color (SC) arising from a periodically ordered self-assembled block copolymer (BCP) photonic crystal (PC) is useful for reflective-mode sensing displays owing to its capability of stimuli-responsive structure alteration. However, a set of PC inks, each providing a precisely addressable SC in the full visible range, has rarely been demonstrated. Here, a strategy for developing BCP PC inks with tunable structures is presented. This involves solution-blending of two lamellar-forming BCPs with different molecular weights. By controlling the mixing ratio of the two BCPs, a thin 1D BCP PC film is developed with alternating in-plane lamellae whose periodicity varies linearly from ≈46 to ≈91 nm. Subsequent preferential swelling of one-type lamellae with either solvent or non-volatile ionic liquid causes the photonic band gap of the films to red-shift, giving rise to full-visible-range SC correlated with the pristine nanostructures of the blended films in both liquid and solid states. The BCP PC palette of solution-blended binary solutions is conveniently employed in various coating processes, allowing facile development of BCP SC on the targeted surface. Furthermore, full-color SC paintings are realized with their transparent PC inks, facilitating low-power pattern encryption.