Niobium-containing catalysts—the state of the art

This review article is devoted to the materials containing niobium, which have been discovered or developed in the past few years and exhibit the potential application in heterogeneous catalysis. Niobium oxides and mixed oxides as well as sulfides, nitrides (oxynitrides), carbides (oxycarbides), and phosphates are considered. Among the catalytic processes in which Nb-containing materials were tested, liquid and gas phase oxidation is described in details, and the role of niobium in the prevention of the catalyst from SO₂ poisoning is mentioned.     

Measurement and Identification of the Parameters of SPICE-Models of a Bipolar Transistor

A method of measuring and identifying the static parameters of a bipolar transistor is considered. The characteristic of the transistor, from which the parameters of the model are determined, is chosen depending on what group the calculated parameters belong to. The characteristics are measured in such a way that the equations of the model describing them can be reduced to the simplest form.     

Monte Carlo simulation of gas phase polymerization of 1,3‐butadiene. Part II: Kinetics optimization and confirmation

Studies on the deactivations and initiations of gas phase polymerizations of 1,3‐butadiene have been achieved by Monte Carlo simulation. Initiation and deactivation control the reaction before and after the peak of the polymerization rate, respectively. The influence of polymerization temperature has been studied. Monte Carlo modeling of polymerization kinetics and mechanism was confirmed by the agreement of experimental data and simulation results of polymerizations run with a temporary evacuation of monomer. The balance of catalysts and active chains is established by both initiation and chain transfer reactions with cocatalyst, which causes a ‘pseudo‐stability’ stage. © 2003 Society of Chemical Industry     

隔河岩水电站大坝廊道排水系统自动化改造

隔河岩水电站大坝廊道排水控制系统存在设备备品、备件不足,技术落后,系统软件工作不稳定等问题,不能按库坝管理要求对排水量进行监控,严重影响廊道排水系统的可靠性。为此,对该系统进行了综合自动化改造,采用TCP6IP通讯,PLC直接上网,异种CPU热备冗余等技术,提高了整个系统的运行可靠性,满足了“无人值班”的要求。     

电视新闻拍摄也需要美感

分析电视新闻拍摄美感的重要性和必要性,提出在实地拍摄过程中如何体现电视新闻的美感。     

基于C6711处理器cdma2000 1X系统前向信道信号的处理

在cdma20001x前向信道中,要对一段信号进行传送,一般选用QPSK调制,因为QPSK调制比QAM更适合噪音环境。采用TI6000系列的TMS320C6711芯片处理前向信道信号,可以对复杂性和实时性较高的信号做采集、量化、编码、调制等实时处理,主要功能通过软件编程实现,从而使系统具有结构灵活、可靠性高、可扩展等优点。     

火炮身管内表面激光硬化处理的实验研究

提高身管寿命是火炮行业亟待解决的关键技术问题，激光表面改性技术是解决这一问题的有效方法之一。本文在分析激光表面相变硬化性能的基础上，对身管内表面进行了激光硬化处理实验研究，检测了其内表面阳线和阴线的硬化层硬度和深度，对比分析了离焦量和焦深对其内表面硬化层硬度的影响，并对激光相变硬化层金相组织进行了分析。经激光硬化处理后，身管的内表面硬度有明显提高，硬化层较深，且为很细的条状马氏体组织。     

机械力化学作用对低介硅灰石瓷料的相变和相组成的影响

采用X射线衍射仪(XRD)、差热分析(DTA)手段详细研究了由氧化物粉末制备硅灰石陶瓷时,机械力化学作用及后续热处理对硅灰石陶瓷相组成和相变过程的影响,分析了机械力化学在球磨过程中的作用机理主要是细化晶粒、使晶格畸变、晶格缺陷增多、非晶化和诱导低温化学反应。结果表明:高能球磨中的机械力化学作用能够有效地降低硅灰石陶瓷的烧成温度(11160~11220℃)。探明了经高能球磨的样品在烧成过程中的晶相转变规律。瓷料最终的晶相为单一的-硅灰石(高温变体)。     

连续波雷达测距中的解模糊技术

研究连续波雷达测距中的距离模糊问题，分析几种常用解模糊方法的性能，并讨论参差比的选取对测距范围的影响。     

地震数据采集系统延迟时间研究与分析

文章分析了影响地震采集系统延迟时间的因素,并根据系统延迟的理论对产生的原因进行了论证.同时对实际生产中的测试方法进行了阐述研究和分析,提出了新的测试方法,并结合实际生产提出了合理性建议.