Joining of Cf/SiC composite to Ti alloy using composite filler materials

Abstract

C_f/SiC was successfully joined to Ti alloy with Ag–Cu–Ti–W, Ag–Cu–Ti–SiC and Ag–Cu–Ti–TiC mixed powders by some suitable brazing parameters. Microstructure and shear strengths of the preformed joint were investigated. The results showed that the W particulate and reaction products can uniformly distribute in the brazing layer of the performed joint. These composite brazing layers relaxed the thermal stress of the joint effectively. These characteristics were beneficial to the joint, which had shear strengths that were significantly higher than the optimal shear strengths of the joint brazed with pure Ag–Cu–Ti at room temperature and 500°C.     

Potential effects of recent transportation accident on transportation of radioactive materials in USA

Abstract

In 2007, two severe transportation accidents, involving primarily long haul tractor trailers, occurred in the State of California. In the first, which occurred in Oakland in what is commonly known as the 'MacArthur Maze' section of Interstate 580 (I-580), a tractor trailer carrying gasoline impacted an overpass support column and burst into flames. The subsequent fire burned for over 2 h and led to the collapse of the overpass due to the loss of strength in the structural steel that supported the overpass. The second incident was a chain reaction accident involving several tractor trailers in the I-5 'Newhall Pass' truck bypass tunnel in Santa Clarita. This accident also involved an intense fire that damaged the tunnel and required the closing of the tunnel for repairs to the concrete walls. The US Nuclear Regulatory Commission (NRC) is studying both these accidents to examine any potential regulatory implications related to the safe transport of radioactive materials including spent nuclear fuel in the United States. This paper will discuss the details of the MacArthur Maze fire investigation. The NRC's investigation of the Newhall Pass fire is ongoing and the results are not available for publication.     

International Working Group for Sabotage Concerns of Transport and Storage Casks

Abstract

The International Working Group for Sabotage Concerns of Transport and Storage Casks (IWGSTSC), gathers multiple organisations from different countries (for US party Department of Energy, Nuclear Regulatory Commission, and Sandia National Laboratories; for German party Gesellschaft für Anlagen- und Reaktorsicherheit and Fraunhofer Institut; for the French party Institut de Radioprotection et de Sûreté Nucléaire). The goal of the IWGSTSC is to continue cooperation to improve the analytic capabilities, through information sharing and collaborative research and development plus modelling, to understand the potential adverse public health effects and environmental impacts of radiological sabotage directed at or associated with the transport and storage of civilian nuclear material or other civilian radioactive materials. The Parties may also undertake collaborative research and development in other areas of the physical protection of civilian nuclear materials or other radioactive materials. Since 2000, the IWGSTSC has conducted an extensive test programme for the assessment of the aerosol source term produced in the case of spent fuel transport sabotage by a high energy density device, after having examined several scenarios. The major goal of this programme is to produce an accurate estimate of the so called spent fuel ratio in the domain of respirable, aerosol particles produced. All the reports prepared by Sandia National Laboratories have precisely emphasised the important efforts they have made from the beginning and the amount of work already accomplished. In parallel, the International Atomic Energy Agency (IAEA), assisted by technical experts from different countries, has provided a draft document promised to become guidance for the security of radioactive or nuclear materials during transport. The IAEA document contains general guidance addressed to anyone who intends to implement or improve the security of material transports, but the text is, as of today, limited to rather general recommendations. Based on all the knowledge accumulated from past experiments and also based on the work carried out in Vienna at the IAEA, the IWGSTSC members have decided to work on the development of a method for the evaluation of the vulnerability and the source term. So for doing that, joint projects for the research, development, testing and evaluation of the consequences of the malevolent actions during transport are being pursued and are described in this paper.     

Development of Chinese database on safe transport of radioactive materials

Abstract

The paper introduces the newly established Chinese database, which is still in its initial stage of development, on the safe transport of radioactive materials in China. The database will collect data on several transport routes in China that presently have comparatively large transport volume. The database mainly includes data on transport management, transport incidents/accidents and road circumstances, etc. This will provide a data shared plane for departments in charge of packaging and transport and for research institutes. Areas of improvements in the future work are also mentioned at the end of the paper.     

Process and compressive properties of porous nickel materials

Abstract

Compressive properties are investigated for the porous Ni materials processing by innovated powder metallurgical (PM) method. The porous Ni materials first show a short elastic region, then a long and oblique stress yield region within the strain range of about 10–50%, and finally, a densification region where the stress increases rapidly.     

Synthesis and wear of Al based,free standing functionally gradient materials: effects of different reinforcements

Abstract

In the present study, three aluminium based functionally gradient materials (FGMs), reinforced with different ceramic particulates (silicon carbide, aluminium oxide, and titanium carbide), were successfully synthesised using the innovative gradient slurry disintegration and deposition (GSDD) technique. The results for Al/SiC and Al/Al₂O₃ revealed, in common, an increase in the weight percentage of reinforcement along the direction of deposition, to result in an increase in porosity and microhardness. However, for Al/TiC, the reverse trend was observed, with porosity and microhardness decreasing with increasing distance from the base of the ingot. The porosity levels for Al/TiC were also found to be significantly lower than those ofthe other two FGMs. Thermomechanical analysis of the FGMs showed thatthe average coefficient of thermal expansion of the high reinforcement end was reduced, as compared to the high aluminium end. Sliding wear test results also revealed that the high reinforcement end was more wear resistant than the high aluminium end, except for the case of Al/Al₂O₃. An attempt is made to interrelate the effects of different types of particulates, with microstructural development, microhardness and wear rate results obtained in the present study.     

Inferences on plastic properties and coefficient of friction during simultaneous compression deformation of dissimilar sintered powder metallurgical preforms

Abstract

Plastic working of powder metallurgical (PM) material necessitates the development of fundamental data such as flow stress, densification behaviour, coefficient of friction, apparent strength coefficient, apparent strain hardening exponent, plastic Poisson's ratio, etc. In the present work compression and standard ring compression tests have been carried out to generate the fundamental data for simultaneous deformation of sintered steel and copper powder metallurgical preforms. The results reveal that the behaviour of individual materials during simultaneous deformation is strongly influenced by local micromechanical interactions at the metal - metal interface. In addition to this, the test conditions (iso-stress and iso-strain) strongly influence the severity of interaction. The interfacial friction coefficients are less than that of the same material when tested between hard tools. The optimal process parameters with higher interfacial friction, which can enhance the solid state joining of dissimilar materials, have been identified. The flow stress of the composite (steel - copper combination) during simultaneous deformation can be estimated if the flow stress of the individual materials comprising the combination/composite are known. With these studies, it should be possible to extend the inferences to the major deformation processes.     

Development of laminated composite materials based on orthorhombic aluminide/titanium alloy and their tensile mechanical properties

Abstract

Laminated composite materials consisting of an orthorhombic Ti₂AlNb based alloy and an (α+β) titanium alloy have been fabricated at a laboratory scale using a two-step process involving diffusion bonding and hot rolling. The feasibility of fabrication of two and three layered materials with high quality bonding between layers was demonstrated. Preliminary assessment of the tensile mechanical properties of the obtained composite materials showed that they were superior to those of the titanium alloy and slightly inferior to the orthorhombic alloy.     

Characterisation of functionally graded and VC/steel surface alloyed composites produced using powder metallurgy

Abstract

In this study, low carbon steel specimens with surface alloyed composites were produced by means of powder metallurgy. Vanadium carbide, graphite (1·2 wt-%) and Fe were used for the surface alloyed composite, while Fe and graphite (0·2 wt-%) were used for the low carbon steel side. The powder mixtures were compacted together in the same mould. On the surface alloyed side the vanadium carbide content was changed from 5 to 25 wt-%. Microstructural investigations including EDX and X-ray, hardness measurement and abrasive wear tests were performed. The results showed that V₈C₇ formed in the alloyed surface and carbon diffusion from the alloyed surface to the parent metal created a functionally graded material. The hardness values decreased towards the parent metal. Wear resistance increased as the vanadium carbide increased in the surface alloyed composite. Thus, a functionally graded steel having a surface composite that is resistant to abrasive wear can be obtained via the powder metallurgy route.     

Structure evolution in annealed and hot deformed Al–V2 O5 composite

Abstract

Structural observations and hot deformation tests were carried out on mechanically alloyed Al-10 wt-%V₂ O₅ composite. Initial annealing experiments revealed a hardening of the material during the first stage of annealing. The material hardness increased from 114 HB for as extruded material to 167 HB after annealing at 873 K for 6 h. Differential scanning calorimetry tests conducted on as extruded material confirmed the development of an exothermic reaction during heating of the material within the temperature range 650–870 K. The amount of heat released was reduced with increasing annealing time at 873 K. Transmission electron microscopy (TEM) and X-ray analysis of annealed material revealed new intermetallic grains and very fine aluminium oxide particles, which resulted from the chemical reaction between the aluminium matrix and vanadium oxides. The development of voids in long aged specimens was found to be an undesirable effect of local specific volume reduction during the course of the chemical reaction that was not fully compensated by the local volume increase due to the growth of intermetallic particles. As a result, the material hardness was reduced in long time annealed specimens. The mechanical properties of as extruded and annealed specimens were investigated by means of hot compression testing within the temperature range 623–903 K. These tests revealed that the flow stress of as extruded material was reduced from 180 to 22 MPa when tested at 623 and 903 K, respectively. Annealed specimens exhibited higher flow stresses of 195 and 32 MPa at the same temperatures. The results indicate that the strength of the material can be effectively increased owing to a change of material structure as a result of the chemical reaction taking place during high temperature annealing.