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B. Bary 《Cement and Concrete Research》2006,36(11):2061-2073
In this paper, the porosity of cementitious materials is described in terms of pore size distribution by means of a 3-dimensional overlapping sphere system with polydispersivity in size. On the basis of results established by Lu and Torquato [B. Lu, S. Torquato, Nearest-surface distribution functions for polydispersed particle systems, Phys. Rev. A 45(8) (1992) 5530-5544] and Torquato [S. Torquato, Random Heterogeneous Media: Microstructure and Macroscopic Properties. Springer-Verlag: New York, 2001] providing relations for nearest-neighbor distribution functions, the volume fraction of pores having a radius larger than a prescribed value is explicitly expressed. By adopting an appropriate size distribution function for the sphere system, it is shown that the pore size distribution of cementitious materials as detected for instance by mercury intrusion porosimetry (MIP), which generally points out several pore classes, can be well approached. On the basis of this porosity representation, the evaluation of the capillary pressure in function of the saturation degree is provided. The model is then applied to the simulation of the saturation degree versus relative humidity adsorption curves. The impact of the pore size distribution, the temperature and the thickness of the adsorbed water layer on these parameters are assessed and analyzed for three model materials having different pore characteristics. 相似文献
93.
1 Introduction A double-walled invertube is difficult to fabricate other than applying inversion process. Such kind of invertube can be used as impact energy absorbing element in transport vehicles, like aircrafts and automobiles. Reddy T Y[1] did the analysis of Internal inversion and calculated the inversion load. Reid[2] et al. examined nosing and internal inversion of cold drawn steel tube by the finite element package ABAQUS. Recently, Rosa P A[3] et al. investigated Internal invers… 相似文献
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R. Tao 《Chemical engineering science》2006,61(7):2186-2190
Molecular dynamical simulation has been carried out to investigate the structure and dynamics of a dipolar fluid under strong shear. Dipolar fluid consists of polarizable particles, which have an induced dipole moment in the applied field direction. Shear stress is perpendicular to the field direction. When shear stress is small, the flow has a flowing-chain structure. If shear stress increases to pass a critical value, flowing-chain structure changes to flowing layer structure. Each layer is parallel to the flow direction and shear direction. Within one layer, particles form strings in the flow direction. 相似文献
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