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101.
102.
The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002 相似文献
103.
为了不使用任何还原剂而获得聚合物固载高分散零价双金属加氢催化剂,利用金属蒸气法制备了3种不同Pd/Cu质量比的聚合物固载双金属原子簇。透射电镜(TEM)和X衍射(XRD)测定表明,Pd-Cu原子簇粒度很小,平均直径小于3.0nm。X射线光电子能谱(XPS)表明,Pd和Cu均为零价态。Pd-Cu原子簇在异丙叉加氢反应中具有很高的活性和选择性。这些结果提供了令人信服的证据,即金属蒸气法可用于在聚合物孔穴内直接而温和地置入小的零价金属原子簇,而且这样制备的聚合物固载金属原子簇很适合于催化应用。 相似文献
104.
对KCl与NaCl在低盐固态酱油发酵中的应用进行了比较研究。结果表明:用KCl代替NaCl,KCl的浓度要高于NaCl才能抑制发酵期间杂茵的污染,且使用KCl的发酵效果比NaCl要好。 相似文献
105.
通过室内实验及同位素测井技术评价高分子聚合物驱油效果 总被引:1,自引:0,他引:1
2500万超高分聚合物室内驱油实验研究了聚合物分子量、浓度、粘度、聚用量、段塞组合等各项性能指标对驱油效果的影响。本文根据室内实验结果,在北一区断西注聚后期开展矿场试验,取得了较好的开发效果。试验前后对比,注入粘度明显增大,月含水上升速度得到有效控制,吸入剖面有了新的动用,有63.1%的油井出现了明显的二次受效特征,取得了显著的经济效益。同时对驱油效果进行系统分析。驱油效果表明:应用2500万超高分聚合物是进一步提高聚驱采收率的有效途径。 相似文献
106.
Mamata Mukhopadhyay Sameer V Dalvi 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(4):445-454
A supercritical antisolvent (SAS) process is employed for production of solid nanoparticles from atomized droplets of dilute solution in a flowing supercritical carbon dioxide (SC CO2) stream by attaining extremely high, very rapid, and uniform supersaturation. This is facilitated by a two‐way mass transfer of CO2 and solvent, to and from the droplet respectively, rendering rapid reduction in equilibrium solubility of the solid solute in the ternary solution. The present work analyses the degree of supersaturation and nucleation kinetics in a single droplet of cholesterol solution in acetone during its flight in a flowing SC CO2 stream. Both temperature and composition are assumed to be uniform within the droplet, and their variations with time are calculated by balancing the heat and mass transfer fluxes to and from the droplet. The equilibrium solubility of cholesterol with CO2 dissolution has been predicted as being directly proportional to the Partial Molar Volume Fraction (PMVF) of acetone in the binary (CO2–acetone) system. The degree of supersaturation has been simulated up to the time required to attain almost zero cholesterol solubility in the droplet for evaluating the rate of nucleation and the size of the stable critical nuclei formed. The effects of process parameters have been analysed in the pressure range of 7.1–35.0 MPa, temperature range of 313–333 K, SC CO2 flow rate of 0.1136–1.136 mol s?1, the ratio of the volumetric flow rates of CO2‐to‐solution in the range of 100–1000, and the initial mole fraction of cholesterol in acetone solution in the range of 0.0025–0.010. The results confirm an extremely high and rapid increase in degree of supersaturation, very high nucleation rates and stable critical nucleus diameter of the order of a nanometre. Copyright © 2005 Society of Chemical Industry 相似文献
107.
108.
增塑对UV固化型高分子固体电解质性能的影响 总被引:1,自引:0,他引:1
将合成的大分子量的聚乙二醇丙烯酸酯(PEGDA)齐聚物与光引发刑、LiClO4组成光敏体系,与一定比例的碳酸乙烯酯(EC)、碳酸丙烯酯(PC)或其混合物进行混合,经紫外光辐照制得了一种新型的高分子固体电解质膜,考察了增塑刑种类和用量对光固化速率、电导率和机械性能的影响。结果表明,增塑是提高UV固化型高分子固体电解质导电性能的有效方法,在机械性能满足使用要求的条件下,增塑的UV固化型固体电解质的电导率可以高达10^-4S/cm左右。 相似文献
109.
根据中原油田地层高温、高盐、易塌、易漏失及水平井的特点,优选了适用于水平井的强抑制强封堵聚合物钻井液体系,并进行了现场应用.室内实验结果表明,优选的强抑制强封堵聚合物钻井液具有良好的井眼净化、摩阻控制、井壁稳定及油层保护等性能.现场应用时能满足钻井、录井、测井的需要,钻井施工顺利,取得了良好的经济和社会效益. 相似文献
110.
《Petroleum Science and Technology》2007,25(7):915-923
Polymer modified bitumen (PMB) is used in various construction applications, especially in motorways. The aim of this study is to improve features of 60/70 penetration grade, modified bitumen used on highways. Increasing the sensitivity to temperature and oxidation resistance are very important points for the modified bitumen. This condition was provided by reacting the carboxylic acid groups in asphaltene with the reactive ethylene terpolymer to form ester. Reactive ethylene terpolymer (RETP) and ethylene terpolymer (ETP) manufactured by DuPont USA were used as additives in this study. Infrared Spectrophotometer (IR) graphics and optical pictures of the modified bitumen have been examined. It has been observed that the softening point has increased on the other hand, the penetration and ductility values have decreased according to the test results. 相似文献