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41.
You-Yi Xia 《Materials Letters》2007,61(21):4321-4324
This paper describes a solution-phase approach to the synthesis of selenium nanoparticles by reducing selenious acid solution with ascorbic acid in the presence of silk fibroin. The monodispersed spherical selenium colloid particles obtained were very stable in silk fibroin solution and characterized by Atomic force microscopy and X-ray techniques. The influences of temperature and ultrasonication on the morphology of selenium nanoparticles were also discussed. The experiments showed that the selenium nanoparticles with various morphologies could be obtained under different temperatures and the appropriate ultrasonication time was 60 min. This result indicated that the silk fibroin molecules intimately associated with the surface of the selenium particles and controlled the growth particles. 相似文献
42.
43.
UV法测定聚甲基丙烯酸酯纳米粒中胰岛素的包封率 总被引:3,自引:0,他引:3
建立一种简便易行的测定聚甲基丙烯酸酯胰岛素纳米粒中游离胰岛素含量方法.用Nanosep OD100C33超滤膜分离纳米粒和游离药物,在276 nm处测定药物的吸光度,建立胰岛素含量测定方法,并对线性、回收率、精密度等指标进行考察,最后测定各种胰岛素和载体比例混合的纳米粒的包封率.结果发现,该超滤膜能较好地分离纳米粒和游离的药物,在0.11~1.10 u/mL范围内,药物在276 nm的吸光度和浓度存在良好的线性关系(r=0.999 8),线性方程为A=0.868 8C-0.001 6,高、中、低3种浓度的回收率和精密度良好.该方法操作简单、结果可靠,可用于胰岛素纳米粒中药物包封率的测定. 相似文献
44.
45.
Core–shell type nanoparticles of poly(L ‐lactide)/poly(ethylene glycol) (LE) diblock copolymer were prepared by a dialysis technique. Their size was confirmed as 40–70 nm using photon correlation spectroscopy. The 1H‐NMR analysis confirmed the formation of core–shell type nanoparticles and drug loading. The particle size, drug loading, and drug release rate of the LE nanoparticles were slightly changed by the initial solvents that were used. The drug release behavior of LE core–shell type nanoparticles showed an initial burst during the first 12 h and then a sustained release until 100 h. The degradation behavior of LE block copolymer nanoparticles was divided into three phases: the initial rapid degradation phase, the stationary phase, and the rapid degradation phase until complete degradation. It was suggested that lidocaine release kinetics were predominantly governed by the diffusion mechanism in the initial burst phase and after that by both of the diffusion and degradation mechanisms. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2625–2634, 2002 相似文献
46.
Hydrothermal synthesis and in situ surface modification of boehmite nanoparticles in supercritical water 总被引:2,自引:1,他引:1
T. Mousavand S. Ohara M. Umetsu J. Zhang S. Takami T. Naka T. Adschiri 《The Journal of Supercritical Fluids》2007,40(3):397-401
In situ surface modification of boehmite (AlOOH) nanoparticles during hydrothermal synthesis in supercritical water was examined by adding CH3(CH2)4CHO and CH3(CH2)5NH2 as modifier reagents to the reactants. Changes in surface properties of the nanoparticles by surface modification was observed by FTIR, dispersion in solvents and TEM analyses, which demonstrated that reagents chemically binded onto the surface of the AlOOH nanoparticles. The results of SEM and TEM pictures show that the surface modification affects crystal growth and reduces the particle size and changes the morphology of the particles. 相似文献
47.
Zhufang Liu Mohammad Shamsuzzoha Earl T. Ada W. Matthew Reichert David E. Nikles 《Journal of power sources》2007
Well-dispersed Pt nanoparticles with controlled size and narrow size distribution were prepared by polyalcohol reduction of platinum acetylacetonate, using oleylamine as a capping agent. The particle size was varied from 3.5 nm to 11.5 nm by decreasing the amount of oleylamine added in the synthesis. Size selection of the as-prepared particles by solvent fractionation yielded nearly monodispersed Pt particles. The as-prepared particles were loaded on a carbon support by physical deposition, but showed no electrocatalytic activity due to the oleylamine bound to the particle surface. The particles were activated for electrocatalysis after heating the particles in air at 185 °C for 5 h, conditions that gave no particle-sintering and no oxidation. Cyclic voltammetry showed that the particles after the heat treatment in air were electrocatalytically active for methanol oxidation. The smaller 3.5 nm and 4.0 nm Pt particles had a higher intrinsic activity for methanol oxidation, but a lower tolerance to CO poisoning, compared with 6.0 nm, 9.5 nm and 11.5 nm particles. CO-stripping results suggest that CO is more easily oxidized on larger Pt particles. 相似文献
48.
Development of nano indium tin oxide (ITO) grains by alkaline hydrolysis of In(III) and Sn(IV) salts
Indium tin oxide (ITO) nano powders of different compositions (In: Sn = 90: 10, 70: 30 and 50: 50) were prepared by heat treatment
(300-450°C) of mixed hydroxides of In(III) and Sn(IV). The hydroxides were obtained by the reaction of aq. NH3 with mixed aq. solutions of In(NO3)3 and SnCl4. FTIR and TG/DTA studies revealed that powders existed as In(OH)3H2O—SnO3H2H2O in the solid state and then they transformed to In2O3—SnO2 via some metastable intermediates after 300°C. Cubic phase of In2O3 was identified by XRD for the oxides up to 30% of Sn. Particle size measurements of the solid dispersed in acetone and SEM
study for microstructure showed that the oxides were in the nano range (55-75 nm) whereas the size range determined from Debye-Scherrer
equation were 11–24 nm. 相似文献
49.
In this paper we discuss the different models proposed to explain the visible luminescence in porous silicon (PS). We review
our recent photoluminescence and Raman studies on PS as a function of different preparation conditions and isochronal thermal
annealing. Our results can be explained by a hybrid model which incorporates both nanostructures for quantum confinement and
silicon complexes (such as SiH
x
and siloxene) and defects at Si/SiO2 interfaces as luminescent centres. 相似文献
50.
LIU Guangzhen MA Zhanfang SHEN Jianquan 《武汉理工大学学报(材料科学英文版)》2006,21(4):16-18
1 IntroductionGold nanoparticles have attracted considerable atten-tionin manyfields duetotheir some special properties al-though goldis very popularfor beingchemicallyinert[1-3].For example ,gold nanoparticles as amplificationtags havebeenthe subject of research directed at gene analysis[4]and antibody or antigen detection[5-7]due to the large di-electric constant ,ease of preparation,andits biocompati-bility[8].Nanoparticles in the range of 1-10 nmin diameterwould display electronic structur… 相似文献