Numerical modeling of combustion processes and pollutant formations in direct-injection diesel engines

The Representative Interactive Flamelet (RIF) concept has been applied to numerically simulate the combustion processes and pollutant formation in the direct injection diesel engine. Due to the ability for interactively describing the transient behaviors of local flame structures with CFD solver, the RIF concept has the capabilities to predict the auto-ignition and subsequent flame propagation in the diesel engine combustion chamber as well as to effectively account for the detailed mechanisms of soot formation, NO_X formation including thermal NO path, prompt and nitrous NO_X formation, and reburning process. Special emphasis is given to the turbulent combustion model which properly accounts for vaporization effects on the mixture fraction fluctuations and the pdf model. The results of numerical modeling using the RIF concept are compared with experimental data and with numerical results of the commonly applied procedure which the low-temperature and high-temperature oxidation processes are represented by the Shell ignition model and the eddy dissipation model, respectively. Numerical results indicate that the RIF approach including the vaporization effect on turbulent spray combustion process successfully predicts the ignition delay time and location as well as the pollutant formation.     

基底元素表面富集与扩散阻档层

根据An－Ag系统以及An－Cu系统的扩散系数计算，提出了扩散阻挡层模型。利用这个模型对Au－Ag系统进行有关实验，得利了较好的验证。     

Microstructural investigation of the breakdown of the protective oxide scale on a 304 steel in the presence of oxygen and water vapour at 600 °C

This article focuses on the detailed microstructural investigation of the oxide scale formed on a 304 steel in the presence of oxygen and water vapour (40%) at 600 °C. The work has been carried out using a combination of microanalytical techniques including FIB, TEM, EDX and electron diffraction. The local breakdown of the initially protective oxide scale and the growth of island/crater oxide morphology are described. Special consideration is given to the influence of the microstructure of the steel and the oxide scale on the breakdown behaviour.     

Determination of the vapor pressures of select polychlorinated dibenzo-p-dioxins and dibenzofurans at 75-275 °C

Vapor pressures were determined for several polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) at 75-275 °C, extending the available literature data to more relevant temperature regions and providing the first experimental data for 2,3,7-trichlorodibenzo-p-dioxin (2,3,7-TriCD). A modification of the effusion technique, based upon controlling the diffusion of the target compound and subsequent high resolution gas chromatography/low resolution mass spectrometry (HRGC/LRMS) analysis, was proven comparable to other accepted methods for determining the vapor pressures of semi-volatile organic compounds (SVOCs). Vapor pressures for octachlorodibenzo-p-dioxin (OCDD) and octachlorodibenzofuran (OCDF) were in excellent agreement with those reported in literature. The application of the current method for the vapor pressure determinations of eight polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) in the extended temperature range (up to 275 °C) is reported. The extension of the vapor pressures to such temperatures, unprecedented for the PCDDs/Fs, is important for vapor-particle partitioning modeling in regions relevant to PCDD/F formation and control. Estimates for the melting temperatures and enthalpies of sublimation and vaporization are also reported, the latter for which no experimentally determined values have been found in the literature. The use of the method to deliver reproducible, trace concentrations (ppt-ppb) of targets was applied to the calibration of the jet-REMPI/TOFMS as an online detector for low chlorinated PCDDs/Fs.     

Distinctive combustion stages of single heavy oil droplet under microgravity

This report presents an investigation on the combustion of single droplets comprised of heavy oil and oil mixtures blending diesel light oil (LO) and a heavy oil residue (HOR). The tests were conducted in a microgravity facility that offered 10 s of free-fall time. Fine wire thermocouples supported the droplets, resulting in a measurement of droplet temperature history. Additional data were the droplet and flame size history. The results identified four distinctive burning stages between ignition and extinction for heavy oil (C class) and HOR-LO blends. They are, in succession, the start-up, inner evaporation, thermal decomposition (pyrolysis) and polymerization stages. The start-up stage denoted an initial transient period, where the LO components burned from the droplet surface and the droplet temperature increased rapidly. The latter three stages featured pronounced droplet swellings and contractions caused by fuel evaporation and decomposition inside the droplet. An evaporation temperature demarcated the start-up stage from the inner evaporation stage, and this temperature corresponded to a plateau in the temperature history of the droplet. Two additional temperatures, termed the decomposition and polymerization temperatures, indicated the ends of the evaporation and decomposition stages. These temperatures were similarly identified by plateaus or inflection points in the time-temperature diagram. The evaporation temperature gradually decreased with increasing the initial LO mass fraction in the droplet, whereas the other two temperatures were almost independent of the oil composition. All three temperatures increased with decreasing initial droplet diameter, but the dependence was very slight. Based on the results, the combustion of heavy oil droplets appears to be dominated by a distillation-like vaporization mechanism, because of the rapid mass transport within the droplets caused by the disruptive burning.     

由液体密度和蒸发焓关联纯物质的临界参数

本文提出了一个由液体密度和正常沸点下蒸发焓数据推算物质临界参数的新方法。本方法所需数据为：液体密度、ＺＲＡ值及正常沸点下蒸发焓。采用本文方法对有代表性的近１００种有机物和１６种无机物的Ｐｃ和Ｔｃ值进行了估算，结果表明本文方法稳定、可靠。     

First-order perturbation solutions of liquid pool spreading with vaporization

In this study, a simple physical model for liquid pool spreading with vaporization is solved semi-analytically for the first time using the mathematical method of perturbation techniques. The evaporation rate per unit area is used as the perturbation parameter, and first-order solutions are obtained for continuous and instantaneous releases.     

液氩冷量回收技术

文章主要介绍液氩冷量回收装置的原理、流程及操作要点。将原来散失在大气中的冷量进行回收 ,用来液化氧气和液氩贮罐中保温不好而汽化的氩气 ,以增加液体产量 ,具有可观的经济效益。     

Intensity and efficiency of spray fuel-fed well-mixed adiabatic combustors

Motivated by the insights it can provide, we revisit the classical problem of liquid fuel-fed idealized steady-flow combustors. New quadrature-based results are presented for the theoretical combustion intensity and corresponding efficiency for well-stirred adiabatic vessels fed with a prescribed polydispersed spray. Each droplet of the spray is assumed to evaporate according to a non-quasi-steady (non-QS) gas-phase energy/mass diffusion-controlled rate for the pseudo-single-component fuel. As a byproduct, we calculate the complete droplet size distribution (DSD) function exiting the chamber, of interest for the design of downstream components. We explicitly assume that the volumetric rate of chemical energy release in such “primary” combustion chambers is controlled by the liquid fuel physical vaporization process (with negligible lags due to propellant droplet heat-up or vapor-phase ignition). In this instructive asymptotic limit, two decisive non-dimensional parameters are shown to be: (1) a vaporization Damköhler number (defined by the ratio of the mean residence time of the chemically reacting vapor mixture in the combustion space, to the reference value of the vaporization lifetime of a droplet with the injector-Sauter-mean diameter, and (2) a single dimensionless non-QS parameter. Illustrative numerical results for a kerosene-like fuel burning in air at pressures up to 24 atm are displayed for the case of a log-normal feedstream DSD with a range of spreads. Our results reveal the existence of an optimum vaporization Damköhler number which maximizes the combustion intensity—with maximum intensities, occurring well before nearly complete fuel evaporation, being quite sensitive to the non-QS parameter at high pressures. These deliberately idealized mathematical model results, spanning more than a 1000 combinations of operational parameters, set instructive bounds to the achievable performance of “real” spray combustors. Even without tractable enhancements (see Section 5.2), this approach can be used to economically map the sensitivity of spray combustor performance to a large number of important design and control parameters.     

The role of ricochet impacts on impact vaporization

Vaporization of carbonate targets by hypervelocity impact increases with decreasing impact angle (from the horizontal), in contrast with expectations based only on peak shock pressures. Experiments at the NASA Ames Vertical Gun Range were designed to allow isolating the underlying controlling processes and probing the vapor composition using high-speed spectroscopy. Vaporization associated with the maximum peak pressures (first contact) was separated from vaporization generated only by downrange ricochet impacts through the use of split targets. Four telescopes isolated the vapor with different velocities and revealed that grazing ricochet debris downrange contributed a significant fraction to the overall vaporization process. These results can be understood by the high temperatures and low pressures created by high strain-rate shear.