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排序方式: 共有618条查询结果,搜索用时 703 毫秒
71.
Michele Serri Giuseppe Cucinotta Lorenzo Poggini Giulia Serrano Philippe Sainctavit Judyta Strychalska-Nowak Antonio Politano Francesco Bonaccorso Andrea Caneschi Robert J. Cava Roberta Sessoli Luca Ottaviano Tomasz Klimczuk Vittorio Pellegrini Matteo Mannini 《Advanced materials (Deerfield Beach, Fla.)》2020,32(24):2000566
Magnetic crystals formed by 2D layers interacting by weak van der Waals forces are currently a hot research topic. When these crystals are thinned to nanometric size, they can manifest strikingly different magnetic behavior compared to the bulk form. This can be the result of, for example, quantum electronic confinement effects, the presence of defects, or pinning of the crystallographic structure in metastable phases induced by the exfoliation process. In this work, an investigation of the magnetism of micromechanically cleaved CrCl3 flakes with thickness >10 nm is performed. These flakes are characterized by superconducting quantum interference device magnetometry, surface-sensitive X-ray magnetic circular dichroism, and spatially resolved magnetic force microscopy. The results highlight an enhancement of the CrCl3 antiferromagnetic interlayer interaction that appears to be independent of the flake size when the thickness is tens of nanometers. The estimated exchange field is 9 kOe, representing an increase of ≈900% compared to the one of the bulk crystals. This effect can be attributed to the pinning of the high-temperature monoclinic structure, as recently suggested by polarized Raman spectroscopy investigations in thin (8–35 nm) CrCl3 flakes. 相似文献
72.
Sanat Ghosh Jaykumar Vaidya Sawani Datta Ram Prakash Pandeya Digambar A. Jangade Ruta N. Kulkarni Kalobaran Maiti Arumugam Thamizhavel Mandar M. Deshmukh 《Advanced materials (Deerfield Beach, Fla.)》2020,32(37):2002220
High-temperature superconductors (HTSs) are important for potential applications and for understanding the origin of strong correlations. Bi2Sr2CaCu2O8+δ (BSCCO), a van der Waals material, offers a platform to probe the physics down to a unit-cell. Guiding the flow of electrons by patterning 2DEGS and oxide heterostructures has brought new functionality and access to new science. Similarly, modifying superconductivity in HTS locally, on a small length scale, is of immense interest for superconducting electronics. A route to modify superconductivity locally by depositing metal on the surface is reported here by transport studies on few unit-cell thick BSCCO. Deposition of chromium (Cr) on the surface over a selected area of BSCCO results in insulating behavior of the underlying region. Cr locally depletes oxygen in CuO2 planes and disrupts the superconductivity in the layers below. This technique of modifying superconductivity is suitable for making sub-micrometer superconducting wires and more complex superconducting devices. 相似文献
73.
Yu Wang Cong Wang Shi-Jun Liang Zecheng Ma Kang Xu Xiaowei Liu Lili Zhang Alemayehu S. Admasu Sang-Wook Cheong Lizheng Wang Moyu Chen Zenglin Liu Bin Cheng Wei Ji Feng Miao 《Advanced materials (Deerfield Beach, Fla.)》2020,32(42):2004533
By virtue of the layered structure, van der Waals (vdW) magnets are sensitive to the lattice deformation controlled by the external strain, providing an ideal platform to explore the one-step magnetization reversal that is still conceptual in conventional magnets due to the limited strain-tuning range of the coercive field. In this study, a uniaxial tensile strain is applied to thin flakes of the vdW magnet Fe3GeTe2 (FGT), and a dramatic increase of the coercive field (Hc) by more than 150% with an applied strain of 0.32% is observed. Moreover, the change of the transition temperatures between the different magnetic phases under strain is investigated, and the phase diagram of FGT in the strain–temperature plane is obtained. Comparing the phase diagram with theoretical results, the strain-tunable magnetism is attributed to the sensitive change of magnetic anisotropy energy. Remarkably, strain allows an ultrasensitive magnetization reversal to be achieved, which may promote the development of novel straintronic device applications. 相似文献
74.
Genki Horiguchi Hidehiro Kamiya Pablo García-Triñanes 《Advanced Powder Technology》2021,32(2):283-289
Understanding the adhesiveness of fine particulate materials at high temperatures is important to achieving the stable, economical operation of various industrial systems. In the present research, two types of calcium carbonate (CaCO3) particles having different mean particle sizes (often used as heat carriers in energy systems) were evaluated. The tensile strengths of beds of these materials were determined at various temperatures by tensile strength measurement tester. The adhesiveness was found to increase greatly at 500 °C even without chemical reactions or sintering, and X-ray diffraction analyses showed thermal expansion of the CaCO3 crystals at 500 °C. Pure alumina (Al2O3) and silica (SiO2) microparticles did not exhibit the same pronounced increases in tensile strength or crystal expansion at this same temperature. Because the surface distances between these primary particles were presumably small, it is proposed that van der Waals forces between the particles greatly increased at high temperatures. The addition of Al2O3 nanoparticles to the CaCO3 decreased the tensile strengths of the powder beds both at ambient temperature and at 500 °C. The experimental data confirm that the surface distances between primary particles were increased upon incorporating the nanoparticles, such that the tensile strength decreased during heat treatment. 相似文献
75.
We present a two-dimensional simulation model to explore cake formation in cross-flow filtration. The model uses the lattice Boltzmann method (LBM) for fluid computation and the discrete element method (DEM) for particle computation; they were fully coupled with the smoothed profile method. We verified our model by simulating filtration under different transmembrane pressures. We then investigated the effects of attractive forces and particle concentration on the cake formation mechanism. Generally, as the attractive interaction and particle concentration increased, the particles formed a cake layer with a looser body and rough surface, due to the decrease in the mobility of the particles in contact with the cake surface. It is concluded that the effects of particle concentration are affected by the different conditions of attractive interactions between the particles. 相似文献
76.
77.
Zhaolong Chen Zhiqiang Liu Tongbo Wei Shenyuan Yang Zhipeng Dou Yunyu Wang Haina Ci Hongliang Chang Yue Qi Jianchang Yan Junxi Wang Yanfeng Zhang Peng Gao Jinmin Li Zhongfan Liu 《Advanced materials (Deerfield Beach, Fla.)》2019,31(23)
The growth of single‐crystal III‐nitride films with a low stress and dislocation density is crucial for the semiconductor industry. In particular, AlN‐derived deep‐ultraviolet light‐emitting diodes (DUV‐LEDs) have important applications in microelectronic technologies and environmental sciences but are still limited by large lattice and thermal mismatches between the epilayer and substrate. Here, the quasi‐van der Waals epitaxial (QvdWE) growth of high‐quality AlN films on graphene/sapphire substrates is reported and their application in high‐performance DUV‐LEDs is demonstrated. Guided by density functional theory calculations, it is found that pyrrolic nitrogen in graphene introduced by a plasma treatment greatly facilitates the AlN nucleation and enables fast growth of a mirror‐smooth single‐crystal film in a very short time of ≈0.5 h (≈50% decrease compared with the conventional process), thus leading to a largely reduced cost. Additionally, graphene effectively releases the biaxial stress (0.11 GPa) and reduces the dislocation density in the epilayer. The as‐fabricated DUV‐LED shows a low turn‐on voltage, good reliability, and high output power. This study may provide a revolutionary technology for the epitaxial growth of AlN films and provide opportunities for scalable applications of graphene films. 相似文献
78.
Minh Dao Tran Hyun Kim Jun Suk Kim Manh Ha Doan Tuan Khanh Chau Quoc An Vu Ji‐Hee Kim Young Hee Lee 《Advanced materials (Deerfield Beach, Fla.)》2019,31(7)
2D van der Waals (vdWs) heterostructures exhibit intriguing optoelectronic properties in photodetectors, solar cells, and light‐emitting diodes. In addition, these materials have the potential to be further extended to optical memories with promising broadband applications for image sensing, logic gates, and synaptic devices for neuromorphic computing. In particular, high programming voltage, high off‐power consumption, and circuital complexity in integration are primary concerns in the development of three‐terminal optical memory devices. This study describes a multilevel nonvolatile optical memory device with a two‐terminal floating‐gate field‐effect transistor with a MoS2/hexagonal boron nitride/graphene heterostructure. The device exhibits an extremely low off‐current of ≈10?14 A and high optical switching on/off current ratio of over ≈106, allowing 18 distinct current levels corresponding to more than four‐bit information storage. Furthermore, it demonstrates an extended endurance of over ≈104 program–erase cycles and a long retention time exceeding 3.6 × 104 s with a low programming voltage of ?10 V. This device paves the way for miniaturization and high‐density integration of future optical memories with vdWs heterostructures. 相似文献
79.
Hua Lv Alessandra da Silva Adriana I. Figueroa Charles Guillemard Iván Fernández Aguirre Lorenzo Camosi Lucia Aballe Manuel Valvidares Sergio O. Valenzuela Jürgen Schubert Martin Schmidbauer Jens Herfort Michael Hanke Achim Trampert Roman Engel-Herbert Manfred Ramsteiner Joao Marcelo J. Lopes 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(39):2302387
Van der Waals (vdW) heterostructures combining layered ferromagnets and other 2D crystals are promising building blocks for the realization of ultracompact devices with integrated magnetic, electronic, and optical functionalities. Their implementation in various technologies depends strongly on the development of a bottom-up scalable synthesis approach allowing for realizing highly uniform heterostructures with well-defined interfaces between different 2D-layered materials. It is also required that each material component of the heterostructure remains functional, which ideally includes ferromagnetic order above room temperature for 2D ferromagnets. Here, it is demonstrated that the large-area growth of Fe5−xGeTe2/graphene heterostructures is achieved by vdW epitaxy of Fe5−xGeTe2 on epitaxial graphene. Structural characterization confirms the realization of a continuous vdW heterostructure film with a sharp interface between Fe5−xGeTe2 and graphene. Magnetic and transport studies reveal that the ferromagnetic order persists well above 300 K with a perpendicular magnetic anisotropy. In addition, epitaxial graphene on SiC(0001) continues to exhibit a high electronic quality. These results represent an important advance beyond nonscalable flake exfoliation and stacking methods, thus marking a crucial step toward the implementation of ferromagnetic 2D materials in practical applications. 相似文献
80.
Matthieu Fortin‐Deschênes Robert M. Jacobberger Charles‐Antoine Deslauriers Olga Waller tienne Bouthillier Michael S. Arnold Oussama Moutanabbir 《Advanced materials (Deerfield Beach, Fla.)》2019,31(21)
Van der Waals (vdW) heterostructures have recently been introduced as versatile building blocks for a variety of novel nanoscale and quantum technologies. Harnessing the unique properties of these heterostructures requires a deep understanding of the involved interfacial interactions and a meticulous control of the growth of 2D materials on weakly interacting surfaces. Although several epitaxial vdW heterostructures have been achieved experimentally, the mechanisms governing their synthesis are still nebulous. With this perspective, herein, the growth dynamics of antimonene on graphene are investigated in real time. In situ low‐energy electron microscopy reveals that nucleation predominantly occurs on 3D nuclei followed by a self‐limiting lateral growth with morphology sensitive to the deposition rate. Large 2D layers are observed at high deposition rates, whereas lower growth rates trigger an increased multilayer nucleation at the edges as they become aligned with the Z2 orientation leading to atoll‐like islands with thicker, well‐defined bands. This complexity of the vdW growth is elucidated based on the interplay between the growth rate, surface diffusion, and edges orientation. This understanding lays the groundwork for a better control of the growth of vdW heterostructures, which is critical to their large‐scale integration. 相似文献