Analysis of the EWT‐DGB solar cell at low and medium concentration and comparison with a PESC architecture

Silicon represents an interesting material to fabricate low‐cost and relatively simple and high‐efficient solar cells in the low and medium concentration range. In this paper, we discuss a novel cell scheme conceived for concentrating photovoltaic, named emitter wrap through with deep grooved base (EWT‐DGB), and compare it with the simpler passivated emitter solar cell. Both cells have been fabricated by means of a complementary metal–oxide–semiconductor‐compatible process in our laboratory. The experimental characterization of both cells is reported in the range 1–200 suns in terms of conversion efficiency, open circuit voltage, short circuit current density and fill factor. In particular, for the EWT‐DGB solar cells, we obtain an encouraging 21.4% maximum conversion efficiency at 44 suns. By using a calibrated finite‐element numerical electro‐optical simulation tool, validated by a comparison with experimental data, we study the potentials of the two architectures for concentrated light conditions considering possible realistic improvements with respect to the fabricated devices. We compare the solar cell figures of merit with those of the state‐of‐the‐art silicon back‐contact back‐junction solar cell holding the conversion efficiency record for concentrator photovoltaic silicon. Simulation results predict a 24.8% efficiency at 50 suns for the EWT‐DGB cell and up to 23.9% at 100 suns for the passivated emitter solar cell, thus confirming the good potential of the proposed architectures for low to medium light concentration. Finally, simulations are exploited to provide additional analysis of the EWT‐DGB scheme under concentrated light. Copyright © 2017 John Wiley & Sons, Ltd.     

Fabrication of vacuum-evaporated SnS/CdS heterojunction for PV applications

SnS/CdS heterojunction is a promising system for the fabrication of thin film solar cells. In our work, thin film SnS/CdS heterojunction was prepared by evaporating CdS and SnS films. The photovoltaic properties of the heterojunction were investigated with posttreatment of the window material treatment by CdCl₂ for grain size enlargement. I–V characteristics in dark and at light were taken and figures of merit were evaluated. The efficiency with and without window layer treatment were about 0.08% and 0.05%, respectively, under 100 mW/cm² intensity. To the best of our knowledge so far there has been no report on vacuum-evaporated SnS-based heterojunction with window material treatment by CdCl₂.     

南方城镇规划中的建筑隔热问题研究

建筑隔热是南方建筑节能的关键，如何有效地做好建筑隔热工作，建立可持续发展的建筑环境是值得探讨的问题。本文从建筑与环境的系统观点分析隔热与散热的相互关系，论证把建筑隔热与房屋规划，环境规划相结合，利用自然规律指导建筑隔热设计的合理性和必要性。     

Photovoltaic Processes of Singlet and Triplet Excited States in Organic Solar Cells

This article reports the respective photovoltaic processes of singlet and triplet photoexcited states in dissociation and charge reactions based on the studies of magnetic‐field effects of photocurrents. The magnetic‐field effects of photocurrents reveal that weak donor‐acceptor interactions lead to a two‐step photovoltaic process: dissociation in polaron‐pair states evolved from singlet excitonic states and exciton‐charge reactions occurred in triplet excitonic states in the generation of the photocurrent. However, strong donor‐acceptor interactions yield a one‐step photovoltaic process: direct dissociation of both singlet and triplet excitons in bulk‐heterojunction organic solar cells. In addition, the magnetic‐field effects of photocurrents indicate that the dissociated electrons and holes form charge‐transfer complexes with singlet and triplet spin configurations at donor‐acceptor intermolecular interfaces. As a result, the magnetic‐field effects of photocurrents can deliver a critical understanding of singlet and triplet photovoltaic processes to design advanced solar‐energy materials and devices.     

Compressive response of multilayered pyramidal lattices during underwater shock loading

The quasi-static and dynamic compressive mechanical response of a multilayered pyramidal lattice structure constructed from stainless-steel was investigated. The lattices were fabricated by folding perforated 304 stainless steel sheets and bonding them to thin intervening sheets using a transient liquid-phase bonding technique. The resulting structure was attached to thick face sheets and the through thickness mechanical response was investigated quasi-statically and dynamically, in the latter case using a planar explosive loading technique. The lattice is found to crush in a progressive manner by the sequential (cooperative) buckling of truss layers. This results in a quasi-static stress strain response that exhibits a significant “metal foam” like stress plateau to strains of about 60% before rapid hardening due to truss impingement with the intermediate face sheets. During dynamic loading, sequential buckling of the truss layers was manifested as a series of transmitted pressure pulses measured at the back face of the test samples. The sequential buckling extended the duration of the back face pressure–time waveform and significantly reduced the transmitted pressure measured at the back face. The impulse transmitted to the structure is found to be about 28% less than that predicted by analytic treatments of the fluid-structure interaction for fully supported structures. This transmitted impulse reduction appears to be a consequence of the wet side face sheet movement away from the blast wave and is facilitated by the low crush resistance of the lattice structure.     

Non-color distortion for visible light transmitted tandem solid state dye-sensitized solar cells

A tandem solid-state dye-sensitized solar cell (SSDSC) without color distortion for potential photovoltaic window applications is reported. The bifacial tandem SSDSC with two spectrally complementary sensitizers using parallel-connection is realized, which leads to non-color distortion. The Commission Internationale de l'Eclairage (CIE) chromaticity diagram is applied to verify the extent of color distortion. At this circumstance, the photovoltaic performance for the tandem SSDSC with a power conversion efficiency of 3.3% was achieved under AM 1.5G, 100 mW/cm² illumination. The overall efficiency in the tandem architecture outperformed each individual cell. Our results demonstrate the feasibility for visible light transmission, non-color distortion, power-generating windows for application in building-integrated photovoltaics (BIPV). Moreover, this tandem SSDSC architecture has potential for the integration into window curtains application due to its flexible characteristics. With further extension of the absorber spectrum into the IR region, a better solid-state tandem DSC is expected.     

德国的建筑节能技术

本文对德国的节能建材、建筑构造、节能体系、采暖系统等作了详情的介绍，这些宝贵经验对推动我国建筑节能事业颇有裨益，值得我们借鉴。     

A photoelectrochemical solar cell based on ZnO/dye/polypyrrole film electrode as photoanode

Nanostructured ZnO film electrodes were prepared. A preliminary PEC solar cell based on nanostructured Zno/dye/polypyrrole (PPy) film electrode was fabricated. A fill factor of 0.754 and a high overall light to electricity conversion efficiency of 1.3% for this PEC solar cell were obtained. The sensitization mechanisms of the nanostructured ZnO electrodes were also discussed.     

The use of poly(vinylpyridine-co-acrylonitrile) in polymer electrolytes for quasi-solid dye-sensitized solar cells

Poly(vinylpyridine-co-acrylonitrile) (P(VP-co-AN)) was used to form polymer electrolytes for dye-sensitized solar cells (DSSCs). The effects of P(VP-co-AN) on the photovoltaic performances of DSSCs have been investigated with nonaqueous electrolytes containing alkali-iodide and iodine. It was found that the effect of P(VP-co-AN) on V_oc closely related to its amount in the electrolyte. Lower amount of P(VP-co-AN) was benefit for the construction of a solar cell containing P(VP-co-AN) with higher energy conversion efficiency. Chemically crosslinking solidification with backbone polymer P(VP-co-AN) amount of 3% fabricated quasi-solid DSSCs with 10% increased conversion efficiencies with relative to that of the initial liquid DSSCs.     

A new energy efficient, environment friendly and high productive texturization process of industrial multicrystalline silicon solar cells

A new texturization process based on a uniform, isotropic and slow removal of silicon, using a composition of sodium hydroxide (NaOH) and sodium hypochlorite (NaOCl) solution at an elevated temperature is developed recently for multicrystalline silicon solar cells. This process is applied in optimized condition in regular industrial production line and it immediately replaces the old popular industrial process of texturization using a combination of NaOH solution, alcoholic NaOH solution and hydrochloric acid solution in different steps at a higher temperature. Also the gain in solar cell efficiency at global AM1.5 spectrum, 1 SUN intensity condition is nearly 10% in final value. In addition, it has become finally an energy efficient and environment friendly texturization process for large area multicrystalline silicon solar cells for commercial use. In this paper the cost effectiveness and environment friendly aspects of the proposed process have been studied in detail along with the surface texture analysis of wafers with SEM and AFM micrographs to substantiate the reasons behind the above facts.