The Fabrication and Characterization of Single‐Component Polymeric White‐Light‐Emitting Diodes

By using Ni⁰‐mediated polymerization, we have systematically synthesized a series of fluorene‐based copolymers composed of blue‐, green‐, and red‐light‐emitting comonomers with a view to producing polymers with white‐light emission. 2,7‐Dibromo‐9,9‐dihexylfluorene, {4‐(2‐[2,5‐dibromo‐4‐{2‐(4‐diphenylamino‐phenyl)‐vinyl}‐phenyl]‐vinyl)‐phenyl}‐diphenylamine (DTPA), and 2‐{2‐(2‐[4‐{bis(4‐bromo‐phenyl)amino}‐phenyl]‐vinyl)‐6‐tert‐butyl‐pyran‐4‐ylidene}‐malononitrile (TPDCM) were used as the blue‐, green‐, and red‐light‐emitting comonomers, respectively. It was found that the emission spectra of the resulting copolymers could easily be tuned by varying their DTPA and TPDCM content. Thus with the appropriate red/green/blue (RGB) unit ratio, we were able to obtain white‐light emission from these copolymers. A white‐light‐emitting diode using the polyfluorene copolymer containing 3 % green‐emitting DTPA and 2 % red‐emitting TPDCM (PG3R2) with a structure of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonic acid)/PG3R2/Ca/Al was found to exhibit a maximum brightness of 820 cd m^–2 at 11 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33,0.35), which are close to the standard CIE coordinates for white‐light emission (0.33,0.33).     

带吊车门式刚架轻型钢结构厂房的设计与分析

以实际工程为背景，采用门式刚架轻型房屋钢结构设计规程，对带吊车门式刚架、吊车梁、抗风柱及基础的受力特点、设计方法进行分析，解决了设计中所遇到的问题。     

垂直定向液晶光阀及光电特性的研究

系统地讨论了排列相畸变模式液晶光阀结构，原理和制作，结合实际测试对其等效电路和电学匹配进行了分析，详细讨论了它的光电特性及相互关系，实测的液晶垂直排列方式工作的液晶光阀性能指标为，分辨率大于５０ｌｐ／ｍｍ，白光输入灵敏度为６．７７μＷ／ｃｍ＾２，响应时间为２００ｍｓ／３００ｍｓ，白光输出对比度为２００：１。     

光柱显示技术探讨

本文叙述自动化仪表用光柱显示技术的工作原理及器件结构，重点论述直流等离子体光柱，发光二极管光柱，真空荧光及液晶光柱器件的结构和驱动电路，还展望光柱显示的发展趋势。     

单液晶光阀彩色大屏幕投影显示

设计一电路,将彩色图象信息编码到黑白CRT的亮度之中,并将其写入液晶光阀,用白光读出,当编码合适时,读出的象颜色可与原图像一致。本文讨论了这一技术原理并进行了单液晶光阀彩色大屏幕投影的实验验证。     

新型微光探测器滤光玻璃

系统分析了微光探测器的结构及其原理。鉴于当前器件存在的激光致盲威胁,提出了新的改进思路。着重介绍了具有特殊激光防护性能的滤光材料,并对其原料及制备、加工过程作了系统地介绍,同时给出了一些重要的性能特征。     

Treatment of slices from carrot (<Emphasis Type="Italic">Daucus carota</Emphasis>) using high intensity white pulsed light

Experiments with washing of carrot slices using distilled water and 0.9% (w/w) NaCl in combination with varying number and pulses of high intensity white were carried out. Slices of carrot 3.5 cm in diameter and 2 mm thick were inoculated using diluted dispersions of yeasts (Saccharomyces cerevisiae) for varying time (0–240 min) and then the slices were treated with high intensity pulsed white light (one pulse = 0.7 J/cm²) using from none to 24 pulses. The major part of the yeast cells were killed using two pulses of light. The studies included washing of inoculated slices up to five times using salt 0.9% (w/w) NaCl and distilled water and inoculation at 22 °C for between 5 and 120 min. It was concluded that treatment of carrot slices with high intensity white light may reduce the load of yeast cells with up to 6 log cycles. Inoculation time at 22 °C had no effect on the maximum load of yeast cells.     

SAPO-34/SiO_2催化甲醇制烯烃

采用水热法合成了SAPO-34分子筛,并用X射线粉末衍射仪和扫描电子显微镜对SAPO-34分子筛的结构进行了表征,同时探讨了黏合剂种类、甲醇分压、催化剂粒径和硅源等对SAPO-34分子筛催化甲醇制烯烃(MTO)反应性能的影响。实验结果表明,在MTO反应中,三烯(乙烯、丙烯和丁烯)选择性在反应初期存在明显的诱导期;以S iO2为黏合剂合成的SAPO-34/S iO2催化剂不但可缩短MTO反应的诱导期,三烯选择性也较未添加黏合剂或以A l2O3为黏合剂时高1~2个百分点;且当催化剂活性明显下降时,三烯选择性下降的幅度较小。催化剂粒径、甲醇分压及硅源对催化剂的诱导期也有明显的作用。在甲醇分压低于19kPa、催化剂粒径0.25~0.38mm、S iO2为黏合剂、硅酸四乙酯为硅源时,SAPO-34/S iO2催化剂的MTO性能明显提高。     

三脉冲不等强度激光片光源的研制及应用

本文报道了最近研制成功三脉冲不等强度调Q红宝石激光片光源系统.利用小颗粒对片光源90°方向的散射光对动态颗粒场进行高速摄影,从底片中能够精确直观地判断微小颗粒的瞬时分布、运动方向、速度和加速度情况.