全文获取类型
收费全文 | 11828篇 |
免费 | 2315篇 |
国内免费 | 301篇 |
专业分类
电工技术 | 120篇 |
综合类 | 302篇 |
化学工业 | 5081篇 |
金属工艺 | 644篇 |
机械仪表 | 272篇 |
建筑科学 | 80篇 |
矿业工程 | 50篇 |
能源动力 | 768篇 |
轻工业 | 599篇 |
水利工程 | 11篇 |
石油天然气 | 191篇 |
武器工业 | 7篇 |
无线电 | 1348篇 |
一般工业技术 | 4423篇 |
冶金工业 | 281篇 |
原子能技术 | 81篇 |
自动化技术 | 186篇 |
出版年
2024年 | 77篇 |
2023年 | 464篇 |
2022年 | 529篇 |
2021年 | 759篇 |
2020年 | 740篇 |
2019年 | 686篇 |
2018年 | 755篇 |
2017年 | 785篇 |
2016年 | 777篇 |
2015年 | 755篇 |
2014年 | 934篇 |
2013年 | 1107篇 |
2012年 | 843篇 |
2011年 | 977篇 |
2010年 | 650篇 |
2009年 | 713篇 |
2008年 | 642篇 |
2007年 | 504篇 |
2006年 | 451篇 |
2005年 | 347篇 |
2004年 | 196篇 |
2003年 | 165篇 |
2002年 | 113篇 |
2001年 | 91篇 |
2000年 | 101篇 |
1999年 | 43篇 |
1998年 | 40篇 |
1997年 | 23篇 |
1996年 | 36篇 |
1995年 | 19篇 |
1994年 | 28篇 |
1993年 | 15篇 |
1992年 | 17篇 |
1991年 | 17篇 |
1990年 | 11篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1976年 | 3篇 |
1951年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
71.
Understanding the Influence of Copper Nanoparticles on Thermal Characteristics and Microstructural Development of a Tin-Silver Solder 总被引:1,自引:0,他引:1
D.C. Lin T.S. Srivatsan G-X. Wang R. Kovacevic 《Journal of Materials Engineering and Performance》2007,16(5):647-654
This paper presents and discusses issues relevant to solidification of a chosen lead-free solder, the eutectic Sn-3.5%Ag,
and its composite counterparts. Direct temperature recordings for the no-clean solder paste during the simulated reflow process
revealed a significant amount of undercooling to occur prior to the initiation of solidification of the eutectic Sn-3.5%Ag
solder, which is 6.5 °C, and for the composite counterparts, it is dependent on the percentage of copper nanopowder. Temperature
recordings revealed the same temperature level of 221 °C for both melting (from solid to liquid) and final solidification
(after recalescence) of the Sn-3.5%Ag solder. Addition of copper nanoparticles was observed to have no appreciable influence
on melting temperature of the composite solder. However, it does influence solidification of the composite solder. The addition
of 0.5 wt.% copper nanoparticles lowered the solidification temperature to 219.5 °C, while addition of 1.0 wt.% copper nanoparticles
lowered the solidification temperature to 217.5 °C, which is close to the melting point of the ternary eutectic Sn-Ag-Cu solder
alloy, Sn-3.7Ag-0.9Cu. This indicates the copper nanoparticles are completely dissolved in the eutectic Sn-3.5%Ag solder and
precipitate as the Cu6Sn5, which reinforces the eutectic solder. Optical microscopy observations revealed the addition of 1.0 wt.% of copper nanoparticles
to the Sn-3.5%Ag solder results in the formation and presence of the intermetallic compound Cu6Sn5. These particles are polygonal in morphology and dispersed randomly through the solder matrix. Addition of microsized copper
particles cannot completely dissolve in the eutectic solder and projects a sunflower morphology with the solid copper particle
surrounded by the Cu6Sn5 intermetallic compound coupled with residual porosity present in the solder sample. Microhardness measurements revealed the
addition of copper nanopowder to the eutectic Sn-3.5%Ag solder resulted in higher hardness. 相似文献
72.
73.
Yb2O3/TiO2纳米颗粒的制备及表征 总被引:13,自引:0,他引:13
采用溶胶-凝胶法制备了微量 Yb2O3掺杂纳米 TiO2颗粒,采用 XRD, TG-DTA, TEM等手段对试样经不同温度热处理后的结构相变、表面形貌、颗粒大小等特性进行了表征.实验表明温度不高于 400℃时,试样的颗粒粒径较小,粒径在 15 nm以下,比表面积大于 107.22 m2@ g-1, TiO2呈锐钛型;在 400℃以上, TiO2粒径迅速增大,微粒出现锐钛相与金红石相混晶结构;800℃时 TiO2微粒完全转化成金红石相. 相似文献
74.
巯基活性炭分离富集发射光谱法同时测定金、铂、钯和铊 总被引:1,自引:0,他引:1
研究了巯基活性炭在盐酸介质中对金、铂、钯和铊的吸附能力。该法具有吸附速度快、吸附容量大、在一定条件下,普通金属不被吸附的特点,可用于分离富集各类矿物中微量贵金属。吸附后巯基活性炭低温灰化,与缓冲剂混合发射光谱法同时测定金、铂、钯和铊,选择锆作内标线,直接压样于杯形的石墨电极中,该方法简便、快速、准确。对测定条件、干扰因素进行了研究,从而建立测定金、铂、钯和铊的新方法。金、铂、钯和铊的分析线分别为312.3nm,306.5nm,311.4nm和313.1nm,内标线选择为310.7nm的锆,金、铂、钯和铊的线性范围(原子百分数)分别为0~0.20%,0~0.40%,0~0.20%和0~0.40%。金、铂、钯和铊的检测限分别0.01%,0.003%,0.003%和0.001%。用于样品的测定获得满意结果。 相似文献
75.
采用简单的溶液还原方法,以聚乙烯吡咯烷酮(PVP,MW=58,000)作为高分子表面修饰剂,用水合肼(50%)作为还原剂,经回流处理,成功地制备出了分散性较好的钻纳米颗粒。利用XRD、TEM、SQUID等实验方法对产物的形貌、物相及磁性进行了表征。结果表明,产物为六方结构。其饱和磁化强度为153emu/g-1.62μB/Co,是体相材料的饱和磁矩的95%,其矫顽力为5174A·m^-1。此方法的优点在于反应条件温和、成本较低,重复性强、产率高且宜于控制。 相似文献
76.
The epoxidation of β-ionone over the Pt/MCM-41 catalyst using molecular oxygen in the liquid phase had been studied. The results
indicated that the β-ionone was catalytically oxidized to 5,6-epoxy-β-ionone, 4-oxo-β-ionone, 4-hydroxy-β-ionone and dihydroactinidiolide
using molecular oxygen as the sole oxidant. The effects of solvent, content of Pt, reaction temperature and time on the catalytic
activity and product selectivity had also been investigated in detail. 相似文献
77.
A series of iron oxide doped norbornene (NOR)/deuterated norbornene dicarboxylic acid (NORCOOH) diblock copolymers were synthesized and characterized by X-ray photoelectron spectroscopy (XPS), small angle neutron scattering (SANS) and superconducting quantum interference device (SQUID) experiments. γ-Fe2O3 nanoparticles were synthesized within the microdomains of diblock copolymers with volume fractions of NOR/NORCOOH 0.64/0.36, 0.50/0.50 and 0.40/0.60. A spherical nanoparticle morphology was displayed in the polymer with 0.64/0.36 volume fraction. Polymers with 0.50/0.50 and 0.40/0.60 volume fractions exhibited interconnected metal oxide nanostructures. The observed changes in the shape and peak positions of the small-angle neutron scattering profiles of polymers after metal doping were related to the scattering from the metal oxide particles and to the possible deformed morphologies due to the strong interparticle interactions between metal particles, which may influence the polymer microphase separation. The combined scattering from both polymer domains and magnetic particles was depicted in SANS profiles of metal oxide doped polymers. γ-Fe2O3 containing block copolymers were superparamagnetic at room temperature. An increase in the blocking temperature (Tb) of interconnected nanoparticles was observed and was related to the interparticle interactions, which depends on the average distance (d) between particles and individual particle diameter (2R). The sample with volume fraction of 0.4/0.6 have the lowest d/(2R) ratio and exhibit the highest Tb at 115 K. 相似文献
78.
Borgna A. Le Normand F. Garetto T. Apesteguia C. R. Moraweck B. 《Catalysis Letters》1992,13(3):175-188
The effect of an oxidative atmosphere (300 °C) is studied on fresh and sintered unchlorinated naphtha reforming catalysts containing 0.6–1% Pt. The TPR profiles show that only one species is formed using our experimental conditions, regardless of the mean crystallite size of the metal particles. The structural information supplied by EXAFS compared with cuboctahedral particle modeling, implies that such species is a surface platinum oxide, the structure of which is close to that of PtO2, but largely distorted. This is true whether the catalyst is sintered or not. 相似文献
79.
SiO2·Bi2O3对NiZn铁氧体的烧结和磁性能的影响 总被引:2,自引:0,他引:2
本文采用溶胶-凝胶法制备NiZn铁氧体-SiO2·Bi2O3复合材料。结果表明:烧结过程中Bi2O3与SiO2形成非晶态玻璃相促进烧结,使瓷体烧结温度降至1030℃,并且瓷体的磁导率随非磁性玻璃相的增加显著减少。磁导率的变化主要是由于非磁性相的引入导致磁路隔断、退磁场增加以及铁氧体晶粒减小所致。加入适量非磁性相有助于改善瓷体的高频特性。 相似文献
80.
为提高石蜡相变乳液的传热性能,通过添加氧化石墨烯(GO),制备了GO/石蜡复合相变乳液并对其相关性能进行了表征。搭建了流动阻力、对流换热试验台,对比研究了石蜡相变乳液及GO/石蜡复合相变乳液的流动阻力特性和对流换热特性,试验结果表明,由于GO的亲水性,复合相变乳液都表现出较好的稳定性。当GO的质量分数为0.01%、0.02%、0.03%时,复合相变乳液的热导率分别增加了20.01%、30.50%、35.18%。添加GO使乳液的流动阻力略有增加,直管段最大增加了6.70%,90°弯管处最大增加了13.20%;对流传热系数随着GO浓度的增加而增大,当GO浓度为0.03%时,对流传热系数最大提高了43.90%。 相似文献