碳纤维/乙烯基酯树脂复合材料拉伸性能研究

研究了碳纤维进行氧化处理、铺层形式,以及紫外光照射和不同溶液介质浸泡处理等,对碳纤维/乙烯基酯树脂复合材料拉伸性能的影响。结果表明:碳纤维最佳氧化工艺为浓硝酸氧化1 h,空气氧化温度250℃,空气氧化30 min。碳纤维最佳铺层设计为[0°, 0°,45°]_2s。随紫外光照射时间增加,复合材料拉伸强度呈先增后降趋势,120 h时达最大值。溶液介质浸泡会降低复合材料的拉伸强度。温度相同溶液介质不同时,复合材料在NaOH溶液中拉伸强度降低程度最大,温度提高会加速复合材料失效老化。     

O'-Sialon/BN和O'-Sialon/ZrO2复合材料抗熔融金属和保护渣侵蚀

研究了O'-Siaion/BN和O'-Sialon/ZrO₂复合材料抗熔融金属和保护法侵蚀.结果表明:O'-Sialon/BN复合材料抗钢水侵蚀的动力学分为两段控制:前期为界面化学反应控制,后期为扩散控制.O'-Sialon/ZrO₂复合材料具有良好的抗保护渣侵蚀性能这是由于ZrO₂在硅酸盐熔体中的溶解度较低,随着ZrO₂的增加,抑制了O'-Sialon与CO,以及渣中其他组元的反应,从而提高了O'-Sialon抗渣的侵蚀性.     

Microstructural evolution of a silicon carbide-carbon coated nanostructured ferritic alloy composite during in-situ Kr ion irradiation at 300℃ 450℃

This work focuses on irradiation behaviors of a novel silicon carbide and carbon coated nanostructured ferritic alloy (SiC-C@NFA) composite for potential applications as a cladding and structural material for next generation nuclear reactors.The SiC-C@NFA samples were irradiated with 1 MeV Kr ions up to 10 dpa at 300 and 450 ℃.Microstructures and defect evolution were studied in-situ at the IVEM-Tandem facility at Argonne National Laboratory.The effects of ion irradiation on various phases such as α-ferrite matrix,(Fe,Cr)7C3,and (Ti,W)C precipitates were evaluated.The α-ferrite matrix showed a continuous increase in dislocation density along with spatial ordering of dislocation loops (or loop strings) at ＞5 dpa.The size of the dislocation loops at 450 ℃ was larger than that at 300 ℃.The nucleation and growth of new (Ti,W)C precipitates in α-ferrite grains were enhanced with the ion dose at 450 ℃.This study provides new insight into the irradiation resistance of the SiC-C@NFA system.     

原子转移自由基方法合成聚合物刷的研究进展

从聚合物刷基底的选择和聚合方法的优化两方面介绍了原子转移自由基聚合方法合成聚合物刷的研究进展,讨论了聚合物刷在图案化材料表面、提高材料表面的生物相容性及其它方面的应用情况,并对其前景进行了展望.     

反应烧结温度对自结合钛酸铝/莫来石复相材料的影响

44 MPa,热震抗折强度保持率为97.2%.     

Preparation,Properties, and Mechanism of Flame-Retardant Poly(vinyl alcohol) Aerogels Based on the Multi-Directional Freezing Method

In this work, exfoliated α-zirconium phosphate (α-ZrP) and phosphated cellulose (PCF) were employed to synthesize poly(vinyl alcohol) composite aerogels (PVA/PCF/α-ZrP) with excellent flame retardancy through the multi-directional freezing method. The peak heat release rate (PHRR), total smoke release (TSR), and CO production (COP) of the (PVA/PCF₁₀/α-ZrP₁₀-3) composite aerogel were considerably decreased by 42.3%, 41.4%, and 34.7%, as compared to the pure PVA aerogel, respectively. Simultaneously, the limiting oxygen index (LOI) value was improved from 18.1% to 28.4%. The mechanistic study of flame retardancy showed evidence that PCF and α-ZrP promoted the crosslinking and carbonization of PVA chains to form a barrier, which not only served as insulation between the material and the air, but also significantly reduced the emissions of combustible toxic gases (CO₂, CO). In addition, the multi-directional freezing method further improved the catalytic carbonization process. This mutually advantageous strategy offers a new strategy for the preparation of composite aerogels with enhanced fire resistance.     

Photoluminescent Polymer Aerogels with R,G and B Emission

In this work, three new polymer aerogels based on 2-hydroxy ethyl methacrylate (HEMA) complexes with Eu(III), Tb(III) and La(III) are prepared and investigated. The polymer aerogels present strong photoluminescence with emissions located in the red, green and blue regions of the visible spectrum. Depending on the water content used during the preparation path, the consistency of the photoluminescent aerogels varies from rigid, regularly shaped monoliths to a flexible, fibrous material with very low density. The morpho-structural investigation was performed by FT-IR, XPS and SEM. Thermal behavior was also evaluated, while steady-state fluorescence spectroscopy, absolute PLQY and lifetime were used for the investigation of their luminescent properties. The impressive photoluminescent emission located in the red, green and blue areas of the visible spectrum is preserved irrespective of the selected porosity. Their photo-emissive properties, tunable porosity and the convenience of the preparation path could be some arguments for applications as photonic conversion mediums in special-purpose optoelectronic devices or sensors.     

Poly(dithiophosphate)s,a New Class of Phosphorus- and Sulfur-Containing Functional Polymers by a Catalyst-Free Facile Reaction between Diols and Phosphorus Pentasulfide

Novel poly(dithiophosphate)s (PDTPs) were successfully synthesized under mild conditions without any additive in the presence of THF or toluene diluents at 60 °C by a direct, catalyst-free reaction between the abundant phosphorus pentasulfide (P₄S₁₀) and glycols such as ethylene glycol (EG), 1,6-hexanediol (HD) and poly(ethylene glycol) (PEG). GPC, FTIR, ¹H and ³¹P NMR analyses proved the formation of macromolecules with dithiophosphate coupling groups having P=S and P-SH pendant functionalities. Surprisingly, the ring-opening of THF by the P-SH group and its pendant incorporation as a branching point occur during polymerization. This process is absent with toluene, providing conditions to obtain linear chains. ³¹P NMR measurements indicate long-time partial hydrolysis and esterification, resulting in the formation of a thiophosphoric acid moiety and branching points. Copolymerization, i.e., using mixtures of EG or HD with PEG, results in polymers with broadly varying viscoelastic properties. TGA shows the lower thermal stability of PDTPs than that of PEG due to the relatively low thermal stability of the P-O-C moieties. The low T_gs of these polymers, from −4 to −50 °C, and a lack of PEG crystallites were found by DSC. This polymerization process and the resulting novel PDTPs enable various new routes for polymer synthesis and application possibilities.     

考虑剪力滞后效应结合梁的长期性能计算

目前结构施工仿真计算多采用平面杆系有限元模型,而桥面板剪力滞后效应会使平面杆系模型分析结果产生误差.该文考虑混凝土的长期性能,引入翘曲位移形状函数与强度函数,描述结合梁剪力滞后效应.利用最小势能原理,以整体竖向挠度和翘曲强度函数为未知函数,推导出结合梁微段平衡微分方程及边界条件方程,引入“附加弯矩”描述剪力滞后效应对结构变形的影响;可根据具体结构形式的边界条件,得到结合梁模型变形的解析解.通过算例验证了模型和解析解的正确性,并分析了结合梁剪力滞后效应的时效性.考虑承受均布荷载的固端梁,采用现行规范有效宽度计算的结果介于弹性与粘弹性结果之间.利用该文计算方法,可以减小剪力滞后效应对杆系模型计算结果带来的误差.     

带节能复合墙板钢框架低周反复荷载试验研究

为了研究带节能复合墙板钢框架结构的滞回性能,设计了8 榀单层单跨试件并进行了低周反复荷载试验.考虑了影响结构滞回性能的6 个主要因素：墙板厚度、墙板类型、墙板位置、钢框架柱的强弱轴方向、钢框架的节点形式以及墙板与钢框架的连接方法.根据试验现象和由试验数据获得的滞回曲线、骨架曲线、强度退化曲线、刚度退化曲线、延性系数、等效粘滞阻尼系数等,综合评价了结构的抗震性能.试验结果表明：墙板的破坏主要集中在与钢框架连接的预埋件处,但整体性优于传统墙体;连接件的可靠是确保墙板与钢框架协同工作的重要前提;增加墙板的厚度、加强墙板与钢框架之间的连接,均可改善结构的抗震性能.最后,通过计算延性系数和耗能能力,该文给出了该结构体系在进行抗震设计时相关数据的建议取值.