Phase separation studies in RIM polyurethanes catalyst and hard segment crystallinity effects

Polyurethanes were prepared from pure 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butane diol (BDO) or 1,2-ethane diol (EDO) and α,ω-hydroxyl poly(propylene oxide) (PPO) by reaction injection moulding (RIM). Hard segment (MDI + BDO or EDO) level was 45–50 wt%. The PPO had about 20% ethylene oxide copolymerized in at the chain ends to provide 80% primary OH end groups. M_n was varied from 2000 to 4000. Dibutyl tin dilaurate catalyst and mould temperature were varied. Dynamic mechanical, wide-angle X-ray, differential scanning calorimeter, molecular weight and tensile elongation measurements were made on the RIM polyurethanes. At low reaction rates (low catalyst or temperature) highly crystalline, well phase separated but low molecular weight polymers were produced. At high catalyst or temperature levels more poorly phase separated but high molecular weight, tough polymers resulted. Higher M_n PPO gave better phase separation and EDO gave higher melting temperatures. Preventing hard segment crystallinity by substituting asymmetric MDI or glycols resulted in phase compatibility.     

VERIFICATION AND COMPARISON OF FORMULAS FOR BED LOAD TRANSPORT

1 .　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｂｅｄｌｏａｄｔｒａｎｓｐｏｒｔｈａｓｂｅｅｎｅｘｔｅｎｓｉｖｅｌｙｓｔｕｄｉｅｄｉｎｔｈｅｐａｓｔｆｅｗｄｅｃａｄｅｓａｎｄｍａｎｙｆｏｒｍｕｌａｓｆｏｒｐｒｅｄｉｃｔｉｎｇｂｅｄｌｏａｄｔｒａｎｓｐｏｒｔｒａｔｅｈａｖｅｂｅｅｎｐｒｅｓｅｎｔｅｄ(Ｅｉｎｓｔｅｉｎ 1950 ;Ｍｅｙｅｒ Ｐｅｔｅｒ 194 8;Ｂａｇｎｏｌｄ 1973;Ｅｎｇｅｌｕｎｄ 1976;Ｙａｌｉｎ 1972 ;Ｓａｍａｇａ 1986;ａｎｄＫａｒｉｍ 1998) .Ｗｈｅｎａｐｐｌｉｅｄｔｏｓｔｒｅａｍｓｗｉｔｈｐａｒｔｉａｌ…     

迫零对Turbo码的性能影响

从距离谱的角度对迫零在Turbo码中的作用进行了理论分析。通过仿真，研究了迫零对Turbo码性能的影响。仿真结果表明，Turbo码编码器迫零处理有助于改善Turbo码的性能。     

酒泉盆地青西油田快速钻井技术

酒泉盆地青西地区油层储藏深 ,地层可钻性差 ,钻井过程中存在机械钻速低、井斜不易控制、刺断钻具频繁等问题。为此 ,在近年的钻井实践中 ,采取了优化钻具组合、优选钻头、应用 PDC钻头、强化钻具管理等措施 ,使该区块的钻井速度不断提高 ,钻井周期缩短 ,钻头用量减少 ,从而形成了一套适合该区块的快速钻井技术。     

葡北地区快速钻井技术

介绍了葡北地区地质构造及分层特征 ,分析了钻井难点 ,并给出了详细对策 ,从钻具组合、钻头优选、钻进参数优选、钻井液体系及安全技术措施等方面详细介绍了该区快速钻井技术。在葡北 4 - 11井和葡北 6- 1井的应用表明 ,该快速钻井技术能显著提高钻速 ,钻井周期明显缩短     

混合冷媒气液相充注对冷媒成分的影响

R40 7C、R5 0 7A、R40 4A和R410A混合冷媒按气、液相方式进行充注时 ,冷媒容器内的冷媒成分会或多或少地随着冷媒容器移充填率的变化而变化。因此 ,本文建议充注任何混合冷媒时 ,都应该采用液相方式进行充注 ,同时为了将冷媒成分变化控制在 2 %以内 ,R40 7C冷媒容器中最后的 10 %冷媒剩余量不应再进行充注 ,R5 0 7A、R40 4A和R410A冷媒容器中的最后冷媒剩余量可控制在 5 %。     

辽宁省2000年夏季干旱分析

本文针对辽宁省2000年发生的干旱,从大气环流、气候、降水、径流、水资源量等方面,较系统地阐述了各因素的发展规律、特点及物理成因。采用降水指标、径流指标、受旱率进行干旱程度分析。评价出辽宁省2000年干旱为特大干旱。     

Pad effects on material-removal rate in chemical-mechanical planarization

The role of a porous pad in controlling material-removal rate (MRR) during the chemical-mechanical planarization (CMP) process has been studied numerically. The numerical results are used to develop a phenomenological model that correlates the forces on each individual abrasive particle to the applied nominal pressure. The model provides a physical explanation for the experimentally observed domains of pressure-dependent MRR, where the pad deformation controls the load sharing between active-abrasive particles and direct pad-wafer contact. The predicted correlations between MRR and slurry characteristics, i.e., particle size and concentration, are in agreement with experimentally measured trends reported by Ouma¹ and Izumitani.²     

已二醇二丙烯酸酯对真丝的接枝改性研究

研究了用二醇二丙烯酸酯为接枝单体、过硫酸铵（APS）为引发剂对真丝的接枝共聚反应，分析了接枝率的影响素，并测试了改性真丝的主要应用性能。结果表明：乳液和乙醇/水为溶剂的2种体系都能在真丝上获得较高接枝率。对于乙醇/水体系v(乙醇）：v(H2O）=1:1，接枝单体20～30g/L,2%甲酸4ml，引发剂APS 0.5g/L,65～70℃接枝60min的接枝率高。改性后真丝的断裂强度、延伸度、吸湿性能都可获得改善，对酸、碱的溶解性提高，但染色性能提高不明显，对泛黄性改善一般。     

钛合金的银脆,镉脆敏感性及其控制

利用慢应变速率拉伸技术（ＳＳＲＴ），并结合恒载实验，较全面地研究了Ｔｉ－６Ａｌ－４Ｖ合金的银脆行为、固态与液态镉脆行为，确定了应变速率、接触条件、热处理制度、试样取向、温度等因素对Ｔｉ－６Ａｌ－４Ｖ合金银脆与镉脆敏感性的影响，探讨了Ｎｉ阻挡层对控制Ｔｉ－６Ａｌ－４Ｖ合金和ＴＣ１１合金银脆开裂的作用。