离网型太阳能光伏发电系统设计研究

离网型太阳能光伏发电系统是太阳能光伏发电系统的重要组成。它具有灵活度高、分布广、项目成本低等优点。本文主要对现有离网光伏发电系统设计过程进行分析。     

Synthesis of fluorine-graphite intercalation compounds by elemental fluorine and high oxidation-state transition-metal fluorides

Fluorine-graphite intercalation compounds have been synthesized using high purity fluorine gas and high oxidation-state transition-metal fluorides, AgF₃ and NiF₃, at room temperature and at −78 °C. At room temperature, a mixture of stage 1 + 2 − 4 compounds with compositions, C_4.2F to C_14.6F were obtained. On the other hand, stage 2–4 compounds with compositions C_5.6F to C_14.2F were synthesized at −78 °C. The fluorinating ability of AgF₃ and NiF₃ has been shown more clearly at room temperature because a small amount of fluorine was intercalated/absorbed into graphite at −78 °C without catalysts. XPS spectra show that ionic, nearly ionic, semi-covalent and covalent fluorines coexist in the C_xF samples, and that the covalency of CF bonding increases with decreasing stage number.     

Electrochemical studies of pyrite oxidation and reduction using freshly-fractured electrodes and rotating ring-disc electrodes

Oxidation and reduction processes on coal- and mineral-pyrite surfaces have been investigated to better understand the reactions that control the hydrophobicity and flotation behavior of pyrite. The incipient oxidation and reduction reactions were studied using fresh surfaces of pyrite that were created by in situ fracturing electrodes potentiostated at a predetermined potential. Chronoamperometry immediately after fracture and subsequent cyclic voltammetry have established that fresh fracture surfaces of pyrite instantaneously assume a unique potential (referred to as the “stable” potential) at which neither oxidation nor reduction takes place. For Peruvian and Chinese pyrites, the stable potential is −0.28 V (standard hydrogen electrode, SHE) at pH 9.2 and 0 V at pH 4.6. The initial oxidation of pyrite begins at potentials slightly positive of the stable potential and is believed to produce a hydrophobic sulfur-rich species, most likely a polysulfide or metal-deficient sulfide. A rotating ring-disc electrode (RRDE) was employed to study the kinetics and mechanisms of surface reactions on pyrite over moderate potential ranges. Two distinct soluble reduction products (ferrous hydroxide and HS⁻) and one distinct soluble oxidation product (ferrous hydroxide) were observed on pyrite in alkaline solutions. It is concluded that the initial oxidation of pyrite and the oxidation of ferrous to ferric hydroxide occur in a similar potential range. When the electrode is oxidized, e.g. by polishing, prior to experiments, the initial oxidation of pyrite is masked by the oxidation of ferrous hydroxide, making it difficult to study the oxidation of pyrite itself.     

含氯离子废水化学需氧量分析方法比较

含氯离子废水化学需氧量的分析方法的研究是当前环境监测研究的热点之一，各种文献报道也较多，但各自使用的效果不一。采用试验的方法对含氯离子废水中CODCr的分析进行了初步研究，比较了硫酸汞加入法、稀释法、硝酸银滴定法、氯气校正法、氯离子校正法等方法在不同化学需氧量不同氯离子浓度下的分析结果，利用分析结果与配置的标准溶液浓度相比较，分析了各种方法的优缺点，结果表明硝酸银滴定法是比较理想的适应范围较广的方法。     

基于势场栅格法的移动机器人避障路径规划

针对传统人工势场法应用于移动机器人避障路径规划存在的缺陷,建立了改进的人工势场模型,通过在障碍物的斥力势场函数中增加最小安全距离,同时考虑机器人与目标点的相对距离,成功地解决了障碍物附近目标不可达(Good Nonreachable with Obstacles Nearby GNRON)的问题。此外,针对传统人工势场法的局部极小点和障碍物附近目标不可达同时存在的问题,提出了以改进人工势场法为主,栅格法为辅的方案来实施避障,使得机器人能够尽快地脱离局部极小并成功地绕过障碍物到达目标点。采用栅格法对改进人工势场法做辅助决策,弥补了改进人工势场法的不足,使机器人能够顺利到达势场的全局最小点,提高了避障路径规划的安全性和可达性。论文利用Matlab进行了算法仿真,结果证明了所提方法的正确性和有效性。     

氮三甲撑膦酸中氯离子含量测定方法的研究

在酸性条件下,用Ag~ 沉淀氮三甲撑膦酸溶液中的Cl~-,然后以淀粉和KIO_3为指示剂,用标准I~-溶液滴定过量的Ag~ 。测定准确,方法灵敏,可靠和方便。克服了莫尔法和佛尔哈德法不适用于该测定体系的困难。     

基于电力GIS的电网故障监控系统的研究与设计

电网故障监控系统利用故障采集器回传的电参数信息和地理标志信息,通过监控中心对这些信息读取处理后,导入GIS中,在显示器上通过GIS地图显示相关信息。从而帮助调度人员快速准确地发现和了解故障信息,及时制定抢修方案或启动抢修预案,并调度维修人员快速到达现场,可有效提高供电抢修效率,提升客户满意度,具有良好的应用价值。     

黑白棋盘网格中的直线检测方法研究

黑白棋盘网格的直线检测在摄像机标定中具有重要的应用价值。针对黑白棋盘网格图像的特点及传统Hough变换直线检测方法中参数选择敏感的不足,在Hough变换的基础上进行了后续处理,结合最小二乘法获得黑白棋盘网格图像中的直线信息。最后,通过大量真实图像实验验证了方法的可行性,并与传统Hough变换方法及其改进方法进行了比较。     

非金属电镀用导电漆的研制

介绍了导电漆、作为导电填料的片状镀银铜粉的制备工艺流程。分别研究了漆膜表面单位电阻与镀银铜粉的含量及其粒径以及钛酸酯偶联剂的含量之间的关系。结果表明,当镀银铜粉的粒径为400目、质量分数在57%~65%之间,钛酸酯偶联剂的质量分数为10%时,所得涂膜的导电性能最佳。加入含C-18的油酸可以使导电漆长期贮存而电阻值不变。经检测,所得涂膜具有良好的性能:附着力1级,硬度1 H,柔韧性1 mm,冲击强度50 kg/cm2,膜厚10~15μm,漆膜表面每厘米电阻0.15Ω,每分米电阻0.47Ω。指出了导电漆应用过程中的注意事项。     

基于Java 3D的地球空间环境可视化研究

根据空间科学研究对交互性和Web化的发展需求,将Java 3D应用于该领域。深入剖析了Java 3D的主要几何类和实现细节;改进并实现了一种矩形网格等值线生成算法,解决了二义性和等值点在网格顶点的问题;介绍了一种生成规则网格的简单算法,并选用合适的Java 3D类加以实现;介绍了一种数值———颜色映射算法,并将空间环境数据映射为RGB颜色信息。综合运用这些算法,对地球空间环境中若干物理要素模型进行了二维和三维可视化。可视化结果与国内外空间环境模型研究成果基本一致,说明上述算法正确,有较高的参考价值。